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CAS No.: | 5668-93-9 |
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Name: | 3-ETHYLBIPHENYL |
Article Data: | 17 |
Molecular Structure: | |
Formula: | C14H14 |
Molecular Weight: | 182.265 |
Synonyms: | Biphenyl,3-ethyl- (6CI,7CI,8CI); 3-Ethylbiphenyl; NSC 75365; m-Ethylbiphenyl |
Density: | 0.971g/cm3 |
Melting Point: | -27 °C |
Boiling Point: | 284 °C |
Flash Point: | 125.3°C |
PSA: | 0.00000 |
LogP: | 3.91600 |
Conditions | Yield |
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Stage #1: 3-methoxybiphenyl With bis(1,5-cyclooctadiene)nickel (0); 1,2-bis-(dicyclohexylphosphino)ethane In di-isopropyl ether; toluene at 20℃; for 0.0833333h; Glovebox; Inert atmosphere; Stage #2: triethylaluminum In di-isopropyl ether; toluene at 120℃; for 72h; Glovebox; Inert atmosphere; | 95% |
3-(methoxymethyl)-1,1'-biphenyl
methylmagnesium bromide
3-ethyl-1,1'-biphenyl
Conditions | Yield |
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1,1'-bis-(diphenylphosphino)ferrocene; [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride; potassium iodide In diethyl ether; toluene at 80℃; for 10h; | 91% |
3-ethylphenyl trifluoromethanesulfonate
3-ethyl-1,1'-biphenyl
Conditions | Yield |
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With acetone; trifluoroacetic acid In water at 15℃; UV-irradiation; Inert atmosphere; | 64% |
Conditions | Yield |
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With aluminium trichloride |
Conditions | Yield |
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With aluminium trichloride |
Conditions | Yield |
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With aluminium trichloride |
Conditions | Yield |
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Kochen des nach der Hydrolyso erhaltenen Reaktionsprodukts mit Palladium/Kohle; |
Conditions | Yield |
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With diethyl ether Kochen des nach der Hydrolyse erhaltenen Reaktionsprodukts mit Palladium-Kohle; |
(RS)-1-([1,1'-biphenyl]-3-yl)ethanol
3-ethyl-1,1'-biphenyl
Conditions | Yield |
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With copper chromite at 200℃; under 102971 Torr; Hydrogenolyse; |
phenylium
ethylbenzene
A
3-ethyl-1,1'-biphenyl
B
2-ethyl-1,1'-biphenyl
C
4-ethylbiphenyl
Conditions | Yield |
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Product distribution; Rate constant; with totally tritiated phenyl cation, gas and liquid phases at r.t., solid phase at temp. of liquid N2; | A 26 % Chromat. B 36 % Chromat. C 38 % Chromat. |