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569-42-6

Basic Information
CAS No.: 569-42-6
Name: 1,8-DIHYDROXYNAPHTHALENE
Article Data: 42
Molecular Structure:
Molecular Structure of 569-42-6 (1,8-DIHYDROXYNAPHTHALENE)
Formula: C10H8O2
Molecular Weight: 160.172
Synonyms: 1,8-Dihydroxynaphthalene;Naphthalene-1,8-diol;
EINECS: 209-316-5
Density: 1.33g/cm3
Melting Point: 142-143℃
Boiling Point: 375.4 °C at 760 mmHg
Flash Point: 193.5 °C
Hazard Symbols: Xi
Risk Codes: 41
Safety: 26-39
PSA: 40.46000
LogP: 2.25100
Synthetic route
83-31-8

1,8-naphthosultone

569-42-6

1,8-dihydroxynaphthalene

Conditions
ConditionsYield
With potassium hydroxide at 300℃; for 0.5h;86%
With potassium hydroxide; water at 225℃; for 0.5h;83%
With potassium hydroxide at 300℃; for 0.5h;80%

1,1-dimethyl-1H,3H-naphtho[1,8-cd][1,2,6]oxasilaborinin-3-ol

569-42-6

1,8-dihydroxynaphthalene

Conditions
ConditionsYield
With dihydrogen peroxide In tetrahydrofuran; methanol; dodecane at 20℃;67%

1,8-naphthalenesultone

569-42-6

1,8-dihydroxynaphthalene

Conditions
ConditionsYield
With potassium hydroxide for 0.25h; Inert atmosphere;60%

1,8-naphthosultone

569-42-6

1,8-dihydroxynaphthalene

Conditions
ConditionsYield
Stage #1: 1,8-naphthosultone With potassium hydroxide; sodium hydroxide at 210℃; for 0.75h; Inert atmosphere;
Stage #2: With sulfuric acid; water at 0℃;
53%
117-22-6

8-hydroxy-naphthalene-1-sulfonic acid

569-42-6

1,8-dihydroxynaphthalene

Conditions
ConditionsYield
at 230℃; in der Kalischmelze;
83-65-8

4,5-dihydroxy-1-naphthalene-sulfonic acid

569-42-6

1,8-dihydroxynaphthalene

Conditions
ConditionsYield
With sulfuric acid at 150℃;
603-72-5

1,8-naphthosultam

569-42-6

1,8-dihydroxynaphthalene

Conditions
ConditionsYield
bei der Kalischmelze;

furan-2,3,5(4H)-trione pyridine (1:1)

82-75-7

8-anilino-1-naphthalenesulfonate

A

569-42-6

1,8-dihydroxynaphthalene

B

2834-91-5

8-amino-1-naphthol

C

117-22-6

8-hydroxy-naphthalene-1-sulfonic acid

D

134-32-7

1-amino-naphthalene

Conditions
ConditionsYield
at 220 - 300℃; im Autoklaven;
82-75-7

8-anilino-1-naphthalenesulfonate

569-42-6

1,8-dihydroxynaphthalene

Conditions
ConditionsYield
With sodium hydroxide at 220 - 230℃; unter Druck;
Multi-step reaction with 2 steps
1: 92 percent / NaNO2, aq. HCl / H2O / 1 h / Heating
2: KOH / neat (no solvent) / 1.75 h / 250 - 255 °C
View Scheme
3588-75-8

8-methoxy-naphthalen-1-ol

A

569-42-6

1,8-dihydroxynaphthalene

B

930-73-4

1-methyl pyridinium iodide

Conditions
ConditionsYield
With pyridine; pyridine hydroiodide at 115℃; Rate constant; LiI, KI, var. temp.;
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Chemistry

Molecular Structure of 1,8-Naphthalenediol (CAS NO.569-42-6):

IUPAC Name: naphthalene-1,8-diol 
Empirical Formula: C10H8O2
Molecular Weight: 160.1693
H bond acceptors: 2
H bond donors: 2
Freely Rotating Bonds: 2
Polar Surface Area: 18.46 Å2
Index of Refraction: 1.725
Molar Refractivity: 47.85 cm3
Molar Volume: 120.4 cm3
Surface Tension: 64.4 dyne/cm
Density: 1.33 g/cm3
Flash Point: 193.5 °C
Enthalpy of Vaporization: 64.73 kJ/mol
Boiling Point: 375.4 °C at 760 mmHg
Vapour Pressure: 3.62E-06 mmHg at 25°C
EINECS: 209-316-5
InChI
InChI=1/C10H8O2/c11-8-5-1-3-7-4-2-6-9(12)10(7)8/h1-6,11-12H
Smiles
c12c(O)cccc2cccc1O

Specification

  1,8-Naphthalenediol , with CAS number of 569-42-6, can be called 1,8-Dihydroxynaphthalene ; Naphthalene-1,8-diol .