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Basic Information
| CAS No.: | 57-48-7 |
|---|---|
| Name: | D(-)-Fructose |
| Molecular Structure: | |
|
|
|
| Formula: | C6H12O6 |
| Molecular Weight: | 180.158 |
| Synonyms: | Fructose, D-(8CI);Advantose FS 95;D-(-)-Fructose;D-(-)-Levulose;D-arabino-2-Hexulose;Fructose;Fruit sugar;Fujifructo L 95;Furucton;Hi-Fructo 970;Krystar;Krystar 300;Levulose;Nevulose;Sugar, fruit; |
| EINECS: | 200-333-3 |
| Density: | 1.59 g/cm3 |
| Melting Point: | 119-122 °C (dec.)(lit.) |
| Boiling Point: | 440.1oC at 760 mmHg |
| Flash Point: | 220oC |
| Solubility: | 3750 g/L (20°C) in water |
| Appearance: | Highly hygroscopic white odorless crystal or crystalline powder |
| Hazard Symbols: |
 C
|
| Risk Codes: | 34 |
| Safety: | 24/25-45-36/37/39-27-26 |
| Transport Information: | White Cyrstalline Solid |
| PSA: | 118.22000 |
| LogP: | -3.37720 |
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Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| With niobic acid In water at 89.84℃; for 2h; Catalytic behavior; Reagent/catalyst; Autoclave; Inert atmosphere; | A 87% B n/a |
Conditions
| Conditions | Yield |
|---|---|
| With copper(II) oxide In water at 199.84℃; for 0.5h; Temperature; Inert atmosphere; | A n/a B n/a C 85% |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| With dihydrogen peroxide; iron(II) sulfate In water at 70℃; for 0.25h; Temperature; Reagent/catalyst; Green chemistry; | A 7% B 84% |
Conditions
| Conditions | Yield |
|---|---|
| With oxygen In water at 50℃; under 750.075 Torr; for 12h; Catalytic behavior; Time; Autoclave; Green chemistry; | A 8% B 83% |
Conditions
| Conditions | Yield |
|---|---|
| With D-fructose-6-phosphate aldolase of Escherichia coli Ala129Ser mutant at 25℃; for 48h; pH=7.5; NaHCO3 buffer; | 81% |
| With transaldolase from listeria monocytogenes In aq. phosphate buffer for 8h; pH=7.5; Enzymatic reaction; | 25% |
| With E. coli transaldolase B mutant F178Y In glycyl-glycine buffer at 25℃; pH=8.5; Enzymatic reaction; optical yield given as %de; stereoselective reaction; | |
| With E. coli transaldolase B mutant F178Y In glycyl-glycine buffer at 30℃; pH=8.5; Kinetics; Enzymatic reaction; stereoselective reaction; |
A
- 57-48-7
D-Fructose
B
- 546-42-9, 97949-45-6
di-D-fructofuranosyl 2,6':2',6-dianhydride
Conditions
| Conditions | Yield |
|---|---|
| levan fructotransferase In phosphate buffer at 30℃; for 24h; pH=6.0; Hydrolysis; | A n/a B 75% C n/a |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: magnesium glycerol phosphate; D-Glyceraldehyde With glycerol phosphate oxidase; recombinant D-fructose 1,6-bisphosphate aldolase from Staphylococcus carnosus; catalase In water at 20℃; for 22h; pH=7; Enzymatic reaction; Stage #2: With hydrogenchloride; acid phosphatase from sweet potato In water at 37℃; for 24h; pH=Ca. 5; Enzymatic reaction; stereoselective reaction; | 60% |
| With FAD; Staphylococcus carnosus D-fructose 1,6-bisphosphate aldolase; Streptococcus pneumonia glycerol phosphate oxidase In water-d2 at 30℃; for 22h; pH=7; Enzymatic reaction; | 56% |
Conditions
| Conditions | Yield |
|---|---|
| With Mg-Al hydrotalcite In butan-1-ol at 95℃; for 10h; Temperature; Reagent/catalyst; | 57% |
| With hydrotalcite with a Mg/Al ratio of 3:1 In ethanol at 119.84℃; under 760.051 Torr; for 0.5h; Catalytic behavior; Solvent; Temperature; Inert atmosphere; | 56% |
| Stage #1: D-glucose In ethanol at 90℃; for 24h; Stage #2: With water at 90℃; for 24h; Reagent/catalyst; | 50% |
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: D-glucose With zirconium metal organic framework UiO-66 In propan-1-ol at 90℃; for 24h; Sealed tube; Stage #2: In water at 90℃; for 24h; Catalytic behavior; Mechanism; Solvent; | A 56% B n/a |
| With SrO(SrTiO3)2 In water at 110℃; for 1h; Reagent/catalyst; | A 34% B 10% |
| With 5% LaOH/C In water at 100℃; under 15001.5 Torr; for 2h; Reagent/catalyst; Solvent; Autoclave; Inert atmosphere; | A 25.97% B 6.95% |
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