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| CAS No.: | 5746-86-1 |
|---|---|
| Name: | 3-(2-Pyrrolidinyl)pyridine |
| Article Data: | 49 |
| Molecular Structure: | |
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| Formula: | C9H12 N2 |
| Molecular Weight: | 148.208 |
| Synonyms: | Nicotine,1'-demethyl-, (?à)-(8CI); Pyridine, 3-(2-pyrrolidinyl)-, (?à)-; (RS)-Nornicotine; (?à)-1'-Demethylnicotine; (?à)-Nornicotine; 2-(3-Pyridinyl)pyrrolidine;3-(Pyrrolidin-2-yl)pyridine |
| EINECS: | 200-659-6 |
| Density: | 1,074 g/cm3 |
| Melting Point: | 235-236 °C(Solv: ethanol (64-17-5)) |
| Boiling Point: | 107-108°C 2mm |
| Flash Point: | 101°C |
| Solubility: | H2O: 50 mg/mL |
| Appearance: | liquid |
| Hazard Symbols: | R20/21/22:; R36/37/38:; |
| Risk Codes: | 20/21/22-36/37/38 |
| Safety: | Poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of NOx and HCl. See also NORNICOTINE. |
| PSA: | 24.92000 |
| LogP: | 1.83490 |
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Chemistry
The Molecular formula of NORNICOTINE (+)-HYDROCHLORIDE (5746-86-1):C9H12N2
The Molecular Weight of NORNICOTINE (+)-HYDROCHLORIDE (5746-86-1):148.2
The Molecular Structure of NORNICOTINE (+)-HYDROCHLORIDE (5746-86-1) is:.gif)
Density:1.042 g/cm3
Boiling point:270 °C at 760 mmHg
Flash point:111.3 °C
Solubility in water:H2O: 50 mg/mL
Index of Refraction:1.536
Molar Refractivity:44.33 cm3
Molar Volume:142.1 cm3
Polarizability:17.57 10-24cm3
Surface Tension:41.3 dyne/cm
Enthalpy of Vaporization:50.82 kJ/mol
Appearance:colourless oil
IUPAC Name: 3-pyrrolidin-2-ylpyridine
Synonyms: (+/-)-NORNICOTINE ; (R,S)-NORNICOTINE ; (+-)-1’-demethylnicotine ; beta-dl-nornicotine ; 2-[3-PYRIDYL]PYRROLIDINE ; 2-[3-PYRIDYL]PYRROLIDONE ; (+/-)-3-(2-PYRROLIDINYL)PYRIDINE ; NORNICOTINE, DL-
Uses
A metabolite of Nicotine. Can catalyze aqueous aldol reactions
Toxicity Data With Reference
| 1. | ipr-rat LDLo:6 mg/kg | AJEBAK Australian Journal of Experimental Biology and Medical Science. 25 (1947),83. | ||
| 2. | ipr-gpg LDLo:10 mg/kg | AJEBAK Australian Journal of Experimental Biology and Medical Science. 25 (1947),83. |
Safety Profile
Poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of NOx and HCl. See also NORNICOTINE.
Hazard Codes:Xn,Xi
Xi:Irritant.gif){kind=small}
Xn:Harmful
Risk Statements
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
Safety Statements
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
RIDADR:2810
WGK Germany:3
RTECS:QS6350000
F:3-10
HazardClass:6.1
PackingGroup:III