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5796-98-5

Basic Information
CAS No.: 5796-98-5
Name: BIS(TRIMETHYLSILYL)PEROXIDE
Article Data: 1
Molecular Structure:
Molecular Structure of 5796-98-5 (BIS(TRIMETHYLSILYL)PEROXIDE)
Formula: C6H18O2Si2
Molecular Weight: 178.379
Synonyms: 3,4-Dioxa-2,5-disilahexane,2,2,5,5-tetramethyl- (8CI);Peroxide, bis(trimethylsilyl) (6CI);Silane,dioxybis[trimethyl- (9CI);Bis(trimethylsilyl) peroxide;Trimethylsilylperoxide;
Density: 0.842 g/cm3
Melting Point: < 0 °C
Boiling Point: 124.639 °C at 760 mmHg
Flash Point: 20.542 °C
Risk Codes: 8-10
Safety: 17-36/37/39
Transport Information: 3103
PSA: 18.46000
LogP: 2.60440
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Specification

The CAS register number of Silane,1,1'-dioxybis[1,1,1-trimethyl- is 5796-98-5. It also can be called as Dioxybis(trimethylsilane) and the IUPAC name about this chemical is trimethyl(trimethylsilylperoxy)silane. The molecular formula about this chemical is C6H18O2Si2 and the molecular weight is 178.38. It belongs to the Industrial/Fine Chemicals.

Physical properties about Silane,1,1'-dioxybis[1,1,1-trimethyl- are: (1)ACD/LogP: 2.59; (2)ACD/LogD (pH 5.5): 3; (3)ACD/LogD (pH 7.4): 3; (4)ACD/BCF (pH 5.5): 228; (5)ACD/BCF (pH 7.4): 228; (6)ACD/KOC (pH 5.5): 1694; (7)ACD/KOC (pH 7.4): 1694; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 3; (10)Polar Surface Area: 18.46Å2; (11)Index of Refraction: 1.395; (12)Molar Refractivity: 50.771 cm3; (13)Molar Volume: 211.774 cm3; (14)Polarizability: 20.127x10-24cm3; (15)Surface Tension: 16.764 dyne/cm; (16)Enthalpy of Vaporization: 34.756 kJ/mol; (17)Boiling Point: 124.639 °C at 760 mmHg; (18)Vapour Pressure: 15.267 mmHg at 25°C.

Preparation: this chemical can be prepared by chloro-trimethyl-silane. This reaction will need reagent pyridine, diethyl ether, H2O2.

Uses of Silane,1,1'-dioxybis[1,1,1-trimethyl-: it can be used to produce trimethyl-vinyloxy-silane with vinylmagnesium bromide at temperature of 0 ℃. This reaction will need solvent diethyl ether, tetrahydrofuran. The yield is about 53%.

When you are using this chemical, please be cautious about it as the following:
This chemical is flammable. It contacts with combustible material may cause fire. If you want to use this chemical, plese keep away from combustible material. When you are using it, wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)SMILES: O(O[Si](C)(C)C)[Si](C)(C)C
(2)InChI: InChI=1/C6H18O2Si2/c1-9(2,3)7-8-10(4,5)6/h1-6H3
(3)InChIKey: XPEMYYBBHOILIJ-UHFFFAOYAI
(4)Std. InChI: InChI=1S/C6H18O2Si2/c1-9(2,3)7-8-10(4,5)6/h1-6H3
(5)Std. InChIKey: XPEMYYBBHOILIJ-UHFFFAOYSA-N