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CAS No.: | 5906-35-4 |
---|---|
Name: | 1-AMINOHOMOPIPERIDINE |
Article Data: | 11 |
Molecular Structure: | |
Formula: | C6H14 N2 |
Molecular Weight: | 114.191 |
Synonyms: | 1H-Azepine,1-aminohexahydro- (7CI,8CI); (Azepan-1-yl)amine; 1,1-Hexamethylenehydrazine;1-Aminoazepane; 1-Aminohexahydro-1H-azepine; 1-Aminohexahydroazepine;1-Aminohexamethyleneimine; 1-Aminohomopiperidine; 1-Aminoperhydroazepine;Hexahydro-1H-azepin-1-amine; N-Aminoazacycloheptane; N-Aminohexahydroazepine;N-Aminohexamethyleneimine; N-Aminohexamethylenimine; N-Aminohomopiperidine; N-Aminoperhydroazepine;NSC 221198; NSC 82329 |
Density: | 0.984 g/mL at 25 °C(lit.) |
Melting Point: | 86.0-86.5 °C |
Boiling Point: | 165 °C(lit.) |
Flash Point: | 133 °F |
Hazard Symbols: | Xi |
Risk Codes: | 36/37/38 |
Safety: | A poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic vapors of NOx. |
PSA: | 29.26000 |
LogP: | 1.37430 |
Conditions | Yield |
---|---|
With hydrogenchloride In tetrahydrofuran; water; ethyl acetate | 90% |
Conditions | Yield |
---|---|
In methanol for 25.5h; Reflux; | 45% |
(CH2)6NNH2*BH3
water
A
hydrogen
B
boric acid
C
1-azepanylamine
Conditions | Yield |
---|---|
In water | |
In water |
1-azepanylamine
diethyl 2-ethoxymethylenemalonate
(hexahydro-1H azepinyl-1 amino)-3 ethoxycarbonyl-2 propenoate d'ethyle
Conditions | Yield |
---|---|
In methanol for 1h; Ambient temperature; | 98% |
Conditions | Yield |
---|---|
With potassium hydride In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide for 24h; Ambient temperature; | 97% |
Conditions | Yield |
---|---|
With sodium sulfite In diethyl ether for 24h; Ambient temperature; | 95% |
Conditions | Yield |
---|---|
for 0.25h; Heating; | 94% |
2-chloro-6-methylphenyl isocyanate
1-azepanylamine
Conditions | Yield |
---|---|
In benzene Heating; | 92% |
1-azepanylamine
2,6-dimethylphenylisocyanate
Conditions | Yield |
---|---|
In benzene Heating; | 92% |
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IUPAC Name: Azepan-1-amine
Synonyms : 1-Aminohexahydroazepine ; 1-Azepanamine ; 1H-Azepin-1-amine, hexahydro- ; 1,1-Hexamethylenehydrazine
Product Categories: Heterocyclic Compounds
CAS NO: 5906-35-4
Molecular Formula of 1,1-Hexamethylenehydrazine (CAS NO.5906-35-4) :C6H14N2
Molecular Weight of 1,1-Hexamethylenehydrazine (CAS NO.5906-35-4) :114.19
Molecular structure of 1,1-Hexamethylenehydrazine (CAS NO.5906-35-4) :
EINECS: 227-609-6
Index of Refraction:1.478
Surface Tension: 34 dyne/cm
Density: 0.929 g/cm3
Flash Point: 56.1 °C
Enthalpy of Vaporization: 40.2 kJ/mol
Boiling Point: 165.6 °C at 760 mmHg
Vapour Pressure: 1.86 mmHg at 25°C
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rat | LDLo | oral | 300mg/kg (300mg/kg) | Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 93 |
A poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic vapors of NOx.
Hazard CodesXi
Risk Statements 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 26-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RIDADR UN 1993 3/PG 3
WGK Germany 3
RTECS CM3165000
HazardClass 3.2
PackingGroup III