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5919-74-4

Basic Information
CAS No.: 5919-74-4
Name: 2,3-DIHYDROXYPROPYL METHACRYLATE
Article Data: 21
Molecular Structure:
Molecular Structure of 5919-74-4 (2,3-DIHYDROXYPROPYL METHACRYLATE)
Formula: C7H12O4
Molecular Weight: 160.17
Synonyms: Methacrylicacid, 2,3-dihydroxypropyl ester (6CI);Methacrylin, 1-mono- (8CI);2,3-Dihydroxypropyl methacrylate;Glyceryl methacrylate;
EINECS: 227-642-6
Density: 1.161 g/cm3
Melting Point: 140℃/0.6mm
Boiling Point: 310.3 °C at 760 mmHg
Flash Point: 127.3 °C
Solubility: 100g/L at 25℃
Risk Codes: 36/37/38
Safety: 26-36
PSA: 66.76000
LogP: -0.54110
Synthetic route
106-91-2

2,3-Epoxypropyl methacrylate

5919-74-4

2,3-dihydroxypropyl methacrylate

Conditions
ConditionsYield
With Cs2.5H0.5PMo12O40; water In tetrahydrofuran at 35 - 70℃; for 4h; Reagent/catalyst;93.2%
With sulfuric acid; water In tetrahydrofuran for 2h; Ambient temperature;88%
With sulfuric acid; 4-tert-Butylcatechol In water for 24h; Ambient temperature;70%
7098-80-8

2-methyl-acrylic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester

5919-74-4

2,3-dihydroxypropyl methacrylate

Conditions
ConditionsYield
With acetic acid; 4-methoxy-phenol at 80℃; for 0.166667h;80%
Hydrolysis; Acid hydrolysis;
With hydrogenchloride; water at 20℃; for 48h; Industry scale; Air stream;
With methanol; TEMPOL; 4-methoxy-phenol at 65℃; for 20h; Reagent/catalyst; Temperature;73.1 %Chromat.
100-79-8

(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol

920-46-7

Methacryloyl chloride

5919-74-4

2,3-dihydroxypropyl methacrylate

Conditions
ConditionsYield
With triethylamine In chloroform cooling;
80-62-6

methacrylic acid methyl ester

56-81-5

glycerol

A

glycerine dimethacrylate

B

5919-74-4

2,3-dihydroxypropyl methacrylate

C

1830-78-0

glycerol-1,3-dimethacrylate

D

2-hydroxy-1-(hydroxymethyl)ethyl methacrylate

Conditions
ConditionsYield
With Novozyme 435 In tert-Amyl alcohol at 50℃; for 120h; Inert atmosphere; Molecular sieve; Enzymatic reaction;
79-41-4

poly(methacrylic acid)

56-81-5

glycerol

A

7401-88-9

glyceryl tri(methyl)acrylate

B

5919-74-4

2,3-dihydroxypropyl methacrylate

C

1830-78-0

glycerol-1,3-dimethacrylate

Conditions
ConditionsYield
With toluene-4-sulfonic acid; p-benzoquinone at 90℃;
106-91-2

2,3-Epoxypropyl methacrylate

A

5919-74-4

2,3-dihydroxypropyl methacrylate

B

2-hydroxy-1-(hydroxymethyl)ethyl methacrylate

Conditions
ConditionsYield
With water at 10 - 50℃; for 5h; Green chemistry; Overall yield = 22.0 g;
With 2,6-di-tert-butyl-4-methyl-phenol; water at 70℃; for 2.5h; Overall yield = 98 %;

2,5-dimethoxybenzylidenedioxypropyl methacrylate

A

672-13-9

2-hydroxy-5-methoxybenzaldehyde

B

5919-74-4

2,3-dihydroxypropyl methacrylate

Conditions
ConditionsYield
In methanol; water at 20℃; for 1h; Kinetics; Irradiation;
5919-74-4

2,3-dihydroxypropyl methacrylate

7158-32-9

4,4'-bis(chlorocarbonyl)diphenyl oxide

C28H30O11

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; 2,6-di-tert-butyl-4-methyl-phenol In dichloromethane at -78℃; for 5h;92%
30674-80-7

2-Isocyanatoethyl methacrylate

5919-74-4

2,3-dihydroxypropyl methacrylate

C21H30N2O10

Conditions
ConditionsYield
dibutyltin dilaurate In tetrahydrofuran at 50℃; for 5h;90%
5919-74-4

2,3-dihydroxypropyl methacrylate

93-02-7

2,5-dimethoxybenzaldehyde

2,5-dimethoxybenzylidenedioxypropyl methacrylate

Conditions
ConditionsYield
With toluene-4-sulfonic acid In cyclohexane Reflux; Dean-Stark;66%
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    Min.Order: 1 Metric Ton

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  • 2-Propenoic acid,2-methyl-, 2,3-dihydroxypropyl ester

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    5919-74-4

    2,3-dihydroxypropyl Methacrylate

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Specification

This chemical is called 2-Propenoic acid,2-methyl-, 2,3-dihydroxypropyl ester, and it can also be named as Glyceryl methacrylate. With the molecular formula of C7H12O4, its molecular weight is 160.17. The CAS registry number of this chemical is 5919-74-4. Additionally, its product category is Monomer.

Other characteristics of the 2-Propenoic acid,2-methyl-, 2,3-dihydroxypropyl ester can be summarised as followings: (1)ACD/LogP: -0.12; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.12; (4)ACD/LogD (pH 7.4): -0.12; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 20.4; (8)ACD/KOC (pH 7.4): 20.4; (9)#H bond acceptors: 4; (10)#H bond donors: 2; (11)#Freely Rotating Bonds: 7; (12)Polar Surface Area: 44.76 Å2; (13)Index of Refraction: 1.475; (14)Molar Refractivity: 38.85 cm3; (15)Molar Volume: 137.8 cm3; (16)Polarizability: 15.4×10-24cm3; (17)Surface Tension: 42.2 dyne/cm; (18)Density: 1.161 g/cm3; (19)Flash Point: 127.3 °C; (20)Enthalpy of Vaporization: 63.91 kJ/mol; (21)Boiling Point: 310.3 °C at 760 mmHg; (22)Vapour Pressure: 5.43E-05 mmHg at 25°C.

You can still convert the following datas into molecular structure: 
1.SMILES: O=C(OCC(O)CO)\C(=C)C
2.InChI: InChI=1/C7H12O4/c1-5(2)7(10)11-4-6(9)3-8/h6,8-9H,1,3-4H2,2H3 
3.InChIKey: QRIMLDXJAPZHJE-UHFFFAOYAY