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5927-18-4

Basic Information
CAS No.: 5927-18-4
Name: Aceticacid, 2-(dimethoxyphosphinyl)-, methyl ester
Molecular Structure:
Molecular Structure of 5927-18-4 (Aceticacid, 2-(dimethoxyphosphinyl)-, methyl ester)
Formula: C5H11O5P
Molecular Weight: 182.1116
Synonyms: Acetic acid, phosphono-,trimethyl ester (7CI,8CI);(Carboxymethyl)phosphonic acid trimethyl ester;(Dimethoxyphosphinyl)acetic acid methyl ester;Carbomethoxymethanephosphonicacid dimethyl ester;Dimethyl methoxycarbonylmethanephosphonate;Methyl (dimethoxyphosphinyl)acetate;Methyl 2-(dimethylphosphono)acetate;Methyl dimethylphosphonoacetate;NSC 84262;Phosphonoacetic acid trimethylester;[(Methoxycarbonyl)methyl]dimethylphosphonate;
EINECS: 227-663-0
Density: 1.125 g/cm3
Melting Point: 242 °C
Boiling Point: 311 ºC at 760 mmHg
Flash Point: 109.7 °C
Solubility: Slightly miscible with water.
Appearance: clear colorless to light yellow liquid
Hazard Symbols:
Risk Codes:
Safety: 23-24/25
Transport Information:
PSA: 71.64000
LogP: 0.64530
Synthetic route
67-56-1

methanol

88738-78-7

bis-(2,2,2-trifluoroethyl)(methoxycarbonylmethyl)phosphonate

A

5927-18-4

trimethyl phosphonoacetate

B

681123-85-3

methyl methyl(2,2,2-trifluoroethyl)phosphonoacetate

Conditions
ConditionsYield
With triethylamine at 20℃; for 0.5h;A 7%
B 88%
96-32-2

bromoacetic acid methyl ester

121-45-9

phosphorous acid trimethyl ester

5927-18-4

trimethyl phosphonoacetate

Conditions
ConditionsYield
at 100℃; for 12h;74%
96-34-4

methyl chloroacetate

121-45-9

phosphorous acid trimethyl ester

5927-18-4

trimethyl phosphonoacetate

Conditions
ConditionsYield
Heating;70%
6832-16-2

methyl diazoacetate

868-85-9

Dimethyl phosphite

5927-18-4

trimethyl phosphonoacetate

Conditions
ConditionsYield
With copper acetylacetonate In benzene Heating;60%
67-56-1

methanol

16139-79-0

ethyl diphenylphosphonoacetate

A

311-46-6

ethyl 2-(dimethoxyphosphoryl)acetate

B

5927-18-4

trimethyl phosphonoacetate

C

625396-69-2

methyl methylphenylphosphonoacetate

D

625396-71-6, 852573-54-7

ethyl methylphenylphosphonoacetate

Conditions
ConditionsYield
With sodium hydroxide at 20℃; for 0.666667h;A 2%
B 13%
C 32%
D 7%
67-56-1

methanol

4408-78-0

phosphonoacetic acid

5927-18-4

trimethyl phosphonoacetate

Conditions
ConditionsYield
(i) PCl5, (ii) /BRN= 1098229/, Et3N; Multistep reaction;
67-56-1

methanol

42451-44-5

(2-chloro-2-ethoxy-vinyl)-phosphonic acid dichloride

5927-18-4

trimethyl phosphonoacetate

Conditions
ConditionsYield
In diethyl ether
96-34-4

methyl chloroacetate

868-85-9

Dimethyl phosphite

5927-18-4

trimethyl phosphonoacetate

Conditions
ConditionsYield
With potassium carbonate at 20 - 30℃;
60032-57-7

2-methylnicotinaldehyde

5927-18-4

trimethyl phosphonoacetate

137146-28-2, 137146-29-3

methyl (E)/(Z)-3-(2-methyl-3-pyridyl)propenoate

Conditions
ConditionsYield
With potassium carbonate In water for 4h; Ambient temperature;100%
497-03-0

2-methylbut-2-enal

5927-18-4

trimethyl phosphonoacetate

57258-50-1

methyl (2E,4E)-4-methyl-2,4-hexadienoate

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In benzene at 20℃; for 1.33333h;
Stage #2: 2-methylbut-2-enal In benzene for 0.5h; Heating;
100%
With sodium hydride 1.) THF, 2.) RT, 9 h; Multistep reaction;
With sodium hydride In benzene at 65℃; for 4h;37.82 g
5927-18-4

trimethyl phosphonoacetate

1,3-Diphenylpropanone

1,3-Diphenylpropanone

157731-51-6

4-Phenyl-3-(phenylmethyl)-2-butenoic acid methyl ester

Conditions
ConditionsYield
With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium In diethyl ether; hexane 1.) -20 deg C, 20 min, 2.) r.t., 50 h;100%
5927-18-4

trimethyl phosphonoacetate

123-11-5

4-methoxy-benzaldehyde

3901-07-3

3-(4-methoxy-phenyl)acrylic acid methyl ester

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Metallation;
Stage #2: 4-methoxy-benzaldehyde In tetrahydrofuran; hexane at -78 - 20℃; Condensation; Horner-Wadsworth-Emmons reaction;
100%
Stage #1: trimethyl phosphonoacetate With n-butyllithium In tetrahydrofuran at -78℃;
Stage #2: 4-methoxy-benzaldehyde In tetrahydrofuran at -78 - 20℃; Horner-Wadsworth-Emmons reaction;
In tetrahydrofuran; hexane for 1h; Horner-Wadsworth-Emmons Olefination; Cooling with ice;
98-01-1

furfural

5927-18-4

trimethyl phosphonoacetate

58293-85-9

methyl 3-(2-furyl)acrylate

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran at 0℃;100%
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran at 0℃; Metallation;
Stage #2: furfural In tetrahydrofuran for 0.166667h; Condensation;
90%
With 2,8,9-tris(2-methylpropyl)-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane In tetrahydrofuran at 20℃; for 2.2h; Inert atmosphere; optical yield given as %de; stereoselective reaction;84%
75-77-4

chloro-trimethyl-silane

5927-18-4

trimethyl phosphonoacetate

67605-34-9

methyl 2-(bis((trimethylsilyl)oxy)phosphoryl)acetate

Conditions
ConditionsYield
at 80℃; for 96h; Inert atmosphere;100%
In chlorobenzene at 130℃; for 8h;
at 80℃; for 96h; Inert atmosphere;
5927-18-4

trimethyl phosphonoacetate

178379-71-0

(1S,3aS,5S,7aR)-3a-hydroxy-5-cyclohexyl-7a-methylperhydroindene-1-carboxaldehyde

392235-25-5

methyl (1R,3aS,5S,7aR)-5-cyclohexyl-3a-hydroxy-7a-methylperhydroindene-1-yl-(E)-acrylate

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran at 0℃; for 1h;
Stage #2: (1S,3aS,5S,7aR)-3a-hydroxy-5-cyclohexyl-7a-methylperhydroindene-1-carboxaldehyde In tetrahydrofuran at 20℃; for 2h; Horner-Emmons reaction; Further stages.;
100%
3731-38-2

3-Quinuclidinone

5927-18-4

trimethyl phosphonoacetate

94764-01-9

2-(1-azabicyclo[2.2.2]oct-3-ylidene)acetic acid methyl ester

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1h; Wittig Olefination; Inert atmosphere;
Stage #2: 3-Quinuclidinone In tetrahydrofuran; mineral oil at 20℃; Wittig Olefination; Inert atmosphere;
100%
Stage #1: trimethyl phosphonoacetate With sodium In methanol at 0℃; for 1h;
Stage #2: 3-Quinuclidinone In methanol at 0℃; for 0.5h; Horner-Wadsworth-Emmons reaction;
Stage #3: In methanol at 50℃; for 18h;
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran at 0 - 20℃;
Stage #2: 3-Quinuclidinone In tetrahydrofuran at 0 - 20℃; Wadsworth-Emmons reaction;
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 1h;
Stage #2: 3-Quinuclidinone In tetrahydrofuran; mineral oil at 20℃; for 18h;
5927-18-4

trimethyl phosphonoacetate

669075-94-9

4-(2-oxo-2-quinolin-3-yl-ethyl)-piperidine-1-carboxylic acid tert-butyl ester

669075-95-0

4-(3-methoxycarbonyl-2-quinolin-3-ylallyl)piperidine-1-carboxylic acid tert-butyl ester

Conditions
ConditionsYield
With sodium hexamethyldisilazane In tetrahydrofuran for 4h; Heating;100%
498-60-2

furan-3-carboxaldehyde

5927-18-4

trimethyl phosphonoacetate

99595-62-7

Methyl 3-(3'-furanyl)prop-2-en-1-oate

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran at 0℃;100%
498-62-4

3-thiophene carboxaldehyde

5927-18-4

trimethyl phosphonoacetate

75754-85-7

3-Thiophen-3-yl-acrylic Acid Methyl Ester

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran at 0℃;100%
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran for 1h;
Stage #2: 3-thiophene carboxaldehyde In tetrahydrofuran at 20℃; for 18h;
94%
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran; mineral oil at 20℃; for 2h; Inert atmosphere;
Stage #2: 3-thiophene carboxaldehyde In tetrahydrofuran; mineral oil at 20℃; Inert atmosphere;
81%

3-(4-methoxyphenoxy)-3-perfluoropentyl-prop-2-enal

5927-18-4

trimethyl phosphonoacetate

methyl (EE)-5-(4-methoxyphenoxy)-5-perfluoropentyl-2,4-pentadienoate

Conditions
ConditionsYield
With sodium hydride In methanol at 20℃; for 2h; Wadsworth-Emmons reaction;100%
5927-18-4

trimethyl phosphonoacetate

619-66-9

4-Carboxybenzaldehyde

115974-97-5

methyl (E)-4-carboxyl cinnamate

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate; 4-Carboxybenzaldehyde With potassium carbonate In water at 0 - 20℃; for 1.5h;
Stage #2: In water pH=1; Acidic aqueous solution;
100%
With potassium carbonate In water at 0 - 20℃; pH=Ca. 2;95%
5927-18-4

trimethyl phosphonoacetate

619-21-6

m-formylphenyl benzoic acid

115974-96-4

(E)-3-(methoxy-3-oxoprop-1-en-1-yl)benzoic acid

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate; m-formylphenyl benzoic acid With potassium carbonate In water at 0 - 20℃; for 17h;
Stage #2: In water pH=1; Acidic aqueous solution;
100%
With potassium carbonate In water at 0 - 20℃; pH=Ca. 2;93%
5927-18-4

trimethyl phosphonoacetate

1134-43-6

2-ethoxy-4-nitro-benzaldehyde

863885-81-8

ethyl 4-nitro-2-ethoxycinnamate

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere;
Stage #2: 2-ethoxy-4-nitro-benzaldehyde In tetrahydrofuran at 20℃; for 4h; Wittig-Horner Reaction; Inert atmosphere;
100%
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran at 0℃;
Stage #2: 2-ethoxy-4-nitro-benzaldehyde In tetrahydrofuran at 0 - 20℃; for 15h;
99%
With sodium hydride In tetrahydrofuran at 0 - 20℃; for 15h;
5927-18-4

trimethyl phosphonoacetate

105640-07-1

4-(4-hydroxyphenyl)cyclohexan-1-one

701232-66-8

[4-(4-hydroxyphenyl)cyclohexylidene]acetic acid methyl ester

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In mineral oil at 0 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: 4-(4-hydroxyphenyl)cyclohexan-1-one In tetrahydrofuran; mineral oil at 20℃; for 0.416667h; Inert atmosphere;
100%
With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 2.83333h; Inert atmosphere;100%
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran; mineral oil at 0℃; Inert atmosphere;
Stage #2: 4-(4-hydroxyphenyl)cyclohexan-1-one In tetrahydrofuran; mineral oil at 25℃; for 5h;
97%
5927-18-4

trimethyl phosphonoacetate

171560-20-6

(2R)-2-(1,1-dimethylethoxycarbonylamino)-2-cyclohexylethanal

876761-53-4

(R)-4-tert-butoxycarbonylamino-4-cyclohexyl-but-2-enoic acid methyl ester

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran; mineral oil at 5℃; for 1h; Inert atmosphere;
Stage #2: (2R)-2-(1,1-dimethylethoxycarbonylamino)-2-cyclohexylethanal In tetrahydrofuran; mineral oil at 0 - 20℃;
100%
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran at 0 - 20℃; for 0.5h;
Stage #2: (2R)-2-(1,1-dimethylethoxycarbonylamino)-2-cyclohexylethanal In tetrahydrofuran at 0 - 20℃; for 0.333333h;
4397-53-9

p-benzyloxybenzaldehyde

5927-18-4

trimethyl phosphonoacetate

84184-51-0

(E)-methyl 3-(4-(benzyloxy)phenyl)acrylate

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran; mineral oil at 0℃;
Stage #2: p-benzyloxybenzaldehyde In tetrahydrofuran; mineral oil at 20℃;
100%
872-85-5

pyridine-4-carbaldehyde

5927-18-4

trimethyl phosphonoacetate

81124-49-4

(E)-methyl 3-(pyridine-4-yl)prop-2-enoate

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran at 0 - 20℃; for 5h;100%
918337-11-8

tert-butoxycarbonylamino-[4-(4-formylphenoxy)-phenyl]-acetic acid

5927-18-4

trimethyl phosphonoacetate

918337-12-9

3-{4-[4-(tert-butoxycarbonylaminocarboxymethyl)-phenoxy]-phenyl}-acrylic acid methyl ester

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran at 0 - 5℃; for 0.0833333h;
Stage #2: tert-butoxycarbonylamino-[4-(4-formylphenoxy)-phenyl]-acetic acid In tetrahydrofuran at 0 - 20℃; for 0.5h;
Stage #3: With hydrogenchloride; citric acid In tetrahydrofuran; water pH=~ 2;
100%
5927-18-4

trimethyl phosphonoacetate

94651-33-9

2-(trifluoromethoxy)benzaldehyde

1202578-19-5

methyl (2E)-3-[2-(trifluoromethoxy)phenyl]prop-2-enoate

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran at 0℃; Inert atmosphere;
Stage #2: 2-(trifluoromethoxy)benzaldehyde In tetrahydrofuran at 20℃; Inert atmosphere;
100%
5927-18-4

trimethyl phosphonoacetate

C13H19NO2

C16H23NO3

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran at 20℃; Horner-Wadsworth-Emmons Olefination;100%
5927-18-4

trimethyl phosphonoacetate

529-20-4

2-methylphenyl aldehyde

70625-62-6, 75950-75-3, 130451-86-4

methyl (E)-3-(2-methylphenyl)-2-propenoate

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran; paraffin oil at 0 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: 2-methylphenyl aldehyde In tetrahydrofuran; paraffin oil at -78 - 20℃; Inert atmosphere;
100%
With sodium methylate In methanol; N,N-dimethyl-formamide Wittig-Horner Reaction;
5927-18-4

trimethyl phosphonoacetate

101385-93-7

3-oxo-pyrrolidine-1-carboxylic acid tert-butyl ester

441773-67-7

tert-butyl 3-(2-methoxy-2-oxoethylidene)pyrrolidine-1-carboxylate

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 0.333333h;
Stage #2: 3-oxo-pyrrolidine-1-carboxylic acid tert-butyl ester In tetrahydrofuran; mineral oil at 0 - 20℃; for 16h;
100%
Stage #1: trimethyl phosphonoacetate With potassium tert-butylate In tetrahydrofuran at 0℃; for 2.5h;
Stage #2: 3-oxo-pyrrolidine-1-carboxylic acid tert-butyl ester In tetrahydrofuran at 0℃; for 1h;
92.8%
5927-18-4

trimethyl phosphonoacetate

620-23-5

m-tolyl aldehyde

82444-40-4, 118315-74-5, 95416-56-1

(E)-methyl 3-methylcinnamate

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran; paraffin oil at 0 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: m-tolyl aldehyde In tetrahydrofuran; paraffin oil at -78 - 20℃; Inert atmosphere;
100%
120-57-0

piperonal

5927-18-4

trimethyl phosphonoacetate

40918-96-5

methyl (2E)-3-(1,3-benzodioxol-5-yl)acrylate

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran; paraffin oil at 0 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: piperonal In tetrahydrofuran; paraffin oil at -78 - 20℃; Inert atmosphere;
100%
5927-18-4

trimethyl phosphonoacetate

104-87-0

4-methyl-benzaldehyde

20754-20-5

3-p-tolyl-acrylic acid methyl ester

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In tetrahydrofuran; paraffin oil at 0 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: 4-methyl-benzaldehyde In tetrahydrofuran; paraffin oil at -78 - 20℃; Inert atmosphere;
100%
5927-18-4

trimethyl phosphonoacetate

96964-45-3

2-(8-phenyloctyl) benzaldehyde

145950-31-8

methyl 3-<2-(8-phenyloctyl)phenyl>propenoate

Conditions
ConditionsYield
99%
5927-18-4

trimethyl phosphonoacetate

178391-54-3

(2S,3S)-3-(tert-Butyl-diphenyl-silanyl)-oxirane-2-carbaldehyde

(E)-3-[(2S,3S)-3-(tert-Butyl-diphenyl-silanyl)-oxiranyl]-acrylic acid methyl ester

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride In acetonitrile for 0.5h; Ambient temperature;99%
5927-18-4

trimethyl phosphonoacetate

15971-29-6

4-methoxy-1-naphthaldehyde

methyl-3-(4-methoxy-1-naphthyl)-E-propenoate

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 0℃; for 0.25h;
Stage #2: 4-methoxy-1-naphthaldehyde In dichloromethane at 20℃; for 36h;
99%
Stage #1: trimethyl phosphonoacetate With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 0℃; for 0.25h;
Stage #2: 4-methoxy-1-naphthaldehyde In dichloromethane at 0 - 20℃; for 36h;
99%
With sodium hydride In N,N-dimethyl-formamide at 20℃; for 2h; Horner-Wadsworth-Emmons reaction;89%
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    Trimethyl Phosphonoacetate

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    5927-18-4

    Trimethyl phosphonoacetate

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    Trimethyl phosphonoacetate

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  • Trimethyl phosphonoacetate

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    Trimethyl phosphonoacetate

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    Name Trimethyl phosphonoacetate Synonyms (Dimethoxyphosphinyl)-acetic acid methyl ester; Methyl (dimethoxyphosphoryl)acetate CAS NO. 5927-18-4 Molecular Formu

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  • TriMethyl phosphonoacetatCAS NO.:5927-18-4

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    TriMethyl phosphonoacetatCAS NO.:5927-18-4

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    Factory Supply Trimethyl phosphonoacetate

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  • Casno:

    5927-18-4

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  • Casno:

    5927-18-4

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  • Casno:

    5927-18-4

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    Business Type:Trading Company

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  • Casno:

    5927-18-4

    MSDS/COA Download

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  • Casno:

    5927-18-4

    MSDS/COA Download

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    5927-18-4

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    5927-18-4

    MSDS/COA Download

    Monad--Factory Supply Trimethyl phosphonoacetate CAS NO.5927-18-4

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  • Casno:

    5927-18-4

    Trimethyl phosphonoacetate CAS NO.5927-18-4

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    5927-18-4

    MSDS/COA Download

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    5927-18-4

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  • Casno:

    5927-18-4

    Aceticacid, 2-(dimethoxyphosphinyl)-, methyl ester

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  • Trimethyl Phosphonoacetate

  • Casno:

    5927-18-4

    Trimethyl Phosphonoacetate

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  • Casno:

    5927-18-4

    Trimethyl Phosphoroacetate

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  • Casno:

    5927-18-4

    High quality Trimethyl Phosphoroacetate?? supplier in China

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  • Casno:

    5927-18-4

    RIMETHYL PHOSPHONOACETATE

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    5927-18-4

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    Business Type:Lab/Research institutions

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    5927-18-4

    Trimethyl phosphonoacetate

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    Business Type:Lab/Research institutions

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    5927-18-4

    Trimethyl phosphonoacetate

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  • Casno:

    5927-18-4

    Trimethyl phosphonoacetate

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  • Casno:

    5927-18-4

    Trimethyl phosphonoacetate CAS 5927-18-4

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    5927-18-4

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    Siwei Development Group Ltd. is a reputed professional enterprise in China dedicated to the Amino Acids production and sales of fine chemical products.Over the years we have been m

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    5927-18-4

    Trimethyl phosphonoacetate

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    5927-18-4

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    5927-18-4

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  • Casno:

    5927-18-4

    Trimethyl phosphonoacetate

    Min.Order: 1 Gram

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Specification

The IUPAC name of Trimethylacetyl phosphate is methyl 2-dimethoxyphosphorylacetate. With the CAS registry number 5927-18-4, it is also named as Acetic acid, (dimethoxyphosphinyl)-, methyl ester; Phosphonoacetic acid trimethyl ester. The product's categories are horner-emmons reaction, synthetic organic chemistry, wittig & horner-emmons reaction, C-C bond formation, horner-wadsworth-emmons reagents and olefination. It is clear colorless to light yellow liquid. And people should not breathe the vapour of this chemical and avoid contact with skin and eyes.

The other characteristics of this product can be summarized as: (1)ACD/LogP: -0.68; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.68; (4)ACD/LogD (pH 7.4): -0.68; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 10.2; (8)ACD/KOC (pH 7.4): 10.2; (9)#H bond acceptors: 5; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 5; (12)Index of Refraction: 1.407; (13)Molar Refractivity: 37.35 cm3; (14)Molar Volume: 151.4 cm3; (15)Polarizability: 14.8×10-24 cm3; (16)Surface Tension: 34.6 dyne/cm; (17)Enthalpy of Vaporization: 55.19 kJ/mol; (18)Vapour Pressure: 0.000577 mmHg at 25°C; (19)Rotatable Bond Count: 5; (20)Exact Mass: 182.03441; (21)MonoIsotopic Mass: 182.03441; (22)Topological Polar Surface Area: 61.8; (23)Heavy Atom Count: 11.

Preparation of Trimethylacetyl phosphate: It can be obtained by bromoacetic acid methyl ester and phosphorous acid trimethyl ester. The reaction temperature is 100 °C and the reaction time is 12 hours. The yield is 74%.

Uses of Trimethylacetyl phosphate: It is an important Wittig-horner reagent and it is also used as an important intermediate in the manufacture of vitamin compounds, drugs, insect pheromones and other natural compounds. It is also can be used in many organic synthesis. For example: It reacts with cyclohexanone to get cyclohexylidene-acetic acid methyl ester. This reaction needs reagent NaH and solvent tetrahydrofuran.

People can use the following data to convert to the molecule structure.
1. SMILES: O=C(OC)CP(=O)(OC)OC;
2. InChI: InChI=1/C5H11O5P/c1-8-5(6)4-11(7,9-2)10-3/h4H2,1-3H3.