CAS No.60-51-5,Dimethoate Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	60-51-5
Name:	Dimethoate

Formula:	C₅H₁₂NO₃PS₂
Molecular Weight:	229.261
Synonyms:	Cygon;Fosfotox;Dimevur;Perfekthion;Tara 909;BI 58;Daphene;Phosphorodithioic acid,esters,O,O-dimethyl S-[2-(methylamino)-2-oxoethyl] ester;Salut;Phosphamide;Roxion;Systoate;Technical Dimethoate 98PCT;Racusan;2-dimethoxyphosphinothioylsulfanyl-N-methyl-acetamide;PEI 75;Sinoratox;Rogor;Systemin (pesticide);L-395;AC-12682;EI-12880;BI-58;ENT 24,650;
EINECS:	200-480-3
Density:	1.304 g/cm³
Melting Point:	52-52.5 °C
Boiling Point:	107 °C (0.05 torr)
Flash Point:	107 °C
Solubility:	2.5 g/100 mL in water
Appearance:	white crystalline solid
Hazard Symbols:	Xn, T, F
Risk Codes:	21/22-63-43-36/37/38-23/24/25-45-36-20/21/22-11
Safety:	2-36/37-24/25-23-53-26
Transport Information:	UN 2783
PSA:	114.76000
LogP:	2.02440

Synthetic route

: 96-30-0
chloroacetylmethylamide

: 16001-68-6
potassium O,O-dimethyldithiophosphate

: 60-51-5
Dimethoate

Conditions

Conditions	Yield
With acetone

: 34680-81-4
2-bromo-N-methylacetamide

: 16001-68-6
potassium O,O-dimethyldithiophosphate

: 60-51-5
Dimethoate

Conditions

Conditions	Yield
With acetone

: 757-86-8
O,O-Dimethyl-S-(methoxycarbonylmethyl)-dithiophosphat

: 74-89-5
methylamine

A: 67-56-1
methanol

B: 60-51-5
Dimethoate

C: 125403-49-8
(Mercapto-methoxy-phosphorylsulfanyl)-acetic acid methyl ester; compound with dimethyl-amine

D: 16284-76-7
Dithiophosphoric acid O-methyl ester S-methylcarbamoylmethyl ester; compound with dimethyl-amine

Conditions

Conditions	Yield
In water Kinetics; Rate constant;

...Expand

: 757-86-8
O,O-Dimethyl-S-(methoxycarbonylmethyl)-dithiophosphat

: 74-89-5
methylamine

A: 60-51-5
Dimethoate

B: 16284-76-7
Dimethylammonium-O-methyl-S-(N-methylcarbamoylmethyl)-dithiophosphat

C: 125403-49-8
Dimethylammonium-O-methyl-S-(methoxycarbonylmethyl)-dithiophosphat

Conditions

Conditions	Yield
In methanol; water at 10℃; Rate constant; Kinetics; Thermodynamic data; other temperatures ( 298 K); the influence of the solvent polarity, ΔH(excit.), ΔS(excit.), ΔG(excit.);

...Expand

: 74-89-5
methylamine

dimethoxythiophosphorylsulfanyl-acetic acid phenyl ester: dimethoxythiophosphorylsulfanyl-acetic acid phenyl ester

: 60-51-5
Dimethoate

Conditions

Conditions	Yield
With n-hexan-2-one
With n-hexan-2-one

: 2234-97-1
tris-n-propylphosphine

: 60-51-5
Dimethoate

: 7237-27-6
C10H24P(1+)*C4H9NO3PS2(1-)

: 998-40-3
tributylphosphine

: 60-51-5
Dimethoate

: 7237-32-3
C13H30P(1+)*C4H9NO3PS2(1-)

: 124-28-7
N,N-dimethyl-n-octadecylamine

: 60-51-5
Dimethoate

: 101943-42-4
Trimethyl-octadecyl-ammonium-O-methyl-S-methylcarbamoylmethyl-dithiophosphat

Conditions

Conditions	Yield
In Petroleum ether

: 4253-76-3
N-octadecyl-propane-1,3-diamine

: 60-51-5
Dimethoate

: 4221-19-6
N-Methyl-N'-octadecyl-trimethylendiammonium-O-methyl-S-methylcarbamoylmethyl-dithiophosphat

Conditions

Conditions	Yield
In benzene

: 4253-76-3
N-octadecyl-propane-1,3-diamine

: 60-51-5
Dimethoate

: 96591-11-6
N,N'-Dimethyl-N-octadecyl-trimethylendiammonium-bis-(O-methyl-S-methylcarbamoylmethyl)-dithiophosphat

Conditions

Conditions	Yield
In benzene

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Chemistry

Product Name: O,O-dimethyl S-[2-(methylamino)-2-oxoethyl] phosphorodithioate (CAS NO.60-51-5)
IUPAC Name: 2-dimethoxyphosphinothioylsulfanyl-N-methylacetamide
Molecular Formula: C₅H₁₂NO₃PS₂

Molecular Weight: 229.26
EINECS: 200-480-3
Melting point: 52-52.5°C
Boiling point: 107°C (0.05 torr)
Density: 1.281
Flash point: 107 °C
Storage temp.: 0-6°C
Water Solubility: Slightly soluble. 2.5 g/100 mL
Merck: 13,3246
Index of Refraction: 1.532
Molar Refractivity: 54.45 cm³
Molar Volume: 175.7 cm³

Uses

O,O-dimethyl S-[2-(methylamino)-2-oxoethyl] phosphorodithioate (CAS NO.60-51-5) is inside-absorption contact pesticides,it can be used to kill a variety of crop pests such as most of insect pests and mites,and it is particularly effective for the health pests.

Toxicity Data With Reference

1.	mma-sat 500 µg/plate	JTEHD6 Journal of Toxicology and Environmental Health. 16 (1985),403.
2.	mma-hmn:fbr 100 µmol/L	MUREAV Mutation Research. 42 (1977),161.
3.	sce-hmn:lym 20 mg/L	MUREAV Mutation Research. 88 (1981),307.
4.	orl-man TDLo:286 mg/kg:PNS,BAH	ICMED9 Intensive Care Medicine. 12 (1986),110.
5.	orl-hmn LD50:30 mg/kg	GUCHAZ Guide to the Chemicals Used in Crop Protection 6 (1973),209.
6.	orl-man TDLo:300 mg/kg	JTCTDW Journal of Toxicology, Clinical Toxicology. 24 (1986),69.
7.	orl-rat LD50:60 mg/kg	YKYUA6 Yakkyoku. Pharmacy. 30 (1979),623.
8.	skn-rat LD50:353 mg/kg	BJIMAG British Journal of Industrial Medicine. 26 (1969),59.
9.	ipr-rat LD50:100 mg/kg	BJIMAG British Journal of Industrial Medicine. 21 (1964),52.
10.	scu-rat LD50:350 mg/kg	BJIMAG British Journal of Industrial Medicine. 21 (1964),52.

Consensus Reports

NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-4 ,1977. . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. EPA Extremely Hazardous Substances List.

Safety Profile

A deadly human poison. Poison by ingestion, skin contact, intraperitoneal, and subcutaneous routes. Moderately toxic by intravenous route. Human systemic effects: coma, dyspnea, fasciculations. Questionable carcinogen with experimental carcinogenic data. Experimental teratogenic and reproductive effects. Human mutation data reported. When heated to decomposition it emits very toxic fumes of NO_x, PO_x, and SO_x.
Hazard Codes: Xn Harmful ,T Toxic ,F Flammable
Risk Statements: 21/22-63-43-36/37/38-23/24/25-45-36-20/21/22-11
R20/21:Harmful by inhalation and in contact with skin.
R63:Possible risk of harm to the unborn child.
R43:May cause sensitization by skin contact.
R36/37/38:Irritating to eyes, respiratory system and skin.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R45:May cause cancer.
R36:Irritating to eyes.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
R11:Highly flammable.
Safety Statements: 2-36/37-24/25-23-53-26
S36/37:Wear suitable protective clothing and gloves.
S24/25:Avoid contact with skin and eyes.
S23:Do not breathe vapour.
S53:Avoid exposure - obtain special instructions before use.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RIDADR: UN 2783
HazardClass: 6.1(b)
PackingGroup: III

Specification

O,O-dimethyl S-[2-(methylamino)-2-oxoethyl] phosphorodithioate (CAS NO.60-51-5) has some synonyms like Dimethoate ; EL 12880 ; Defend ; Fosfamid; Perfekthion ; Rebelate ; Rogor ; Roxion ,and so on.