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CAS No.: | 60099-09-4 |
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Name: | Benzyl formimidate-hydrochloride |
Article Data: | 2 |
Molecular Structure: | |
Formula: | C8H9NO.ClH |
Molecular Weight: | 171.626 |
Synonyms: | formimidic acid benzyl ester,hydrochloride;methanimidic acid phenylmethyl ester hydrochloride;3-Benzyloxypropanol;3-Benzyloxy-1-propanol;O-benzyl 1,3-propylene glycol;benzyloxyformimidate hydrochloride;3-benzyloxy-l-propanol;O-benzyl formimidate hydrochloride;monobenzylated 1,3-propanediol;benzylformimidate hydrochloride;Formimidsaeure-benzylester,Hydrochlorid;Propane-1,3 diol mono-benzyl ether; |
PSA: | 33.08000 |
LogP: | 2.71200 |
hydrogen cyanide
benzyl alcohol
methanimidic acid phenylmethyl ester hydrochloride
Conditions | Yield |
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With hydrogenchloride; diethyl ether |
benzoyl chloride
methanimidic acid phenylmethyl ester hydrochloride
Conditions | Yield |
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With acetic anhydride; formamide; benzyl alcohol In potassium hydroxide | 130 g (67%) |
methanimidic acid phenylmethyl ester hydrochloride
(6S)-<(1R)-hydroxyethyl>-2-(cis-3-aminocyclopentylthio)-(5R)-carbapen-2-em-3-carboxylic acid
(6S)-<(1R)-hydroxyethyl>-2-(cis-3-formimidoylaminocyclopentylthio)-(5R)-carbapen-2-em-3-carboxylic acid
Conditions | Yield |
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With potassium hydroxide In water at 0 - 5℃; for 0.25h; | 93% |
Conditions | Yield |
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With N-ethyl-N,N-diisopropylamine In methanol; dichloromethane at -25℃; Large scale; | 85% |
methanimidic acid phenylmethyl ester hydrochloride
(6S)-<(1R)-hydroxyethyl>-2-(cis-3-aminocyclohexylthio)-(5R)-carbapen-2-em-3-carboxylic acid
(6S)-<(1R)-hydroxyethyl>-2-(cis-4-formimidoylaminocyclohexylthio)-(5R)-carbapen-2-em-3-carboxylic acid
Conditions | Yield |
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With potassium hydroxide In water at 0 - 5℃; for 0.25h; | 82% |
methanimidic acid phenylmethyl ester hydrochloride
1,2',6'-tri-N-benzyloxycarbonylistamycin A trifluoroacetat
1,2',6'-tri-N-benzyloxycarbonyl-2''-N-formimidoylistamycin A hydrochloride
Conditions | Yield |
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In methanol for 1h; | 54% |
methanimidic acid phenylmethyl ester hydrochloride
(1S,5S,8aS,8bR)-1-((R)-1-Hydroxy-ethyl)-5-methylamino-2-oxo-1,2,5,6,7,8,8a,8b-octahydro-azeto[2,1-a]isoindole-4-carboxylic acid
Conditions | Yield |
---|---|
With IRA68 resin In water; acetonitrile at 0℃; Substitution; | 42% |
In phosphate buffer pH=8; Substitution; |
methanimidic acid phenylmethyl ester hydrochloride
1,3,5-Triazine
Conditions | Yield |
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With N,N-diethylaniline under 12 Torr; |
methanimidic acid phenylmethyl ester hydrochloride
Cysteamine
A
4,5-dihydro-thiazole
B
1,3,5-Triazine
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In acetonitrile | |
With N-ethyl-N,N-diisopropylamine In acetonitrile | |
With N-ethyl-N,N-diisopropylamine In acetonitrile Mechanism; |
methanimidic acid phenylmethyl ester hydrochloride
N,N-bis(trimethylsilyl)acetamide
C11H17NOSi
Conditions | Yield |
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Yield given; |