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Basic Information
CAS No.: 6032-29-7
Name: 2-Pentanol
Article Data: 296
Molecular Structure:
Molecular Structure of 6032-29-7 (2-Pentanol)
Formula: C5H12O
Molecular Weight: 88.1497
Synonyms: 1-Methyl-1-butanol;1-Methylbutanol;2-Hydroxypentane;2-Pentyl alcohol;DL-2-Pentanol;Methylpropylcarbinol;sec-Amyl alcohol;sec-Pentyl alcohol;
EINECS: 227-907-6
Density: 0.809 g/cm3
Melting Point: -50 °C
Boiling Point: 118.8 °C at 760 mmHg
Flash Point: 33.9 °C
Solubility: 16.6 g/ 100 mL (20 °C ) in water
Appearance: clear colourless liquid
Hazard Symbols: HarmfulXn
Risk Codes: 10-20-37-66
Safety: 46
Transport Information: UN 1105 3/PG 3
PSA: 20.23000
LogP: 1.16730
Synthetic route
107-87-9

2-Pentanone

6032-29-7

(+/-)-2-pentanol

Conditions
ConditionsYield
With sodium isopropylate; acetonitrile In isopropyl alcohol at 80℃; for 1h; Catalytic behavior;99%
With formic acid; sodium formate; (η5-C4Ph4COHOC4Ph4-η5)(μ-H)(CO)4Ru2 In water at 100℃; for 3h;98%
With C40H37ClN2PRuS(1+)*C24H20B(1-); isopropyl alcohol; potassium hydroxide at 82℃; for 2h; Catalytic behavior;97.7%

A

6032-29-7

(+/-)-2-pentanol

B

24652-50-4

(Z)-pent-3-en-2-ol

Conditions
ConditionsYield
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics;A n/a
B 99%
98-01-1

furfural

A

534-22-5

2-methylfuran

B

6032-29-7

(+/-)-2-pentanol

C

71-41-0

pentan-1-ol

D

107-87-9

2-Pentanone

Conditions
ConditionsYield
With Cu/SiO2; hydrogen at 220℃; under 760.051 Torr; for 0.5h; Catalytic behavior; Reagent/catalyst; Time; Temperature; Green chemistry;A 89.5%
B n/a
C n/a
D n/a
98-01-1

furfural

A

96-47-9

2-methyltetrahydrofuran

B

534-22-5

2-methylfuran

C

6032-29-7

(+/-)-2-pentanol

D

107-87-9

2-Pentanone

Conditions
ConditionsYield
With hydrogen; Cu-based catalyst at 212℃; Product distribution; Further Variations:; Temperatures; reaction in vapour phase, fixed bed reactor;A 3.3%
B 88.6%
C 4.8%
D 2.7%

C26H30O3

6032-29-7

(+/-)-2-pentanol

Conditions
ConditionsYield
With cerium(IV) triflate; water In acetonitrile at 25℃; for 1.25h;88%

C13H27BO

6032-29-7

(+/-)-2-pentanol

Conditions
ConditionsYield
With sodium hydroxide In water Inert atmosphere;87%
107-87-9

2-Pentanone

68-12-2, 33513-42-7

N,N-dimethyl-formamide

A

6032-29-7

(+/-)-2-pentanol

B

57303-85-2

dimethyl-(1-methyl-butyl)-amine

Conditions
ConditionsYield
With sodium dithionite; sodium hydrogencarbonate In water for 4h; Product distribution; Heating; also also ketones investigated;A 85%
B 13%
98-00-0

(2-furyl)methyl alcohol

A

534-22-5

2-methylfuran

B

6032-29-7

(+/-)-2-pentanol

Conditions
ConditionsYield
With hydrogen In 1,2-dichloro-ethane at 25℃; under 2250.23 Torr; for 2h; Reagent/catalyst; Time; Sealed tube; Green chemistry;A 85%
B 15%

C24H26O

6032-29-7

(+/-)-2-pentanol

Conditions
ConditionsYield
With cerium(IV) triflate; water In acetonitrile at 25℃; for 2.83333h;82%
Conditions
ConditionsYield
With samarium diiodide; water In tetrahydrofuran at 20℃; for 0.141667h;A 78%
B 6%
C 6%
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Chemistry

IUPAC Name: 2-Pentanol
The MF of 2-Pentanol (6032-29-7) is C5H12O.

                     
The MW of 2-Pentanol (6032-29-7) is 88.15.
Synonyms of 2-Pentanol (6032-29-7): (RS)-2-Pentanol ; 1-Methylbutanol ; 2-Hydroxypentane ; 2-Pentyl alcohol ; Alcoold’amylesecondaire ; Isoamyl alcohol, secondary ; Isoamylalcohol(secondary) ; Isoamylalcohol,secondary
Product Categories: alcohol Flavor
Form: clear colourless liquid
Index of Refraction: 1.405  
EINECS: 227-907-6
Density: 0.809 g/ml 
Flash Point: 33.9 °C 
Boiling Point: 118.8 °C
Melting Point: -50 °C
Storage temp: Flammables area
Water Solubility: 16.6 g/100 mL (20 ºC)
Merck: 14,7119
BRN: 1718819
FEMA: 3316

Uses

  2-Pentanol (6032-29-7) is used as allowing the use of food with spices, organic synthesis of raw materials and solvents, chromatographic analysis reagent and cotton plastic paint solvent.

Toxicity Data With Reference

1.    

skn-rbt 500 mg/24H MOD

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,36.
2.    

eye-rbt 20 mg/24H SEV

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,36.
3.    

ipr-rat LDLo:2130 mg/kg

    JIHTAB    Journal of Industrial Hygiene and Toxicology. 27 (1945),1.
4.    

orl-rbt LD50:2821 mg/kg

    IMSUAI    Industrial Medicine and Surgery. 41 (1972),31.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. A narcotic. A skin and severe eye irritant. Flammable liquid when exposed to heat or flame; can react with oxidizing materials. A severe explosion hazard when exposed to heat or flame. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALCOHOL, DENATURED; ALCOHOLS, C6-12; ALCOHOLS, C9-11; ALCOHOLS, C12-13, ETHOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED; ALCOHOLS, C12-16, ETHOXYLATED; ALCOHOLS, C14-15, ETHOXYLATED; ALCOHOLS, C16-18, ETHOXYLATED; ALCOHOLS, C8-10, ETHOXYLATED PROPOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED PROPOXYLATED; ALCOHOLS, N.O.S.
Safety information of 2-Pentanol (6032-29-7):
Hazard Codes  Xn
Risk Statements 
10  Flammable
20  Harmful by inhalation
37  Irritating to the respiratory system
66  Repeated exposure may cause skin dryness or cracking
Safety Statements 
46  If swallowed, seek medical advice immediately and show this container or label
RIDADR  UN 1105 3/PG 3
WGK Germany  1
RTECS  SA4900000
HazardClass  3
PackingGroup  III
HS Code  29051500

Standards and Recommendations

OSHA PEL: TWA 100 ppm (360 mg/m3); STEL 125 ppm (450 mg/m3)
NIOSH REL: (Isoamyl Alcohol, sec-): TWA 100 ppm; STEL 125 ppm