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| CAS No.: | 6046-93-1 |
|---|---|
| Name: | Cupric acetate monohydrate |
| Article Data: | 33 |
| Cas Database | |
| Molecular Structure: | |
|
|
|
| Formula: | Cu(C2H4O2)2.H2O |
| Molecular Weight: | 199.651 |
| Synonyms: | Copper(2+) acetate monohydrate;Copper(II) acetatemonohydrate;copper(2+) acetate hydrate (1:2:1);acetic acid, copper(2+) salt, hydrate (2:1:1); |
| EINECS: | 205-553-3 |
| Density: | 1.882 |
| Melting Point: | 115 °C |
| Boiling Point: | 117.1 °C at 760 mmHg |
| Flash Point: | 40 °C |
| Solubility: | 7.2 g/100 mL in cold water, 20 g / 100 mL in hot water, Soluble in alcohol, Slightly soluble in ether and glycerol |
| Appearance: | Dark green small crystal with odour of acetic acid |
| Hazard Symbols: |
 Xn;  N;  Xi
|
| Risk Codes: | 22-36/37/38-50/53 |
| Safety: | 36/37/39-60-61-36-26 |
| Transport Information: | UN 9106/3077 |
| PSA: | 89.49000 |
| LogP: | -2.55440 |
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| Conditions | Yield |
|---|---|
| In not given Electrolysis; 20% sodium acetate soln.; Cu anode;; | 96.3% |
| In not given Electrolysis; 20% sodium acetate soln.; Cu electrodes; 2-8V; 50-100°C;; | |
| In not given Electrolysis; 20% sodium acetate soln.; Cu electrodes; 2-8V; 50-100°C;; |
| Conditions | Yield |
|---|---|
| With acetic acid; sodium chloride Electrolysis; |
| Conditions | Yield |
|---|---|
| With copper(I) sulfate; copper(II) sulfate |
| Conditions | Yield |
|---|---|
| With basic verdigris |
| Conditions | Yield |
|---|---|
| With air |
| Conditions | Yield |
|---|---|
| In water Cu(OH)2 treated with aq. soln. of acetic acid; |
| Conditions | Yield |
|---|---|
| In acetic acid 2h; excess of concd. acetic acid;; | |
| In acetic acid 2h; excess of concd. acetic acid;; |
| Conditions | Yield |
|---|---|
| in the warm;; | |
| in the warm;; |
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Copper and its compounds are on the Community Right-To-Know List.
Specification
The Copper(II) Acetate Monohydrate, with the CAS registry number 6046-93-1 and EINECS registry number 205-553-3, has the systematic name of copper(2+) acetate hydrate (1:2:1). It is a kind of dark green small crystal with odour of acetic acid, and incompatible with oxidizing agents. And the molecular formula of the chemical is Cu(C2H4O2)2.H2O. What's more, it is usually used in the field of Pharmaceutical and printing & dyeing. It is also used as analytical reagent and catalyst in the organic synthesis.
The physical properties of Copper(II) Acetate Monohydrate are as followings: (1)ACD/LogP: -0.29; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -1.07; (4)ACD/LogD (pH 7.4): -2.86; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 2.73; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 37.3 Å2; (13)Flash Point: 40 °C; (14)Enthalpy of Vaporization: 23.7 kJ/mol; (15)Boiling Point: 117.1 °C at 760 mmHg; (16)Vapour Pressure: 13.9 mmHg at 25°C.
Preparation and uses of Copper(II) Acetate Monohydrate: Dissolve copper sulphate with hot water, and add sodium carbonate solution, and the production is copper carbonate precipitation. Dissolve the precipitation with acetic acid, and after a series of evaporation, concentration, washing and drying, you can get the product.
You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin. It is toxic to aquatic organisms, and may cause long-term adverse effects in the aquatic environment. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; This material and/or its container must be disposed of as hazardous waste; Avoid release to the environment. Refer to special instructions safety data sheet.
You can still convert the following datas into molecular structure:
(1)SMILES: [Cu+2].[O-]C(=O)C.[O-]C(=O)C.O
(2)InChI: InChI=1/2C2H4O2.Cu.H2O/c2*1-2(3)4;;/h2*1H3,(H,3,4);;1H2/q;;+2;/p-2
(3)InChIKey: NWFNSTOSIVLCJA-NUQVWONBAK
The toxicity data is as follows:
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mammal (species unspecified) | LD50 | intraperitoneal | 5mg/kg (5mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS GASTROINTESTINAL: NAUSEA OR VOMITING | Journal of Animal Science. Vol. 55, Pg. 337, 1982. |
| mouse | LDLo | oral | 1600mg/kg (1600mg/kg) | Archives of Environmental Contamination and Toxicology. Vol. 14, Pg. 111, 1985. | |
| rat | LD50 | oral | 710mg/kg (710mg/kg) | American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969. |