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6046-93-1

Basic Information
CAS No.: 6046-93-1
Name: Cupric acetate monohydrate
Article Data: 33
Molecular Structure:
Molecular Structure of 6046-93-1 (Cupric acetate monohydrate)
Formula: Cu(C2H4O2)2.H2O
Molecular Weight: 199.651
Synonyms: Copper(2+) acetate monohydrate;Copper(II) acetatemonohydrate;copper(2+) acetate hydrate (1:2:1);acetic acid, copper(2+) salt, hydrate (2:1:1);
EINECS: 205-553-3
Density: 1.882
Melting Point: 115 °C
Boiling Point: 117.1 °C at 760 mmHg
Flash Point: 40 °C
Solubility: 7.2 g/100 mL in cold water, 20 g / 100 mL in hot water, Soluble in alcohol, Slightly soluble in ether and glycerol
Appearance: Dark green small crystal with odour of acetic acid
Hazard Symbols: HarmfulXn; DangerousN; IrritantXi
Risk Codes: 22-36/37/38-50/53
Safety: 36/37/39-60-61-36-26
Transport Information: UN 9106/3077
PSA: 89.49000
LogP: -2.55440
Synthetic route
Conditions
ConditionsYield
In not given Electrolysis; 20% sodium acetate soln.; Cu anode;;96.3%
In not given Electrolysis; 20% sodium acetate soln.; Cu electrodes; 2-8V; 50-100°C;;
In not given Electrolysis; 20% sodium acetate soln.; Cu electrodes; 2-8V; 50-100°C;;
127-09-3

sodium acetate

6046-93-1

copper(II) acetate monohydrate

Conditions
ConditionsYield
With acetic acid; sodium chloride Electrolysis;
62-54-4

calcium acetate

6046-93-1

copper(II) acetate monohydrate

Conditions
ConditionsYield
With copper(I) sulfate; copper(II) sulfate
64-19-7

acetic acid

6046-93-1

copper(II) acetate monohydrate

Conditions
ConditionsYield
With basic verdigris
64-19-7

acetic acid

6046-93-1

copper(II) acetate monohydrate

acetic acid

acetic acid

copper turnings

copper turnings

6046-93-1

copper(II) acetate monohydrate

Conditions
ConditionsYield
With air
water

water

20427-59-2

copper hydroxide

64-19-7

acetic acid

6046-93-1

copper(II) acetate monohydrate

Conditions
ConditionsYield
In water Cu(OH)2 treated with aq. soln. of acetic acid;
64-19-7

acetic acid

copper(II) oxide

6046-93-1

copper(II) acetate monohydrate

Conditions
ConditionsYield
In acetic acid 2h; excess of concd. acetic acid;;
In acetic acid 2h; excess of concd. acetic acid;;
141-78-6

ethyl acetate

copper(II) oxide

6046-93-1

copper(II) acetate monohydrate

Conditions
ConditionsYield
in the warm;;
in the warm;;
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  • Cupric acetate monohydrate CAS No.6046-93-1

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Consensus Reports

Copper and its compounds are on the Community Right-To-Know List.

Specification

The Copper(II) Acetate Monohydrate, with the CAS registry number 6046-93-1 and EINECS registry number 205-553-3, has the systematic name of copper(2+) acetate hydrate (1:2:1). It is a kind of dark green small crystal with odour of acetic acid, and incompatible with oxidizing agents. And the molecular formula of the chemical is Cu(C2H4O2)2.H2O. What's more, it is usually used in the field of Pharmaceutical and printing & dyeing. It is also used as analytical reagent and catalyst in the organic synthesis.

The physical properties of Copper(II) Acetate Monohydrate are as followings: (1)ACD/LogP: -0.29; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -1.07; (4)ACD/LogD (pH 7.4): -2.86; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 2.73; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 37.3 Å2; (13)Flash Point: 40 °C; (14)Enthalpy of Vaporization: 23.7 kJ/mol; (15)Boiling Point: 117.1 °C at 760 mmHg; (16)Vapour Pressure: 13.9 mmHg at 25°C.

Preparation and uses of Copper(II) Acetate Monohydrate: Dissolve  copper sulphate with hot water, and add sodium carbonate solution, and the production is copper carbonate precipitation. Dissolve the precipitation with acetic acid, and after a series of evaporation, concentration, washing and drying, you can get the product.  

You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin. It is toxic to aquatic organisms, and may cause long-term adverse effects in the aquatic environment. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; This material and/or its container must be disposed of as hazardous waste; Avoid release to the environment. Refer to special instructions safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: [Cu+2].[O-]C(=O)C.[O-]C(=O)C.O
(2)InChI: InChI=1/2C2H4O2.Cu.H2O/c2*1-2(3)4;;/h2*1H3,(H,3,4);;1H2/q;;+2;/p-2
(3)InChIKey: NWFNSTOSIVLCJA-NUQVWONBAK

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mammal (species unspecified) LD50 intraperitoneal 5mg/kg (5mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS

GASTROINTESTINAL: NAUSEA OR VOMITING
Journal of Animal Science. Vol. 55, Pg. 337, 1982.
mouse LDLo oral 1600mg/kg (1600mg/kg)   Archives of Environmental Contamination and Toxicology. Vol. 14, Pg. 111, 1985.
rat LD50 oral 710mg/kg (710mg/kg)   American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.