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| CAS No.: | 6065-63-0 | |
|---|---|---|
| Name: | Diethyl dipropylmalonate | |
| Article Data: | 13 | |
| Molecular Structure: | ||
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| Formula: | C13H24 O4 | |
| Molecular Weight: | 244.331 | |
| Synonyms: | Malonicacid, dipropyl-, diethyl ester (7CI,8CI); Propanedioic acid, dipropyl-, diethylester (9CI); Diethyl 2,2-dipropylmalonate; Diethyl dipropylmalonate; NSC 163902 | |
| EINECS: | 227-998-2 | |
| Density: | 0.976 g/cm3 | |
| Boiling Point: | 262.9 °C at 760 mmHg | |
| Flash Point: | STABILITY | |
| Solubility: | Clear liquid | |
| Hazard Symbols: | UN NO. | |
| Transport Information: | 200kgs | |
| PSA: | 52.60000 | |
| LogP: | 2.69920 | |
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| Conditions | Yield |
|---|---|
| With 6C53H32O8(4-)*13Zr(4+)*18O(2-)*8Co(2+)*8H(1-); hydrogen In tetrahydrofuran at 23℃; under 30003 Torr; for 36h; Catalytic behavior; Mechanism; Reagent/catalyst; | 100% |
| With sodium tetrahydroborate; ruthenium trichloride In tetrahydrofuran; water at 20℃; for 1h; | 93% |
| With 6C53H32O8(4-)*13Zr(4+)*18O(2-)*8Co(2+)*8Cl(1-); hydrogen; sodium triethylborohydride In tetrahydrofuran at 23℃; under 30402 Torr; for 36h; Catalytic behavior; Time; Glovebox; Inert atmosphere; | 100 %Spectr. |
| With fac-[Mn(1,2-bis(di-isopropylphosphino)ethane)(CO)3(CH2CH2CH3)]; hydrogen In diethyl ether at 25℃; under 37503.8 Torr; for 18h; | 75 %Chromat. |
| With hydrogen In water at 60℃; under 22502.3 Torr; for 18h; Autoclave; Green chemistry; |
- 1439866-82-6
diethyl 2-(3-iodopropyl)-2-propylmalonate
- 6065-63-0
2,2-dipropyl-malonic acid diethyl ester
| Conditions | Yield |
|---|---|
| With [Ir(2-phenylpyridine)-2-(4,4’-di-tert-butyl-2,2’-bipyridine)]PF6; N-ethyl-N,N-diisopropylamine In acetonitrile at 25℃; for 5h; Irradiation; | 88% |
- 106-94-5
propyl bromide
- 2163-48-6
diethyl propylmalonate
- 6065-63-0
2,2-dipropyl-malonic acid diethyl ester
| Conditions | Yield |
|---|---|
| With sodium ethanolate In ethanol for 10h; Heating; | 83% |
- 107-08-4
1-iodo-propane
- 2163-48-6
diethyl propylmalonate
- 6065-63-0
2,2-dipropyl-malonic acid diethyl ester
| Conditions | Yield |
|---|---|
| With caesium carbonate In butanone at 70℃; for 15h; | 70% |
- 106-94-5
propyl bromide
- 105-53-3
diethyl malonate
A
- 6065-63-0
2,2-dipropyl-malonic acid diethyl ester
B
- 616-62-6
n-propylmalonic acid
| Conditions | Yield |
|---|---|
| With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride for 16h; | A 48% B 41% |
| Conditions | Yield |
|---|---|
| With zinc |
- 107-08-4
1-iodo-propane
- 105-53-3
diethyl malonate
A
- 6065-63-0
2,2-dipropyl-malonic acid diethyl ester
B
- 2163-48-6
diethyl propylmalonate
| Conditions | Yield |
|---|---|
| With zinc |
- 107-08-4
1-iodo-propane
- 105-53-3
diethyl malonate
A
- 6065-63-0
2,2-dipropyl-malonic acid diethyl ester
B
- 2163-48-6
diethyl propylmalonate
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 93 percent / NaOEt / ethanol / 7 h / Heating 2: 83 percent / NaOEt / ethanol / 10 h / Heating View Scheme |
- 101268-55-7
4,4-bis(ethoxycarbonyl)-1-hepten-6-yne
A
- 6065-63-0
2,2-dipropyl-malonic acid diethyl ester
B
- 1114376-78-1
diethyl cis-3,4-dimethylcyclopentane-1,1-dicarboxylate
| Conditions | Yield |
|---|---|
| With (IPr2,6-(2,6-iPr2C6H3N=CMe)2C5H3N)Fe(N2)2; hydrogen In benzene at 23℃; under 3040.2 Torr; for 3h; Inert atmosphere; optical yield given as %de; | A 25.9 %Chromat. B n/a C n/a |
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Chemistry
Molecular Structure:
Molecular Formula: C13H24O4
Molecular Weight: 244.3273
IUPAC Name: Diethyl 2,2-dipropylpropanedioate
Synonyms of Propanedioic acid,2,2-dipropyl-, 1,3-diethyl ester (CAS NO.6065-63-0): EINECS 227-998-2 ; Diethyl dipropylmalonate
CAS NO: 6065-63-0
Classification Code: Pharmaceutical Intermediates ; TheMalonateRamificationProducts
Index of Refraction: 1.438
Molar Refractivity: 65.79 cm3
Molar Volume: 250.1 cm3
Surface Tension: 31.7 dyne/cm
ensity: 0.976 g/cm3
Flash Point: 113.7 °C
Enthalpy of Vaporization: 50.07 kJ/mol
Boiling Point: 262.9 °C at 760 mmHg
Vapour Pressure: 0.0106 mmHg at 25°C
Uses
Propanedioic acid,2,2-dipropyl-, 1,3-diethyl ester (CAS NO.6065-63-0) is used as a raw material for medicine and pesticide intermediates.
Safety Profile
Safety Statements of Propanedioic acid,2,2-dipropyl-, 1,3-diethyl ester (CAS NO.6065-63-0): 24/25
S24/25: Avoid contact with skin and eyes.