Products Categories
CAS No.: | 617-86-7 |
---|---|
Name: | Triethylsilane |
Article Data: | 105 |
Molecular Structure: | |
Formula: | C6H16Si |
Molecular Weight: | 116.279 |
Synonyms: | Triethylsilyl hydride; |
EINECS: | 210-535-3 |
Density: | 0.728g/mLat 25°C(lit.) |
Melting Point: | -157 °C |
Boiling Point: | 107.499 °C at 760 mmHg |
Flash Point: | 25°F |
Solubility: | Miscible with water. |
Appearance: | Clear liquid |
Hazard Symbols: | F, Xi |
Risk Codes: | 11-36/37/38 |
Safety: | 9-16-29-33-37/39-26 |
Transport Information: | UN 1993 3/PG 2 |
PSA: | 0.00000 |
LogP: | 2.27320 |
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; ethyl bromide; tetraoctyl ammonium bromide In benzene-d6 at 20℃; for 24h; Reagent/catalyst; Solvent; | 96% |
3-(trimethylsilyl)propane-1-thiol
bis(triethylsilyl)mercury
A
triethylsilane
Conditions | Yield |
---|---|
In benzene Heating; | A n/a B 89.5% |
Conditions | Yield |
---|---|
With sodium tetrahydroborate In acetonitrile at 20℃; for 0.25h; Inert atmosphere; | 88% |
With lithium hydride In tetrahydrofuran at 20 - 60℃; Reagent/catalyst; Solvent; | 82% |
Stage #1: triethylsilyl chloride With magnesium In tetrahydrofuran at 75℃; for 12h; Inert atmosphere; Stage #2: Acidic conditions; | 80% |
Conditions | Yield |
---|---|
In benzene Heating; | A n/a B 87.3% |
Conditions | Yield |
---|---|
In benzene at 50℃; for 0.25h; | A n/a B 80% |
1-bromo-butane
triethylsilylcalcium chloride
A
triethylsilane
B
butyltriethylsilane
Conditions | Yield |
---|---|
for 1h; Ambient temperature; | A 1.1% B 26% |
bromobenzene
triethylsilylcalcium chloride
A
triethylsilane
B
triethylphenylsilane
Conditions | Yield |
---|---|
for 1h; Ambient temperature; | A 3% B 24% |
fluorobenzene
triethylsilylcalcium chloride
A
triethylsilane
B
triethylphenylsilane
Conditions | Yield |
---|---|
for 1h; Ambient temperature; | A 15% B n/a |
triethylsilylcalcium chloride
chlorobenzene
A
triethylsilane
B
triethylphenylsilane
Conditions | Yield |
---|---|
for 1h; Ambient temperature; | A 10% B 5% |
Conditions | Yield |
---|---|
With sodium |
The Triethylsilane is an organic compound with the formula C6H16Si. The IUPAC name of this chemical is triethylsilicon. With the CAS registry number 617-86-7, it is also named as Silane, triethyl-. The product's categories are Other Reagents; Reduction; Si (Classes of Silicon Compounds); Si-H Compounds; Silicon Compounds (for Synthesis); Synthetic Organic Chemistry; Alkyl Silanes; Hydrogensilanes Hydrogensiloxanes; Reducing Agents; Chemistry; Silanes; Synthetic Reagents. Besides, it is clear liquid, which should be stored in a dark closed and dry place. It is often used in organic synthesis, specifically for the hydrosilation of olefins to give alkyl silanes. It can also be used as a reducing agent since it has an active hydride.
Physical properties about Triethylsilane are: (1)ACD/LogP: 3.65; (2)ACD/LogD (pH 5.5): 3.65; (3)ACD/LogD (pH 7.4): 3.65; (4)ACD/BCF (pH 5.5): 349.789; (5)ACD/BCF (pH 7.4): 349.789; (6)ACD/KOC (pH 5.5): 2303.888; (7)ACD/KOC (pH 7.4): 2303.888; (8)#Freely Rotating Bonds: 3; (9)Enthalpy of Vaporization: 33.2 kJ/mol; (10)Boiling Point: 107.499 °C at 760 mmHg; (11)Vapour Pressure: 31.55 mmHg at 25°C.
Uses of Triethylsilane: it can be used to produce ethoxy-triethyl-silane. It will need reagent NaOEt.
When you are using this chemical, please be cautious about it as the following:
It is highly flammable. Please keep away from sources of ignition - No smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection, do not breathe dust and take precautionary measures against static discharges.
You can still convert the following datas into molecular structure:
(1)SMILES: CC[SiH](CC)CC
(2)InChI: InChI=1/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
(3)InChIKey: AQRLNPVMDITEJU-UHFFFAOYAL
(4)Std. InChI: InChI=1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
(5)Std. InChIKey: AQRLNPVMDITEJU-UHFFFAOYSA-N