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617-86-7

Basic Information
CAS No.: 617-86-7
Name: Silane,triethyl-
Article Data: 105
Cas Database
Molecular Structure:
Molecular Structure of 617-86-7 (Silane,triethyl-)
Formula: C6H16Si
Molecular Weight: 116.279
Synonyms: Triethylsilyl hydride;
EINECS: 210-535-3
Density: 0.728g/mLat 25°C(lit.)
Melting Point: -157 °C
Boiling Point: 107.499 °C at 760 mmHg
Flash Point: 25°F
Solubility: Miscible with water.
Appearance: Clear liquid
Hazard Symbols: FlammableF, IrritantXi
Risk Codes: 11-36/37/38
Safety: 9-16-29-33-37/39-26
Transport Information: UN 1993 3/PG 2
PSA: 0.00000
LogP: 2.27320
Synthetic route
2117-34-2

triethylmethoxysilane

617-86-7

triethylsilane

Conditions
ConditionsYield
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; ethyl bromide; tetraoctyl ammonium bromide In benzene-d6 at 20℃; for 24h; Reagent/catalyst; Solvent;96%
13399-93-4

3-(trimethylsilyl)propane-1-thiol

4149-29-5

bis(triethylsilyl)mercury

A

617-86-7

triethylsilane

B

1-Triethylsilanylsulfanyl-3-trimethylsilanyl-propane

Conditions
ConditionsYield
In benzene Heating;A n/a
B 89.5%
994-30-9

triethylsilyl chloride

617-86-7

triethylsilane

Conditions
ConditionsYield
With sodium tetrahydroborate In acetonitrile at 20℃; for 0.25h; Inert atmosphere;88%
With lithium hydride In tetrahydrofuran at 20 - 60℃; Reagent/catalyst; Solvent;82%
Stage #1: triethylsilyl chloride With magnesium In tetrahydrofuran at 75℃; for 12h; Inert atmosphere;
Stage #2: Acidic conditions;
80%
7538-45-6

2-mercaptoethyl(trimethoxysilane)

4149-29-5

bis(triethylsilyl)mercury

A

617-86-7

triethylsilane

B

C11H28O3SSi2

Conditions
ConditionsYield
In benzene Heating;A n/a
B 87.3%
30817-94-8

(mercaptomethyl)trimethoxysilane

4149-29-5

bis(triethylsilyl)mercury

A

617-86-7

triethylsilane

B

triethyl(trimethoxysilylmethylthio)silane

Conditions
ConditionsYield
In benzene at 50℃; for 0.25h;A n/a
B 80%
109-65-9

1-bromo-butane

92465-73-1

triethylsilylcalcium chloride

A

617-86-7

triethylsilane

B

994-96-7

butyltriethylsilane

Conditions
ConditionsYield
for 1h; Ambient temperature;A 1.1%
B 26%
108-86-1

bromobenzene

92465-73-1

triethylsilylcalcium chloride

A

617-86-7

triethylsilane

B

2987-77-1

triethylphenylsilane

Conditions
ConditionsYield
for 1h; Ambient temperature;A 3%
B 24%
462-06-6

fluorobenzene

92465-73-1

triethylsilylcalcium chloride

A

617-86-7

triethylsilane

B

2987-77-1

triethylphenylsilane

Conditions
ConditionsYield
for 1h; Ambient temperature;A 15%
B n/a
92465-73-1

triethylsilylcalcium chloride

108-90-7

chlorobenzene

A

617-86-7

triethylsilane

B

2987-77-1

triethylphenylsilane

Conditions
ConditionsYield
for 1h; Ambient temperature;A 10%
B 5%
78-10-4

tetraethoxy orthosilicate

557-20-0

diethylzinc

617-86-7

triethylsilane

Conditions
ConditionsYield
With sodium
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Specification

The Triethylsilane is an organic compound with the formula C6H16Si. The IUPAC name of this chemical is triethylsilicon. With the CAS registry number 617-86-7, it is also named as Silane, triethyl-. The product's categories are Other Reagents; Reduction; Si (Classes of Silicon Compounds); Si-H Compounds; Silicon Compounds (for Synthesis); Synthetic Organic Chemistry; Alkyl Silanes; Hydrogensilanes Hydrogensiloxanes; Reducing Agents; Chemistry; Silanes; Synthetic Reagents. Besides, it is clear liquid, which should be stored in a dark closed and dry place. It is often used in organic synthesis, specifically for the hydrosilation of olefins to give alkyl silanes. It can also be used as a reducing agent since it has an active hydride.

Physical properties about Triethylsilane are: (1)ACD/LogP: 3.65; (2)ACD/LogD (pH 5.5): 3.65; (3)ACD/LogD (pH 7.4): 3.65; (4)ACD/BCF (pH 5.5): 349.789; (5)ACD/BCF (pH 7.4): 349.789; (6)ACD/KOC (pH 5.5): 2303.888; (7)ACD/KOC (pH 7.4): 2303.888; (8)#Freely Rotating Bonds: 3; (9)Enthalpy of Vaporization: 33.2 kJ/mol; (10)Boiling Point: 107.499 °C at 760 mmHg; (11)Vapour Pressure: 31.55 mmHg at 25°C.

Uses of Triethylsilane: it can be used to produce ethoxy-triethyl-silane. It will need reagent NaOEt.

When you are using this chemical, please be cautious about it as the following:
It is highly flammable. Please keep away from sources of ignition - No smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection, do not breathe dust and take precautionary measures against static discharges.

You can still convert the following datas into molecular structure:
(1)SMILES: CC[SiH](CC)CC
(2)InChI: InChI=1/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
(3)InChIKey: AQRLNPVMDITEJU-UHFFFAOYAL
(4)Std. InChI: InChI=1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
(5)Std. InChIKey: AQRLNPVMDITEJU-UHFFFAOYSA-N