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CAS No.: | 624-89-5 |
---|---|
Name: | Methylthioethane |
Article Data: | 41 |
Molecular Structure: | |
Formula: | C3H8S |
Molecular Weight: | 76.1625 |
Synonyms: | Sulfide,ethyl methyl (6CI,8CI);(Methylthio)ethane;1-(Methylthio)ethane;2-Thiabutane;Ethyl methyl sulfide;Ethyl methyl thioether;Methyl ethyl sulfide; |
EINECS: | 210-868-4 |
Density: | 0.827g/cm3 |
Melting Point: | -106 °C(lit.) |
Boiling Point: | 63.2 °C at 760 mmHg |
Flash Point: | 5 °F |
Solubility: | Miscible with alcohols and oils. Immiscible with water. |
Appearance: | Colorless liquid. |
Hazard Symbols: | F |
Risk Codes: | 11 |
Safety: | 16-23-24/25 |
PSA: | 25.30000 |
LogP: | 1.36930 |
triethylsilane
bis(ethylthio)methane
A
Ethyl methyl sulfide
B
triethyl(ethylthio)silane
Conditions | Yield |
---|---|
With nickel at 120℃; for 1h; Product distribution; | A 95% B 97% |
nickel at 120℃; for 1h; | A 95% B 97% |
methylthiol
ethene
A
dimethylsulfide
B
Ethyl methyl sulfide
C
diethyl sulphide
D
ethanethiol
Conditions | Yield |
---|---|
With 2,2-dimethoxy-2-phenylacetophenone at 45℃; under 2250.23 - 6750.68 Torr; for 14.1h; UV-irradiation; | A n/a B 97% C n/a D n/a |
triethylsilane
tris(ethylsulfanyl)methane
A
Ethyl methyl sulfide
B
bis(ethylthio)methane
C
triethyl(ethylthio)silane
Conditions | Yield |
---|---|
With zinc(II) iodide at 100℃; for 3.5h; Product distribution; oth. reagent; | A 90% B 15% C 94% |
Conditions | Yield |
---|---|
With potassium hydroxide; dimethyl sulfoxide for 2h; | 88% |
1-Methyl-2-methylsulfanyl-4,6-diphenyl-pyridinium; iodide
sodium thioethylate
A
Ethyl methyl sulfide
B
2-Methylthio-4,6-diphenylpyridine
Conditions | Yield |
---|---|
at 190℃; for 1h; | A 85% B n/a |
Conditions | Yield |
---|---|
With sodium hydroxide at 125℃; for 7h; | 2.4% |
Conditions | Yield |
---|---|
durch Penicillium brevicaule Saccardo; |
Conditions | Yield |
---|---|
With potassium hydroxide |
Conditions | Yield |
---|---|
With iodine | |
With aluminum oxide at 270 - 380℃; under 16274.9 Torr; Reagent/catalyst; Temperature; Pressure; |
Conditions | Yield |
---|---|
durch Einw.von Brotkulturen von Penicillium brevicaule Saccardo; |
The Ethane, (methylthio)-, with CAS registry number 624-89-5, belongs to the following product categories: (1)Organic Building Blocks; (2)Sulfides/Disulfides; (3)Sulfur Compounds. It has the systematic name of (methylsulfanyl)ethane. This chemical is a kind of clear colorless liquid. The main use of this chemical is organic synthesis.
Physical properties of Ethane, (methylthio)-L: (1)ACD/LogP: 1.42; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.42; (4)ACD/LogD (pH 7.4): 1.42; (5)ACD/BCF (pH 5.5): 7.05; (6)ACD/BCF (pH 7.4): 7.05; (7)ACD/KOC (pH 5.5): 140.85; (8)ACD/KOC (pH 7.4): 140.85; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 25.3 Å2; (13)Index of Refraction: 1.433; (14)Molar Refractivity: 23.94 cm3; (15)Molar Volume: 92 cm3; (16)Polarizability: 9.49×10-24cm3; (17)Surface Tension: 23.2 dyne/cm; (18)Enthalpy of Vaporization: 29.53 kJ/mol; (19)Vapour Pressure: 186 mmHg at 25°C.
Preparation: this chemical can be prepared by iodomethane and ethanethiol. This reaction will need reagents KOH, DMSO. The reaction time is 2 hour(s). The yield is about 88%.
Uses of p-Chloropropiophenone: it can be used to produce methanesulfinyl-ethane. This reaction will need reagents 35percent aq. H2O2 and solvent methanol. The reaction time is 2 hour(s). The yield is about 50%.
When you are using this chemical, please be cautious about it as the following:
The Ethane, (methylthio)- is highly flammable, so keep it away from sources of ignition. When use this chemical, do not breathe vapour and avoid contact with skin and eyes.
You can still convert the following datas into molecular structure:
(1)SMILES: S(CC)C
(2)InChI: InChI=1/C3H8S/c1-3-4-2/h3H2,1-2H3
(3)InChIKey: WXEHBUMAEPOYKP-UHFFFAOYAC
(4)Std. InChI: InChI=1S/C3H8S/c1-3-4-2/h3H2,1-2H3
(5)Std. InChIKey: WXEHBUMAEPOYKP-UHFFFAOYSA-N