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6294-89-9

Basic Information
CAS No.: 6294-89-9
Name: Methyl carbazate
Article Data: 24
Molecular Structure:
Molecular Structure of 6294-89-9 (Methyl carbazate)
Formula: C2H6N2O2
Molecular Weight: 90.0818
Synonyms: Carbazicacid, methyl ester (8CI);(Methoxycarbonyl)hydrazide;Carbomethoxyhydrazide;Methyl hydrazinecarboxylate;Methyl hydrazinoformate;
EINECS: 228-560-3
Density: 1.162 g/cm3
Melting Point: 70-73 °C(lit.)
Boiling Point: 230.906 °C at 760 mmHg
Flash Point: 86.129 °C
Solubility: Soluble in water
Appearance: white to pink crystalline platelets
Hazard Symbols: IrritantXi, ToxicT
Risk Codes: 36/37/38-48-23/25
Safety: 26-36/37/39-22-45
Transport Information: UN 2811
PSA: 64.35000
LogP: 0.30730
Synthetic route
7803-57-8

hydrazine hydrate

616-38-6

carbonic acid dimethyl ester

6294-89-9

hydrazinecarboxylic acid methyl ester

Conditions
ConditionsYield
at 20℃;96%
616-38-6

carbonic acid dimethyl ester

6294-89-9

hydrazinecarboxylic acid methyl ester

Conditions
ConditionsYield
With hydrazine hydrate at 20 - 50℃; for 20.33h;95%
With hydrazine hydrate95%
With hydrazine hydrate at 20 - 50℃; for 24.5h;94%
616-38-6

carbonic acid dimethyl ester

A

6294-89-9

hydrazinecarboxylic acid methyl ester

B

497-18-7

carbonodihydrazide

Conditions
ConditionsYield
With hydrazine hydrate In neat (no solvent) at 80℃; Temperature;A 53%
B 35%
14442-53-6

N-nitro-carbamide acid methylester

6294-89-9

hydrazinecarboxylic acid methyl ester

Conditions
ConditionsYield
With acetic acid Electrolysis.durch Reduktion an einer verzinnten Kupferkathode;
14442-53-6

N-nitro-carbamide acid methylester

64-19-7

acetic acid

6294-89-9

hydrazinecarboxylic acid methyl ester

Conditions
ConditionsYield
Reduktion an einer verzinnten Kupferkathode.Electrolysis;
79-22-1

methyl chloroformate

6294-89-9

hydrazinecarboxylic acid methyl ester

Conditions
ConditionsYield
With methanol; hydrazine hydrate
76529-39-0

methyl (phenylseleno)formate

A

6294-89-9

hydrazinecarboxylic acid methyl ester

B

1666-13-3

diphenyl diselenide

Conditions
ConditionsYield
With hydrazine hydrate In ethanol at -10 - 20℃;

S-(5-benzyl-4-phenyl-4H-1,2,4-triazol-3-yl)O-methyl carbonothioate

A

6294-89-9

hydrazinecarboxylic acid methyl ester

B

22478-90-6

3-benzyl-4-phenyl-5-mercapto-1,2,4-triazole

Conditions
ConditionsYield
With hydrazine hydrate In ethanol; water at 20 - 60℃; for 10h;
61985-23-7

methyl 1-imidazolecarboxylate

6294-89-9

hydrazinecarboxylic acid methyl ester

Conditions
ConditionsYield
With hydrazine hydrate In dichloromethane at 0 - 20℃; for 1h;
6294-89-9

hydrazinecarboxylic acid methyl ester

534-07-6

1,3-Dichloroacetone

87595-89-9

methyl 2-[2-chloro-1-(chloromethyl)ethylidene]-1-hydrazinecarboxylate

Conditions
ConditionsYield
In diethyl ether for 15h; Ambient temperature;100%
In methanol at 23℃; for 4h;54%
for 3h; Ambient temperature; Yield given;
In methanol at 23℃; for 4h;
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Consensus Reports

 Methyl carbazate is reported in EPA TSCA Inventory.

Specification

The Methyl carbazate, with the CAS registry number 6294-89-9, is also known as Methoxycarbonylhydrazine. It belongs to the product categories of Amines; Isotope Labelled Compounds. Its EINECS number is 228-560-3. This chemical's molecular formula is C2H6N2O2 and molecular weight is 90.08. What's more, its systematic name is Methyl hydrazinecarboxylate. 

Physical properties of Methyl carbazate are: (1)ACD/LogP: -0.719; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.72; (4)ACD/LogD (pH 7.4): -0.72; (5)ACD/BCF (pH 5.5): 1.00; (6)ACD/BCF (pH 7.4): 1.00; (7)ACD/KOC (pH 5.5): 9.64; (8)ACD/KOC (pH 7.4): 9.67; (9)#H bond acceptors: 4; (10)#H bond donors: 3; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 64.35 Å2; (13)Index of Refraction: 1.435; (14)Molar Refractivity: 20.22 cm3; (15)Molar Volume: 77.525 cm3; (16)Polarizability: 8.016×10-24cm3; (17)Surface Tension: 38.8 dyne/cm; (18)Density: 1.162 g/cm3; (19)Flash Point: 86.129 °C; (20)Enthalpy of Vaporization: 46.755 kJ/mol; (21)Boiling Point: 230.906 °C at 760 mmHg; (22)Vapour Pressure: 0.06 mmHg at 25°C.

Uses of Methyl carbazate: it can be used to produce benzylidene-carbazic acid methyl ester by heating. It will need reagent acetic acid and solvent methanol with the reaction time of 30 min. The yield is about 90%.

Methyl carbazate can be used to produce benzylidene-carbazic acid methyl ester by heating

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. It it toxic by inhalation and if swallowed. It has a danger of serious damage to health by prolonged exposure. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective clothing, gloves and eye/face protection. You should not breathe dust. In case of accident or if you feel unwell, you must seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: O=C(OC)NN
(2)Std. InChI: InChI=1S/C2H6N2O2/c1-6-2(5)4-3/h3H2,1H3,(H,4,5)
(3)Std. InChIKey: WFJRIDQGVSJLLH-UHFFFAOYSA-N