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630-19-3

Basic Information
CAS No.: 630-19-3
Name: Pivaldehyde
Article Data: 248
Molecular Structure:
Molecular Structure of 630-19-3 (Pivaldehyde)
Formula: C5H10O
Molecular Weight: 86.1338
Synonyms: Pivalaldehyde(7CI,8CI);Pivaldehyde (6CI);2,2-Dimethylpropanal;2,2-Dimethylpropanone;2,2-Dimethylpropionaldehyde;NSC 22043;Neopentaldehyde;Neopentanal;tert-Butylformaldehyde;tert-Pentanal;a,a-Dimethylpropanal;a,a-Dimethylpropionaldehyde;
EINECS: 211-134-6
Density: 0.794 g/cm3
Melting Point: 6 °C(lit.)
Boiling Point: 77.5 °C at 760 mmHg
Flash Point: 4 °F
Solubility: Negligible
Appearance: clear slightly yellow liquid
Hazard Symbols: FlammableF,IrritantXi,HighlyF+
Risk Codes: 11-37/38-43
Safety: 16-23-33-24
Transport Information: UN 1989 3/PG 2
PSA: 17.07000
LogP: 1.23140
Synthetic route

2,2-dimethyl-1-pyrrol-1-yl-propan-1-ol

A

109-97-7

pyrrole

B

630-19-3

pivalaldehyde

Conditions
ConditionsYield
With sodium methylate In tetrahydrofuran at 20℃; for 12h; Product distribution; Further Variations:; Reagents; reaction time;A n/a
B 100%

2,6-di-tert-butyl-4-phenyl-6H-1,3,5-oxathiazine S-oxide

A

4115-15-5

3,5-diphenyl-[1,2,4]thiadiazole

B

630-19-3

pivalaldehyde

Conditions
ConditionsYield
In chloroform-d1 at 25℃; for 800h;A 100%
B 100%
3739-96-6

(2,2-Dimethyl-propylidene)-triphenyl-λ5-phosphane

630-19-3

pivalaldehyde

Conditions
ConditionsYield
With trioxo(N-tert-butylimido)osmium(VIII)100%
75-84-3

2,2-dimethyl-propanol-1

728-87-0

4,4'-Dimethoxybenzhydrol

A

726-18-1

4,4'-dianisylmethane

B

630-19-3

pivalaldehyde

Conditions
ConditionsYield
With o-benzenedisulfonimide at 80℃; for 8h;A 100%
B n/a
210693-60-0

[(S)-Tol-BINAP]Pd(o-C6H4CN)(OCH2CMe3)

A

630-19-3

pivalaldehyde

B

2-(neopentyloxy)benzonitrile

Conditions
ConditionsYield
Kinetics; inert atm.; thermal decompn. (62°C);A <2
B 99%
75-98-9

Trimethylacetic acid

630-19-3

pivalaldehyde

Conditions
ConditionsYield
With thexylchloroborane-Me2SO4 In dichloromethane for 3h; Ambient temperature;98%
With thexylbromoborane dimethyl sulfide complex In carbon disulfide; dichloromethane at -20 - 20℃; for 1h;89%
With 9-borabicyclo[3.3.1]nonane dimer; lithium dihydrido borata-bicyclo[3.3.0]nonane In tetrahydrofuran for 1h; Ambient temperature;85%
75-84-3

2,2-dimethyl-propanol-1

1972-28-7

diethylazodicarboxylate

A

4114-28-7

diethyl hydrazodicarboxylate

B

630-19-3

pivalaldehyde

Conditions
ConditionsYield
With zinc dibromide In toluene for 2.5h; Reflux;A n/a
B 90%
96-17-3, 57456-98-1

2-Methylbutyraldehyde

78-79-5

isoprene

A

563-80-4

3-methyl-butan-2-one

B

513-35-9

2-methyl-but-2-ene

C

563-45-1

3-Methyl-1-butene

D

630-19-3

pivalaldehyde

E

C2-C4 hydrocarbons

C2-C4 hydrocarbons

Conditions
ConditionsYield
With steam; calcium phosphate catalyst TU 103-134-72 at 380℃; Product distribution; Rate constant; Kinetics; other conditions - var. space velocity of adding reagent, var. dilution with steam, var. temp., var. contact time, other object - activation energy data;;A 8.2%
B n/a
C n/a
D 0.6%
E n/a
17198-92-4

<(2-methyl-1-propenyl)oxy>tri-n-butylstannane

630-19-3

pivalaldehyde

Conditions
ConditionsYield
With methyl iodide for 14 h at 90°C;86%
With CH3I for 14 h at 90°C;86%
3282-30-2

pivaloyl chloride

630-19-3

pivalaldehyde

Conditions
ConditionsYield
With ammonium hydroxide; formic acid In diethyl ether; chloroform for 0.333333h; Ambient temperature;85%
With 5%-palladium/activated carbon; hydrogen; N-ethyl-N,N-diisopropylamine In acetonitrile at 20 - 60℃; for 1h; Reagent/catalyst; Solvent; Autoclave;73%
With tri-n-butyl-tin hydride; PdCl(COPh)(PPh3)2 In toluene at 65℃;65%
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    Specifications CAS No.: 630-19-3 Other Names: PIVALALDEHYDE MF: C5H10O EINECS No.: 211-134-6 Place of Origin: China (Mainland) Type: Syntheses Material Intermediates Purity: 98.0%min Brand Name: Luyunjia Model Number: 98% Applicati

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  • Pivaldehyde CAS NO.630-19-3 CAS NO.630-19-3  CAS NO.630-19-3

  • Casno:

    630-19-3

    Pivaldehyde CAS NO.630-19-3 CAS NO.630-19-3 CAS NO.630-19-3

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  • Pivaldehyde

  • Casno:

    630-19-3

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    Pivaldehyde

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    Propanal, 2,2-dimethyl-

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Chemistry

Molecular Structure:

Molecular Formula: C5H10O
Molecular Weight: 86.1323
IUPAC Name: 2,2-Dimethylpropanal
Synonyms of Propanal, 2,2-dimethyl- (CAS NO.630-19-3): 2,2-Dimethylpropanal ; 2,2-Dimethylpropionaldehyde ; AI3-33229 ; EINECS 211-134-6 ; NSC 22043 ; Neopentanal ; Pivalaldehyde ; Pivalic aldehyde ; Trimethylacetaldehyde ; alpha,alpha-Dimethylpropanal ; alpha,alpha-Dimethylpropionaldehyde
CAS NO: 630-19-3
Classification Code: API intermediates ; Miscellaneous Reagents
Melting point: 6 °C 
Index of Refraction: 1.384
Molar Refractivity: 25.36 cm3
Molar Volume: 108.4 cm3
Surface Tension: 22 dyne/cm
Density: 0.794 g/cm3
Flash Point: °C
Enthalpy of Vaporization: 31.85 kJ/mol
Boiling Point: 77.5 °C at 760 mmHg
Vapour Pressure of Propanal, 2,2-dimethyl- (CAS NO.630-19-3): 96.5 mmHg at 25°C

Safety Profile

Hazard Codes of Propanal, 2,2-dimethyl- (CAS NO.630-19-3): FlammableF,IrritantXi,HighlyF+
Risk Statements: 11-37/38-43 
R11: Highly flammable. 
R37/38: Irritating to respiratory system and skin. 
R43: May cause sensitization by skin contact.
Safety Statements: 16-23-33-24 
S16: Keep away from sources of ignition. 
S23: Do not breathe vapour. 
S33: Take precautionary measures against static discharges. 
S24: Avoid contact with skin.
RIDADR: UN 1989 3/PG 2
WGK Germany: 3
F: 8
HazardClass: 3
PackingGroup: III