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6404-31-5

Basic Information
CAS No.: 6404-31-5
Name: N-Benzyloxycarbonyl-D-proline
Article Data: 18
Molecular Structure:
Molecular Structure of 6404-31-5 (N-Benzyloxycarbonyl-D-proline)
Formula: C13H15NO4
Molecular Weight: 249.266
Synonyms: 1,2-Pyrrolidinedicarboxylicacid, 1-(phenylmethyl) ester, (R)-;1,2-Pyrrolidinedicarboxylic acid, 1-benzylester, D- (8CI);(2R)-1-(Benzyloxycarbonyl)pyrrolidine-2-carboxylic acid;(Benzyloxycarbonyl)-D-proline;(R)-1-(Benzyloxycarbonyl)pyrrolidine-2-carboxylic acid;1-(Benzyloxycarbonyl)-D-proline;Cbz-D-Pro-OH;N-(Benzyloxycarbonyl)-(R)-proline;N-Carbobenzyloxy-D-proline;Z-D-Pro-OH;
EINECS: 229-021-5
Density: 1.309 g/cm3
Melting Point: 76-78 °C(lit.)
Boiling Point: 432.3 °C at 760 mmHg
Flash Point: 215.3 °C
Appearance: white to off-white crystalline powder
Hazard Symbols: IrritantXi
Safety: 24/25
PSA: 66.84000
LogP: 1.81010
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Specification

The IUPAC name of N-Carbobenzyloxy-D-proline is (2R)-1-phenylmethoxycarbonylpyrrolidine-2-carboxylic acid .With the CAS registry number 6404-31-5, it is also named as 1-Benzyl hydrogen (R)-pyrrolidine-1,2-dicarboxylate ; 1-[(Benzyloxy)carbonyl]-L-proline ; (+)-Carbobenzyloxy-P-proline ; (+)-Z-D-proline ; 1-[(benzyloxy)carbonyl]pyrrolidine-2-carboxylic acid .

The N-Carbobenzyloxy-D-proline is white to off-white crystalline powder which should be stored at RT. and sealed in the container. It can be used as pharmaceutical intermediates. It also can be used to prepare other chemicals. For example: it reacts with diphenylmethyl diphenyl phosphate to get pyrrolidine-1,2-dicarboxylic acid 2-benzhydryl ester 1-benzyl ester and phosphoric acid diphenyl ester .
 

The other characteristics of this product can be summarized as: (1)ACD/LogP: 1.17 ; (2)# of Rule of 5 Violations: 0 ; (3)ACD/LogD (pH 5.5): -0.35 ; (4)ACD/LogD (pH 7.4): -2.07 ; (5)ACD/BCF (pH 5.5): 1 ; (6)ACD/BCF (pH 7.4): 1 ; (7)ACD/KOC (pH 5.5): 3.13 ; (8)ACD/KOC (pH 7.4): 1 ; (9)#H bond acceptors: 5 ; (10)#H bond donors: 1 ; (11)#Freely Rotating Bonds: 4 ; (12)Index of Refraction: 1.582 ; (13)Molar Refractivity: 63.55 cm3 ; (14)Molar Volume: 190.3 cm3 ; (15)Polarizability: 25.19×10-24 cm3 ; (16)Surface Tension: 58.5 dyne/cm ; (17)Enthalpy of Vaporization: 72.53 kJ/mol ; (18)Vapour Pressure: 3.06E-08 mmHg at 25°C ; (19)Rotatable Bond Count: 4 ; (20)Exact Mass: 249.100108 ; (21)MonoIsotopic Mass: 249.100108 ; (22)Topological Polar Surface Area: 66.8 ; (23)Heavy Atom Count: 18.

People can use the following data to convert to the molecule structure. SMILES: O=C(O)[C@@H]2N(C(=O)OCc1ccccc1)CCC2; InChI: InChI=1/C13H15NO4/c15-12(16)11-7-4-8-14(11)13(17)18-9-10-5-2-1-3-6-10/h1-3,5-6,11H,4,7-9H2,(H,15,16)/t11-/m1/s1.

The N-Carbobenzyloxy-D-proline has many suppliers, such as Changzhou Weiqiang Chemical Co ., Ltd., Chengdu Chempep New Technology Co., Ltd., GL Biochem (Shanghai) Ltd., Hunan Xinyu Native Produce & Animal By-Products Import & Export Co., Ltd., Nanjing Panfeng Chemical Co., Ltd., Shanghai Dere Finechem Co., Ltd., Shanghai Garden Biochem Technology Co., Ltd. and Sichuan Sangao Biochemical Co., Ltd..