Welcome to LookChem.com Sign In|Join Free
  • or
Home > Pharmaceutical > 64285 > 

64285-06-9

Basic Information
CAS No.: 64285-06-9
Name: (+/-)-2-ACETYL-9-AZA BICYCLO[4.2.1]NON-2-ENE FUMARATE
Article Data: 11
Molecular Structure:
Molecular Structure of 64285-06-9 ((+/-)-2-ACETYL-9-AZA BICYCLO[4.2.1]NON-2-ENE FUMARATE)
Formula: C10H15 N O
Molecular Weight: 165.235
Synonyms: Ethanone,1-(9-azabicyclo[4.2.1]non-2-en-2-yl)-, (1R)-; 9-Azabicyclo[4.2.1]nonane,ethanone deriv.; (+)-Anatoxin a; (+)-Anatoxin a; (+)-Anatoxin-a; Anatoxin I; Anatoxin a; Anatoxin a
Density: 1.037 g/cm3
Boiling Point: 291 °C at 760 mmHg
Flash Point: 124.7 °C
Solubility: Soluble to 50 mM in Water
Appearance: Lyophilized Solid
Safety: Poison by intraperitoneal route. An experimental teratogen. When heated to decomposition it emits toxic fumes of NOx.
PSA: 29.10000
LogP: 1.74500
Synthetic route
120692-41-3

(+)-(1R)-2-acetyl-9-benzyloxycarbonyl-9-azabicyclo[4.2.1]-2-nonene

64285-06-9

anatoxin-a

Conditions
ConditionsYield
With trimethylsilyl iodide In acetonitrile at -10℃; for 0.333333h;99%
143264-77-1

(-)-N-tosylanatoxin-a

64285-06-9

anatoxin-a

Conditions
ConditionsYield
With disodium hydrogenphosphate; sodium amalgam In methanol at -40℃; for 0.166667h;76%
216166-93-7

(1R,6R)-2-Acetyl-9-aza-bicyclo[4.2.1]non-2-ene-9-carboxylic acid vinyl ester

64285-06-9

anatoxin-a

Conditions
ConditionsYield
With hydrochloric acid diethyl ether In ethanol at 50℃;
64700-65-8

methyl (2R)-pyroglutamate

64285-06-9

anatoxin-a

Conditions
ConditionsYield
Multi-step reaction with 8 steps
1.1: 100 percent / LiHMDS / tetrahydrofuran / -78 - 20 °C
2.1: Mg / tetrahydrofuran / 0.83 h / 20 °C
2.2: 73 percent / TMEDA / tetrahydrofuran / 1.5 h / -78 °C
3.1: BF3*OEt2; Ph3SiH / CH2Cl2 / 2.5 h / -78 - 20 °C
3.2: DIBAL-H / toluene / 3 h / -78 °C
3.3: 826 mg / Cs2CO3 / toluene; propan-2-ol / 17 h / 20 °C
4.1: 97 percent / NaHMDS / tetrahydrofuran / 2 h / -78 °C
5.1: 84 percent / second generation Grubbs catalyst / CH2Cl2 / 16 h
6.1: 76 percent / Et3N; OsO4 / tetrahydrofuran / 22 h / -78 - 20 °C
7.1: 95 percent / NaIO4 / tetrahydrofuran; H2O / 1.5 h / 20 °C
8.1: 99 percent / TMSI / acetonitrile / 0.33 h / -10 °C
View Scheme
690211-34-8

1-benzyl 2-methyl (R)-5-oxopyrrolidine-1,2-dicarboxylate

64285-06-9

anatoxin-a

Conditions
ConditionsYield
Multi-step reaction with 7 steps
1.1: Mg / tetrahydrofuran / 0.83 h / 20 °C
1.2: 73 percent / TMEDA / tetrahydrofuran / 1.5 h / -78 °C
2.1: BF3*OEt2; Ph3SiH / CH2Cl2 / 2.5 h / -78 - 20 °C
2.2: DIBAL-H / toluene / 3 h / -78 °C
2.3: 826 mg / Cs2CO3 / toluene; propan-2-ol / 17 h / 20 °C
3.1: 97 percent / NaHMDS / tetrahydrofuran / 2 h / -78 °C
4.1: 84 percent / second generation Grubbs catalyst / CH2Cl2 / 16 h
5.1: 76 percent / Et3N; OsO4 / tetrahydrofuran / 22 h / -78 - 20 °C
6.1: 95 percent / NaIO4 / tetrahydrofuran; H2O / 1.5 h / 20 °C
7.1: 99 percent / TMSI / acetonitrile / 0.33 h / -10 °C
View Scheme
690211-37-1

(2R,5R)-5-but-3-enyl-2-ethynylpyrrolidine-1-carboxylic acid 1-benzyl ester

64285-06-9

anatoxin-a

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 97 percent / NaHMDS / tetrahydrofuran / 2 h / -78 °C
2: 84 percent / second generation Grubbs catalyst / CH2Cl2 / 16 h
3: 76 percent / Et3N; OsO4 / tetrahydrofuran / 22 h / -78 - 20 °C
4: 95 percent / NaIO4 / tetrahydrofuran; H2O / 1.5 h / 20 °C
5: 99 percent / TMSI / acetonitrile / 0.33 h / -10 °C
View Scheme
690211-38-2

(2R)-but-3-enyl-(5R)-prop-1-ynylpyrrolidine-1-carboxylic acid 1-benzyl ester

64285-06-9

anatoxin-a

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 84 percent / second generation Grubbs catalyst / CH2Cl2 / 16 h
2: 76 percent / Et3N; OsO4 / tetrahydrofuran / 22 h / -78 - 20 °C
3: 95 percent / NaIO4 / tetrahydrofuran; H2O / 1.5 h / 20 °C
4: 99 percent / TMSI / acetonitrile / 0.33 h / -10 °C
View Scheme
690211-39-3

(+)-(1R)-2-isopropenyl-9-benzyloxycarbonyl-9-azabicyclo[4.2.1]-2-nonene

64285-06-9

anatoxin-a

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 76 percent / Et3N; OsO4 / tetrahydrofuran / 22 h / -78 - 20 °C
2: 95 percent / NaIO4 / tetrahydrofuran; H2O / 1.5 h / 20 °C
3: 99 percent / TMSI / acetonitrile / 0.33 h / -10 °C
View Scheme
690211-35-9

(2R)-benzyloxycarbonylamino-5-oxonon-8-enoic acid methyl ester

64285-06-9

anatoxin-a

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1.1: BF3*OEt2; Ph3SiH / CH2Cl2 / 2.5 h / -78 - 20 °C
1.2: DIBAL-H / toluene / 3 h / -78 °C
1.3: 826 mg / Cs2CO3 / toluene; propan-2-ol / 17 h / 20 °C
2.1: 97 percent / NaHMDS / tetrahydrofuran / 2 h / -78 °C
3.1: 84 percent / second generation Grubbs catalyst / CH2Cl2 / 16 h
4.1: 76 percent / Et3N; OsO4 / tetrahydrofuran / 22 h / -78 - 20 °C
5.1: 95 percent / NaIO4 / tetrahydrofuran; H2O / 1.5 h / 20 °C
6.1: 99 percent / TMSI / acetonitrile / 0.33 h / -10 °C
View Scheme
690211-40-6

(+)-(1R)-2-(1,2-dihydroxy-1-methylethyl)-9-benzyloxycarbonyl-9-azabicyclo[4.2.1]-2-nonene

64285-06-9

anatoxin-a

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 95 percent / NaIO4 / tetrahydrofuran; H2O / 1.5 h / 20 °C
2: 99 percent / TMSI / acetonitrile / 0.33 h / -10 °C
View Scheme
  • Display:default sort

    New supplier

  • Anatoxin in Aqueous methanol

  • Casno:

    64285-06-9

    Anatoxin in Aqueous methanol

    Min.Order: 0 Metric Ton

    FOB Price:  USD $ 0.0-0.0

    We can offer products of different specifications Appearance:bottle Storage:-20℃ Application:Determination of corresponding toxins

    Pribolab is manufacture of food safety testing products, including mycotoxin testing, food allergen , Marine toxins, Vitamin and GMO testing. It is established in Singapore in 2008

  •  Pribolab PTE.LTD

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86 15192580710

    Address:Building 21, MAX Business Hongwan, High-tech Zone, Qingdao

       Inquiry Now

  • (+/-)-Anatoxin A fumarate

  • Casno:

    64285-06-9

    (+/-)-Anatoxin A fumarate

    Min.Order: 1 Kilogram

    FOB Price:  USD $ 1.0-1.0

    As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine c

    Dayang Chem (Hangzhou) Co.,Ltd. dedicated to the development, production and marketing of chemicals which is specialized in Organic compounds; Active Pharmaceutical Ingredi

  •  Dayang Chem (Hangzhou) Co.,Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-571-88938639

    Address:9/F, Unit 2 Changdi Torch Building, 259# WenSan Road, Xihu District, Hangzhou City 310012, P.R.China

       Inquiry Now

  • Ethanone,1-(1R,6R)-9-azabicyclo[4.2.1]non-2-en-2-yl-

  • Casno:

    64285-06-9

    Ethanone,1-(1R,6R)-9-azabicyclo[4.2.1]non-2-en-2-yl-

    Min.Order: 1 Gram

    FOB Price:  USD $ 0.0-0.0

    1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

    Shanghai Upbio Tech Co.,Ltd (Former Onchem (China)Co.,Ltd) is a comprehensive manufacturer and an international distribution of chemicals throughout the world, The predecessor of

  •  Shanghai Upbio Tech Co.,Ltd

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-21-52196435

    Address:No.2 Floor,No.979 Yunhan Rd,Nicheng,Pudong New Area,Shanghai,China

       Inquiry Now

  • (+/-)-2-ACETYL-9-AZA BICYCLO[4.2.1]NON-2-ENE FUMARATE

  • Casno:

    64285-06-9

    (+/-)-2-ACETYL-9-AZA BICYCLO[4.2.1]NON-2-ENE FUMARATE

    Min.Order: 1 Kilogram

    FOB Price:  USD $ 2.0-2.0

    Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

    Welcome to Taizhou Zhenyu Biotech Co.,LTD , Sister Company of Ningbo Zhenlei Chemical co.,ltd ,is a rapid growing company , We are one of TOP supplier and manufactuer of Human APIs

  •  TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:13958565781

    Address:Room 623 Yulan Square Bussiness Building . Jiaojiang Taizhou Zhejiang 318000 China

       Inquiry Now

  • Ethanone,1-(1R,6R)-9-azabicyclo[4.2.1]non-2-en-2-yl-

  • Casno:

    64285-06-9

    Ethanone,1-(1R,6R)-9-azabicyclo[4.2.1]non-2-en-2-yl-

    Min.Order: 1 Metric Ton

    FOB Price:  USD $ 1.0-1.0

    We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

    We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production in China for chemicals cus

  •  Bluecrystal chem-union

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-1895157

    Address:Liang Xi Qu

       Inquiry Now

  • Ethanone,1-(1R,6R)-9-azabicyclo[4.2.1]non-2-en-2-yl-

  • Casno:

    64285-06-9

    Ethanone,1-(1R,6R)-9-azabicyclo[4.2.1]non-2-en-2-yl-

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Our own factory produces direct sales with absolute price advantage Application:Pharmaceutical industry Transportation:By sea Port:Shanghai/tianjin

    Antimex Chemical Limied, was founded in 2001, we are specializing in manufacturing & researching of Active pharmaceutical Ingredients,Veterinary pharm APIs,cosmetic ingredients,and

  •  Antimex Chemical Limied

    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:0086-21-50563169

    Address:Room1027,No.Jinyu Road,Pudong

       Inquiry Now

  • (?-ANATOXIN A FUMARATE; (?-2-ACETYL-9-AZA BICYCLO[4.2.1]NON-2-ENE FUMARATECAS

  • Casno:

    64285-06-9

    (?-ANATOXIN A FUMARATE; (?-2-ACETYL-9-AZA BICYCLO[4.2.1]NON-2-ENE FUMARATECAS

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    (?-ANATOXIN A FUMARATE; (?-2-ACETYL-9-AZA BICYCLO[4.2.1]NON-2-ENE FUMARATECASAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

    Welcome to Hangzhou Fandachem Co.,Ltd (www.FandaChem.com) Hangzhou Fandachem Co.,Ltd (Fandachem),an experienced and professional China-based Fine Chemical supplier. We supply the

  •  Hangzhou Fandachem Co.,Ltd

    China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:+86-571-28800458

    Address:Room 5010, No.9 YanAn Road,Hangzhou,Zhejiang,China

       Inquiry Now

  • 1-(9-azabicyclo[4.2.1]non-2-en-2-yl)ethanone

  • Casno:

    64285-06-9

    1-(9-azabicyclo[4.2.1]non-2-en-2-yl)ethanone

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

    We are a team of industry experts, dedicated to delivering the best chemical solutions from quality suppliers across China. Putting our customers first, we take a holistic approach

  •  Chemlyte Solutions

    China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:+86-189 8945 5137

    Address:Jian Qiao Community, 789 Shenhua Road, Xihu District, Hangzhou, China, 310000

       Inquiry Now

  • Anatoxin

  • Casno:

    64285-06-9

    Anatoxin

    Min.Order: 1 Gram

    FOB Price:  USD $ 0.0-0.0

    Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

    Changzhou Extraordinary Pharmatech co., LTD. Is a full technical team and for the development of hardware and software facilities manufacturing enterprises,The company is located i

  • Changzhou Extraordinary Pharmatech co.,LTD

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86 519 82111935

    Address:Chinese Jiangsu Province Changzhou City Jintan District Jincheng Town Miaotou NO4(Pharmaceutical Park)

       Inquiry Now

  • Total:13 Page 1 of 1 1
Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 64285-06-9

Chemistry

IUPAC Name: 1-[(1R,6R)-9-Azabicyclo[4.2.1]non-4-en-5-yl]ethanone
Synonyms: (1R)-ethanon;anatoxini ; (+/-)-Anatoxin a ; (+/-)-Anatoxin a fumarate ; (+/-)-Anatoxin a fumerate ; (+/-)-2-Acetyl-9-aza bicyclo[4.2.1]non-2-ene fumarate ; (-)-Anatoxin ; (1β,6β)-5-Acetyl-9-azabicyclo[4.2.1]non-4-ene
Product Categories: Acetylcholine receptor
CAS NO: 64285-06-9
Molecular Formula of Anatoxin I (CAS NO.64285-06-9) : C10H15NO
Molecular Weight of Anatoxin I (CAS NO.64285-06-9) : 165.23
Molecular Structure of Anatoxin I (CAS NO.64285-06-9) :
Mol File: 64285-06-9.mol
Index of Refraction: 1.503
Surface Tension: 34 dyne/cm
Density: 1.037 g/cm3
Flash Point: 124.7 °C
Enthalpy of Vaporization: 53.04 kJ/mol
Boiling Point: 291 °C at 760 mmHg
Vapour Pressure: 0.002 mmHg at 25°C

Toxicity Data With Reference

1.    

ipr-mus LDLo:250 µg/kg

    TOXIA6    Toxicon. 27 (1989),79.

Safety Profile

Poison by intraperitoneal route. An experimental teratogen. When heated to decomposition it emits toxic fumes of NOx.

Specification

Category: Toxic Substances
Toxicity classification: highly toxic
Acute toxicity: abdominal - mice LDL0: 0.25 mg / kg
Flammable hazardous characteristics: flammable; burning of toxic nitrogen oxide fumes
Storage features: Treasury ventilation, low temperature, dry
Fire-extinguishing agents: water, carbon dioxide, dry powder, sand