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CAS No.: | 645-36-3 |
---|---|
Name: | 2,2-Diethoxyethylamine |
Article Data: | 29 |
Molecular Structure: | |
Formula: | C6H15NO2 |
Molecular Weight: | 133.191 |
Synonyms: | Acetaldehyde,amino-, diethyl acetal (6CI,7CI,8CI);1,1-Diethoxy-2-aminoethane;1-Amino-2,2-diethoxyethane;2,2-Bis(ethyloxy)ethanamine;2-Aminoacetaldehyde diethylacetal;Aminoacetaldehyde diethyl acetal;Glycinaldehyde diethyl acetal;NSC19501;a-Aminoacetaldehyde diethylacetal;b,b-Diethoxyethylamine; |
EINECS: | 211-439-4 |
Density: | 0.922 g/cm3 |
Melting Point: | -78 °C |
Boiling Point: | 163 °C at 760 mmHg |
Flash Point: | 45.6 °C |
Solubility: | Soluble in water |
Appearance: | clear colourless to light yellow liquid |
Hazard Symbols: | Xi, C, F |
Risk Codes: | 10-36/37/38-34 |
Safety: | 23-24/25-26-45-36/37/39-16-36 |
Transport Information: | UN 1989 3/PG 3 |
PSA: | 44.48000 |
LogP: | 1.04450 |
Conditions | Yield |
---|---|
With hydrazine hydrate; nickel In ethanol at 55℃; | 97% |
With cyclohexane; ammonia; nickel at 75 - 90℃; under 73550.8 Torr; Hydrogenation; |
3-N-(2',2'-diethoxyethyl)quinazolin-4-one
A
anthranilic acid
B
2,2-diethoxy-ethanamine
Conditions | Yield |
---|---|
With sodium hydroxide Heating; | A n/a B 83% |
Conditions | Yield |
---|---|
With ammonia; hydrogen; nickel In ethanol at 70℃; under 67505.4 Torr; for 0.5h; | 80% |
Multi-step reaction with 2 steps 1: 1.) hydroxylamine chlorhydrate, triethylamine; 2.) mesyl chloride / 1.) dichloromethane, r.t.; 2.) 0 deg C, 3 h 2: 97 percent / hydrazin hydrate / Raney nickel / ethanol / 55 °C View Scheme |
2,2-diethoxy-ethanamine
Conditions | Yield |
---|---|
With ethanol; acetic acid; zinc | |
With nickel; benzene under 36775.4 - 51485.6 Torr; Hydrogenation; |
1,1-diethoxy-2-nitroethane
2,2-diethoxy-ethanamine
Conditions | Yield |
---|---|
With ethanol; sodium at 110 - 120℃; under 13239.1 Torr; |
(3,4,3',4'-tetramethoxy-bibenzyl-α-ylidenamino)-acetaldehyde diethylacetal
A
1,2-bis(3,4-dimethoxyphenyl)ethanone
B
2,2-diethoxy-ethanamine
Conditions | Yield |
---|---|
an feuchter Luft; |
Conditions | Yield |
---|---|
With ammonia at 105℃; | |
With ethanol; ammonia |
Conditions | Yield |
---|---|
With ethanol; ammonia at 110 - 115℃; |
Bromoacetaldehyde diethyl acetal
A
iminodiacetaldehyde bis(diethyl acetal)
B
2,2-diethoxy-ethanamine
Conditions | Yield |
---|---|
With ethanol; ammonia at 110 - 115℃; | |
With ammonia at 105℃; |
Conditions | Yield |
---|---|
With ethanol; ammonia at 130℃; durch Zusatz von Natriumjodid wird die Reaktion beschleunigt; | |
With ethanol; ammonia | |
With ethanol; ammonia |
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IUPAC Name: 2,2-Diethoxyethanamine
Following is the structure of Ethanamine,2,2-diethoxy- (CAS NO.645-36-3):
Empirical Formula: C6H15NO2
Molecular Weight: 133.1888
EINECS: 211-439-4
Index of Refraction: 1.423
Molar Refractivity: 36.83 cm3
Molar Volume: 144.3 cm3
Density: 0.922 g/cm3
Flash Point: 45.6 °C
Melting point: -78 °C
Water Solubility: soluble
Storage temp.: Flammables area
Surface Tension: 29.5 dyne/cm
Enthalpy of Vaporization: 39.95 kJ/mol
Boiling Point: 163 °C at 760 mmHg
Vapour Pressure: 2.11 mmHg at 25 °C
Appearance of Ethanamine,2,2-diethoxy- (CAS NO.645-36-3): Clear colorless to light yellow liquid
Product Categories of Ethanamine,2,2-diethoxy- (CAS NO.645-36-3): Pharmaceutical Intermediates; Small molecule
Canonical SMILES: CCOC(CN)OCC
InChI: InChI=1S/C6H15NO2/c1-3-8-6(5-7)9-4-2/h6H,3-5,7H2,1-2H3
InChIKey: HJKLEAOXCZIMPI-UHFFFAOYSA-N
Ethanamine,2,2-diethoxy- (CAS NO.645-36-3) hasn't been listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. And the toxicological properties have not been fully investigated.
Hazard Codes: Xi,CF
Risk Statements: 10-36/37/38-34
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
R34:Causes burns.
Safety Statements: 23-24/25-26-45-36/37/39-16-36
S23:Do not breathe vapour.
S24/25:Avoid contact with skin and eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S16:Keep away from sources of ignition.
S36:Wear suitable protective clothing.
RIDADR: UN 1989 3/PG 3
WGK Germany: 3
Hazard Note: Irritant
HazardClass: 3
PackingGroup: III
Ethanamine,2,2-diethoxy- , its cas register number is 645-36-3. It also can be called Aminoacetaldehyde diethyl acetal ; and 2,2-Diethoxyethylamine .
Ethanamine,2,2-diethoxy- (CAS NO.645-36-3) could be stable under normal temperatures and pressures. It should avoid the condition like incompatible materials, ignition sources. It is not compatible with strong oxidizing agents, acids, acid chlorides, carbon dioxide, acid anhydrides. And also prevent it to broken down into hazardous decomposition products: nitrogen oxides, carbon monoxide, carbon dioxide. However, its hazardous polymerization has not been reported.