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| CAS No.: | 676-58-4 |
|---|---|
| Name: | Methylmagnesium chloride |
| Molecular Structure: | |
|
|
|
| Formula: | CH3 Cl Mg |
| Molecular Weight: | 74.7928 |
| Synonyms: | Methylmagnesiumchloride (6CI);Chloromethylmagnesium; |
| EINECS: | 211-629-7 |
| Density: | 1.013 g/mL at 25 °C |
| Boiling Point: | 66 °C |
| Flash Point: | ?1 °F |
| Solubility: | reacts with water |
| Appearance: | dark brown solution |
| Hazard Symbols: |
 F, C
|
| Risk Codes: | 11-14/15-34-19-15 |
| Safety: | 26-30-36/37/39-43-45-7/8-33-29-16 |
| Transport Information: | UN 3399 4.3/PG 2 |
| PSA: | 0.00000 |
| LogP: | 1.27330 |
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| Conditions | Yield |
|---|---|
| With magnesium In tetrahydrofuran | |
| With magnesium In solid matrix at -258.2℃; | |
| With magnesium; lithium chloride In tetrahydrofuran at 0 - 20℃; Inert atmosphere; |
| Conditions | Yield |
|---|---|
| With diethyl ether |
| Conditions | Yield |
|---|---|
| In diethyl ether at 0 - 20℃; | 100% |
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- 676-58-4
methylmagnesium chloride
- 127810-66-6
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| Conditions | Yield |
|---|---|
| With titanium tetrachloride In tetrahydrofuran; dichloromethane at 0℃; for 2h; | 100% |
- 676-58-4
methylmagnesium chloride
- 119947-11-4
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- 119947-12-5
N-<7-<2-(6-hydroxy-6-methylheptyl)-1,3-dioxolan-2-yl>heptyl>acetamide
| Conditions | Yield |
|---|---|
| In tetrahydrofuran for 12h; | 100% |
- 676-58-4
methylmagnesium chloride
- 156749-48-3
dimethyl (RS)-6,6'-dibromobiphenyl-2,2'-dicarboxylate
- 156749-47-2
6,6'-dibromobiphenyl-2,2'-di(1-methylethanol)
| Conditions | Yield |
|---|---|
| In tetrahydrofuran for 3h; Heating; | 100% |
- 676-58-4
methylmagnesium chloride
| Conditions | Yield |
|---|---|
| In tetrahydrofuran | 100% |
- 676-58-4
methylmagnesium chloride
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- 13720-13-3
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| Conditions | Yield |
|---|---|
| 100% |
- 676-58-4
methylmagnesium chloride
- 119-84-6
C6H4(CH2CH2C(O)O)
- 4167-73-1
4-(2-hydroxyphenyl)-2-methyl-2-butanol
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 0 - 20℃; | 100% |
| In tetrahydrofuran Ambient temperature; | 6.25 g |
| In tetrahydrofuran; (2S)-N-methyl-1-phenylpropan-2-amine hydrate; water | |
| Stage #1: methylmagnesium chloride; C6H4(CH2CH2C(O)O) In tetrahydrofuran for 18.6667h; Stage #2: With water In tetrahydrofuran Cooling; |
- 676-58-4
methylmagnesium chloride
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at -20 - 20℃; | 100% |
| at -20℃; for 0.0833333h; pH=13; Grignard reaction; |
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Chemistry
Molecular Structure:
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Molecular Formula: CH3ClMg
Molecular Weight: 74.7925
IUPAC Name: Magnesium carbanide chloride
Synonyms of Methylmagnesium chloride (CAS NO.676-58-4): Chloromethylmagnesium ; EINECS 211-629-7 ; HSDB 5740 ; Magnesium, chloromethyl-
CAS NO: 676-58-4
Classification Code: Organometallics ; GRIGNARD REAGENTS ; AlkylChemical Synthesis ; Grignard Reagents ; Organic Bases ; Organometallic Reagents ; Synthetic Reagents
Safety Profile
Hazard Codes of Methylmagnesium chloride (CAS NO.676-58-4): 
F,
C
Risk Statements: 11-14/15-34-19
R11: Highly flammable.
R14: Reacts violently with water.
R15: Contact with water liberates extremely flammable gases.
R34: Causes burns.
R19: May form explosive peroxides.
Safety Statements: 26-30-36/37/39-43-45-7/8-33-29-16
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S30: Never add water to this product.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S43: In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S7: Keep container tightly closed.
S8: Keep container dry.
S33: Take precautionary measures against static discharges.
S29: Do not empty into drains.
S16: Keep away from sources of ignition.
RIDADR :UN 3399 4.3/PG 2
WGK Germany: 1
F: 1-3-10
HazardClass: 4.3
PackingGroup: I