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677-22-5

Basic Information
CAS No.: 677-22-5
Name: TERT-BUTYLMAGNESIUM CHLORIDE
Article Data: 22
Molecular Structure:
Molecular Structure of 677-22-5 (TERT-BUTYLMAGNESIUM CHLORIDE)
Formula: C4H9ClMg
Molecular Weight: 116.873
Synonyms: Magnesium,tert-butylchloro- (7CI,8CI);tert-Butylmagnesium chloride (6CI);(1,1-Dimethylethyl)magnesium chloride;t-Butylmagnesium chloride;tert-Butylchloromagnesium;tert-butylmagnesium chloride;
EINECS: 211-638-6
Density: 0.931 g/mL at 25 °C
Melting Point: 46oC to 50oC
Boiling Point: 34 °F
Flash Point: 34 °F
Solubility: Miscible with alcohol and water.
Appearance: clear faint grey to grey, grey-brown or light
Hazard Symbols: HighlyF+;CorrosiveC;FlammableF
Risk Codes: 12-14/15-19-22-34-66-67-15-11-14
Safety: UN 3399 4.3/PG 1
Transport Information: UN 3399 4.3/PG 1
PSA: 0.00000
LogP: 2.44360
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Chemistry

IUPAC Name: Magnesium 2-methylpropane chloride
Synonyms of Magnesium,chloro(1,1-dimethylethyl)- (CAS NO.677-22-5): Magnesium(1+), (1,1-dimethylethyl)-, chloride (1:1) ; tert-Butylmagnesium(1+) chloride
Molecular Structure:
Molecular Formula: C4H9ClMg
Molecular Weight: 116.8723
CAS NO: 677-22-5
EINECS: 211-638-6 
Density: 0.931 g/mL at 25 °C
Flash Point: 34 °F
Storage temp: 2-8°C
Appearance: clear faint grey to grey, grey-brown or light
SMILES: [Cl-].[Mg+]C(C)(C)C
InChI: InChI=1/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1/rC4H9Mg.ClH/c1-4(2,3)5;/h1-3H3;1H/q+1;/p-1 Copy
InChIKey: ZDRJSYVHDMFHSC-DHKKDVNOAZ
Std. InChI: InChI=1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
Std. InChIKey: ZDRJSYVHDMFHSC-UHFFFAOYSA-M
Product Categories of Magnesium,chloro(1,1-dimethylethyl)- (CAS NO.677-22-5): Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;AlkylChemical Synthesis;Grignard Reagents;Organic Bases;Organometallic Reagents;Synthetic Reagents

Safety Profile

Safety Information of Magnesium,chloro(1,1-dimethylethyl)- (CAS NO.677-22-5):
Hazard Codes: HighlyF+F ,CorrosiveC
Risk Statements: 12-14/15-19-22-34-66-67-15-11
R11: Highly flammable. 
R12: Extremely flammable. 
R14/15: Reacts violently with water, liberating extremely flammable gases 
R19: May form explosive peroxides. 
R22: Harmful if swallowed. 
R34: Causes burns. 
R66: Repeated exposure may cause skin dryness or cracking. 
R67: Vapours may cause drowsiness and dizziness.
Safety Statements: 9-16-26-29-33-36/37/39-43-45
RIDADR UN: 3399 4.3/PG 1
WGK Germany: 1
F: 1-3-10

Specification

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Flammable liquid and vapor. May form explosive peroxides.
Extinguishing Media: Use approved class D extinguishing agents or smother with dry sand, clay, or sodium bicarbonate. DO 
Handling: Do not allow water to get into the container because of violent reaction. Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Do not allow contact with water. Use only in a chemical fume hood.
Storage: Keep away from sources of ignition. Do not store in direct sunlight. Store in a tightly closed container. Store in a dry area. Flammables-area. Water free area. Store under nitrogen. Store at room temperature.