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6836-19-7

Basic Information
CAS No.: 6836-19-7
Name: 7-Methoxy-1-tetralone
Article Data: 69
Molecular Structure:
Molecular Structure of 6836-19-7 (7-Methoxy-1-tetralone)
Formula: C11H12O2
Molecular Weight: 176.215
Synonyms: 7-Methoxy-1,2,3,4-tetrahydro-1-oxonaphthalene;3,4-Dihydro-7-methoxy-1(2H)-naphthalenone;7-Methoxy-1,2,3,4-tetrahydro-1-naphthalenone;
EINECS: 229-916-0
Density: 1.124 g/cm3
Melting Point: 59-63 °C(lit.)
Boiling Point: 312.3 °C at 760 mmHg
Flash Point: 145.8 °C
Solubility: 309mg/L at 25℃
Appearance: Off-white powder
Hazard Symbols: HarmfulXn
Risk Codes: 20/21/22-36/37/38
Safety: 22-24/25-36-26
PSA: 26.30000
LogP: 2.21420
Synthetic route
6836-18-6

4-(4-methoxyphenyl) butanoyl chloride

6836-19-7

7-Methoxy-1-tetralone

Conditions
ConditionsYield
With Fe-Al-MCM-41 molecular sieve In toluene at 60℃; for 18h; Green chemistry;98.4%
unter vermindertem Druck;
With aluminium trichloride; 1,1,2,2-tetrachloroethane at -5℃;
32820-10-3

7-methoxy-1,2,3,4-tetrahydro-1-naphthol

6836-19-7

7-Methoxy-1-tetralone

Conditions
ConditionsYield
With acetone In toluene at 80℃; for 0.25h; Flow reactor;96%
4521-28-2

4-(4-Methoxyphenyl)butyric acid

6836-19-7

7-Methoxy-1-tetralone

Conditions
ConditionsYield
With phosphoric acid; phosphorus pentoxide at 70 - 80℃; for 2h;94%
With trifluoroacetic anhydride In 1,2-dichloro-ethane at 0 - 20℃; Friedel-Crafts acylation;94%
With trichloroacetic acid anhydride at 70℃; Friedel Crafts acylation; Neat (no solvent);92%
106336-27-0

(7-Methoxy-1,2,3,4-tetrahydro-naphthalen-1-yl)-methanol

6836-19-7

7-Methoxy-1-tetralone

Conditions
ConditionsYield
With dipyridinium dichromate; Celite In dichloromethane at 25℃; for 24h;79%
666177-27-1

dimethyl 1,2-dihydro-4-hydroxy-6-methoxynaphthalene-1,3-dicarboxylate

6836-19-7

7-Methoxy-1-tetralone

Conditions
ConditionsYield
With sodium chloride In dimethyl sulfoxide at 200℃;65%

4-(4-Methoxy-phenyl)-butyryl azide

6836-19-7

7-Methoxy-1-tetralone

Conditions
ConditionsYield
64%
65128-90-7

7-methoxy-8a-methyl-1,2,3,4,6,8a-hexahydro-naphthalen-1-one

A

6836-19-7

7-Methoxy-1-tetralone

(6S,8aS)-6-Hydroxy-7-methoxy-8a-methyl-3,4,6,8a-tetrahydro-2H-naphthalen-1-one

(6R,8aS)-6-Hydroxy-7-methoxy-8a-methyl-3,4,6,8a-tetrahydro-2H-naphthalen-1-one

Conditions
ConditionsYield
With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid In dichloromethane at 4℃; pH=8.3;A 63%
B 20%
C 12%
87543-05-3

1,1-(1,2-Benzenediyldithio)-7-methoxy-1,2,3,4-tetrahydronaphthalene

6836-19-7

7-Methoxy-1-tetralone

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; mercury(II) oxide In tetrahydrofuran; water62%
With tetrahydrofuran; mercury(II) oxide; boron trifluoride diethyl etherate56%
1202643-83-1

1-(3-methoxyphenyl)cyclobutan-1-ol

6836-19-7

7-Methoxy-1-tetralone

Conditions
ConditionsYield
With potassium carbonate; copper(II) sulfate; Selectfluor In water; acetonitrile at 60℃; for 5h;59%
310897-19-9

8a-allyl-7-methoxy-1,2,3,4,6,8a-hexahydro-naphthalen-1-one

A

6836-19-7

7-Methoxy-1-tetralone

(6S,8aS)-8a-Allyl-6-hydroxy-7-methoxy-3,4,6,8a-tetrahydro-2H-naphthalen-1-one

(6R,8aS)-8a-Allyl-6-hydroxy-7-methoxy-3,4,6,8a-tetrahydro-2H-naphthalen-1-one

Conditions
ConditionsYield
With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid In dichloromethane at 4℃; pH=8.3;A 54%
B 22.5%
C 12.5%
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    7-methoxy-1-tetralone CAS No.:6836-19-7 Name 7-Methoxy-1-tetralone Molecular Structure Molecular Formula C11H12O2 Molecular Weight 176.21 CAS Registry Number 6836-19-7 EINECS 229-916-0 Appearance:de

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    Name: 7-methoxy-1-tetralone Synonyms: 7-methoxy-1,2,3,4-tetrahydronaphthalen-1-one CAS: 6836-19-7 MF: C11H12O2 Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg/drum Application:Chemical materials Trans

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Chemistry

IUPAC Name: 7-Methoxy-3,4-dihydro-2H-naphthalen-1-one
Synonyms of 7-Methoxy-1-tetralone (CAS NO.6836-19-7): 7-Methoxy-1,2,3,4-tetrahydronaphthalen-1-one
CAS NO: 6836-19-7
Molecular Formula: C11H12O2
Molecular Weight: 176.21
Molecular Structure:
EINECS: 229-916-0
H bond acceptors: 2
H bond donors: 0
Freely Rotating Bonds: 1
Polar Surface Area: 26.3 Å2
Index of Refraction: 1.548
Molar Refractivity: 49.84 cm3
Molar Volume: 156.7 cm3
Surface Tension: 40.8 dyne/cm
Density: 1.124 g/cm3
Flash Point: 145.8 °C
Enthalpy of Vaporization: 55.32 kJ/mol
Boiling Point: 312.3 °C at 760 mmHg
Vapour Pressure: 0.000535 mmHg at 25°C 
Melting Point: 59-63 °C(lit.)
Appearance: Off-White Powder
Product Categories of 7-Methoxy-1-tetralone (CAS NO.6836-19-7): Benzocycles;Naphthalene derivatives;Aromatics Compounds;Butorphanol;Aromatics;C11 to C12;Carbonyl Compounds;Ketones

Uses

 7-Methoxy-1-tetralone (CAS NO.6836-19-7) is used for pharmaceutical intermediate.

Safety Profile

Safety Information about 7-Methoxy-1-tetralone (CAS NO.6836-19-7):
Hazard Codes: HarmfulXn
Risk Statements: 20/21/22-36/37/38
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. 
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 22-24/25-36-26
S22: Do not breathe dust. 
S24/25: Avoid contact with skin and eyes. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36: Wear suitable protective clothing.
WGK Germany: 3