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693-95-8

Basic Information
CAS No.: 693-95-8
Name: 4-Methylthiazole
Article Data: 41
Molecular Structure:
Molecular Structure of 693-95-8 (4-Methylthiazole)
Formula: C4H5NS
Molecular Weight: 99.1564
Synonyms: 4-Methyl-1,3-thiazole;NSC 42976;Thiazole, 4-methyl-;
EINECS: 211-764-1
Density: 1.121 g/cm3
Melting Point: 134 °C
Boiling Point: 134.3 °C at 760 mmHg
Flash Point: 37.3 °C
Appearance: Clear colourless to slightly yellow liquid
Hazard Symbols: HarmfulXn, IrritantXi
Risk Codes: 37.3°C
Safety: 16-26-39
Transport Information: UN 1993 3/PG 3
PSA: 41.13000
LogP: 1.45150
Synthetic route
20485-41-0

4-methylthiazole-5-carboxylic acid

693-95-8

4-Methylthiazole

Conditions
ConditionsYield
With acetic acid In N,N-dimethyl-formamide at 105 - 110℃; for 8h; Reagent/catalyst; Temperature; Green chemistry;95%
With acetic acid; silver carbonate In dimethyl sulfoxide at 120℃; for 16h;100 %Spectr.
5685-06-3

4-methylthiazole-2-thiol

693-95-8

4-Methylthiazole

Conditions
ConditionsYield
With hydrogenchloride; dihydrogen peroxide In water at 45℃; for 1.5h; Temperature;78%
With hydrogenchloride; dihydrogen peroxide
1603-91-4

4-methylthiazol-2-ylamine

693-95-8

4-Methylthiazole

Conditions
ConditionsYield
Stage #1: 4-methylthiazol-2-ylamine With sulfuric acid; sodium nitrite In water at -15 - -10℃; for 4h;
Stage #2: With sodium hypophosphite In water at -10 - -5℃; for 6h; Temperature;
72%
6407-34-7, 19885-74-6

methyl-1 ethylideneamine

693-95-8

4-Methylthiazole

Conditions
ConditionsYield
With sulfur dioxide; soda-lime; zirconium(IV) oxide at 450℃;70%
52558-99-3

4-methyl-3-thiazoline

693-95-8

4-Methylthiazole

Conditions
ConditionsYield
With ethanol; iron(III) chloride
32497-10-2

4-methyl-2(3H)-thiazolone

693-95-8

4-Methylthiazole

Conditions
ConditionsYield
With zinc bei der Destillation;
bei der Zinkstaub-Destillation;
5685-06-3

4-methylthiazole-2(3H)-thione

693-95-8

4-Methylthiazole

Conditions
ConditionsYield
With dihydrogen peroxide
14542-16-6

4-methyl-1,3-thiazole-2-carboxylic acid

693-95-8

4-Methylthiazole

26847-01-8

2-chloro-4-methyl-1,3-thiazole

693-95-8

4-Methylthiazole

Conditions
ConditionsYield
With acetic acid; zinc
14397-08-1

2-hydrazinyl-4-methylthiazole hydrochloride

693-95-8

4-Methylthiazole

Conditions
ConditionsYield
With water; mercury(II) oxide
With hydrogenchloride; dihydrogen peroxide
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    4-Methylthiazole Basic information Product Name: 4-Methylthiazole Synonyms: 4-methyl-thiazol;Thiazole, 4-methyl-;METHYLTHIAZOLE, 4-;FEMA NUMBER 3716;FEMA 3716;4-METHYLTHIAZOLE;4-METHYL-1,3-THIAZOLE;4-METHYLTHIAZOLE 98+% CAS: 693-95-8 MF:

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Chemistry

Molecular Structure of 4-Methylthiazole (CAS NO.693-95-8):

IUPAC Name: 4-Methyl-1,3-thiazole
Canonical SMILES: CC1=CSC=N1
InChI: InChI=1S/C4H5NS/c1-4-2-6-3-5-4/h2-3H,1H3
InChIKey: QMHIMXFNBOYPND-UHFFFAOYSA-N
Molecular Weight: 99.1542 [g/mol]
Molecular Formula: C4H5NS
XLogP3: 1
H-Bond Donor: 0
H-Bond Acceptor: 1 
EINECS: 211-764-1 
Index of Refraction: 1.535
Molar Refractivity: 27.55 cm3
Molar Volume: 88.4 cm3
Surface Tension: 39.9 dyne/cm
Density: 1.121 g/cm3
Flash Point: 37.3 °C
Enthalpy of Vaporization: 37.58 kJ/mol
Boiling Point: 134.3 °C at 760 mmHg
Vapour Pressure: 10 mmHg at 25 °C
Appearance: Clear colourless to slightly yellow liquid
storage temp.: Flammables area
Product Categories: Thiazoles; thiazole Flavor; Building Blocks; Heterocyclic Building Blocks; Alphabetical Listings; Flavors and Fragrances; M-N

Uses

 4-Methylthiazole (CAS NO.693-95-8) is used as medicine, fragrance intermediates.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 360uL/kg (0.36mL/kg) SENSE ORGANS AND SPECIAL SENSES: PTOSIS: EYE

BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)

BEHAVIORAL: ATAXIA
Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 182, 1992.

Safety Profile

Safety Information of 4-Methylthiazole (CAS NO.693-95-8):
Hazard Codes: HarmfulXn,IrritantXi
Risk Statements: 10-22-37/38-41 
R10:Flammable. 
R22:Harmful if swallowed. 
R37/38:Irritating to respiratory system and skin. 
R41:Risk of serious damage to the eyes.
Safety Statements: 16-26-39 
S16:Keep away from sources of ignition. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S39:Wear eye / face protection.
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
RTECS: XJ5096000
TSCA: T
HazardClass: 3
PackingGroup: III

Specification

 4-Methylthiazole (CAS NO.693-95-8), its Synonyms are Thiazole, 4-methyl- ; 4-Methyl thiazole ; 4-Methyl-1,3-thiazole .