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CAS No.: | 73482-96-9 |
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Name: | Rhodium(II) octanoate dimer |
Article Data: | 4 |
Molecular Structure: | |
Formula: | C32H60O8Rh2 |
Molecular Weight: | 778.635 |
Synonyms: | Octanoic acid, rhodium complex;Dirhodium tetraoctanoate;Rhodium(II) octanoatedimer;Tetrakis(octanoato)dirhodium;Rhodium,tetrakis[m-(octanoato-O:O')]di-, (Rh-Rh); |
EINECS: | 247-015-0 |
Boiling Point: | 239.3 °C at 760 mmHg |
Flash Point: | 107.4 °C |
Appearance: | green powder |
Hazard Symbols: | Xi |
Risk Codes: | 36/37/38 |
Safety: | 26-36 |
PSA: | 105.20000 |
LogP: | 9.41760 |
Conditions | Yield |
---|---|
With sodium hydroxide at 70℃; for 4h; Temperature; Large scale; | 97.57% |
Conditions | Yield |
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In water at 60℃; for 3h; | 94.4% |
Conditions | Yield |
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With lithium carbonate In ethanol at 20℃; for 6.5h; Heating; | 67% |
Conditions | Yield |
---|---|
In not given heated at 120°C for 2 h; recrystd. (C7H16); elem. anal.; hot-stage polarizing microscopy; DSC; |
rhodium (II) octanoate dimer
3-(piperidin-1-yl)-3-thioxopropanenitrile
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 24h; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 24h; Inert atmosphere; | 100% |
rhodium (II) octanoate dimer
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 24h; Inert atmosphere; | 100% |
rhodium (II) octanoate dimer
3-(morpholin-4-yl)-3-thioxopropanenitrile
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 24h; Inert atmosphere; | 100% |
1-methyl-1H-pyrazole
rhodium (II) octanoate dimer
[Rh2(octanoato)4(1-methylpyrazole)]
Conditions | Yield |
---|---|
In chloroform (N2); a soln. of ligand added to Rh complex in CHCl3, stirred at room temp. for 1 h; evapd. (vac.); elem. anal.; | 99% |
1-methyl-1H-pyrazole
rhodium (II) octanoate dimer
[Rh2(octanoato)4(1-methylpyrazole)2]
Conditions | Yield |
---|---|
In chloroform (N2); a soln. of ligand added to Rh complex in CHCl3, stirred at room temp. for 1 h; evapd. (vac.); elem. anal.; | 99% |
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The systematic name of Rhodium octanoate dimer is rhodium(2+) octanoate (1:2). With the CAS registry number 73482-96-9, it is also named as octanoic acid, rhodium(2+) salt (2:1). The product's categories are Catalysis and Inorganic Chemistry; Chemical Synthesis; Rhodium; Rhodium Micro / Nanoelectronics; Solution Deposition Precursors. It is green powder which is insoluble in water, soluble in hot alcohol, methylene chloride, toluene and acetic acid. Additionally, this chemical should be sealed in the container and stored in the cool and dry place which must be away from oxidant.
The other characteristics of Rhodium octanoate dimer can be summarized as: (1)ACD/LogP: 2.90; (2)# of Rule of 5 Violations: 0; (3)#H bond acceptors: 2; (4)#H bond donors: 1; (5)#Freely Rotating Bonds: 6; (6)Polar Surface Area: 37.3 Å2; (7)Flash Point: 107.4 °C; (8)Enthalpy of Vaporization: 50.32 kJ/mol; (9)Boiling Point: 239.3 °C at 760 mmHg; (10)Vapour Pressure: 0.022 mmHg at 25°C.
When you are using this chemical, please be cautious about it as the following:
It is irritating to eyes, respiratory system and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable protective clothing.
People can use the following data to convert to the molecule structure.
1. SMILES:[Rh+2].[Rh+2].[O-]C(=O)CCCCCCC.[O-]C(=O)CCCCCCC.[O-]C(=O)CCCCCCC.[O-]C(=O)CCCCCCC
2. InChI:InChI=1/4C8H16O2.2Rh/c4*1-2-3-4-5-6-7-8(9)10;;/h4*2-7H2,1H3,(H,9,10);;/q;;;;2*+2/p-4
3. InChIKey:FZXFNYFVNKTQSX-XBHQNQODAG