CAS No.7440-02-0,Nickel Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	7440-02-0
Name:	Nickel
Article Data:	1679

Formula:	Ni
Molecular Weight:	58.69
Synonyms:	B 111W;B 113W;BP 113EXP-B;C.I. 77775;CHT;CNP 525;CNS 20 m;Carbonyl Ni 283;Carbonyl Nickel 123;Carbonyl Nickel 287;Celmet;Celmet 4;Celmet 6;Celmet 8;Cerac N 2003;DNI 20;E 12;E 12 (metal);Fibrex;Fukuda 287;H 467;HCA 1;HDNP 400;Inco 210;Incofoam;N 1000;N 100ES;N154;NDHT 90;NDT 60;NDT 65;NDT 90;NI 123;NI 255AC;NI287;NN 100;NP 2;Ni 4303T;Ni Celmet;Ni-Flake 95;Ni-J 20;NiFL;NiFW;Nickel element;Nicrobraz LM:BNi 2;Nikko 255;Novamet123;Novamet 4SP;Novamet CNS 400;Novamet NI 255;PF 20 (metal);R 200;R 200 (metal);R 205;Raney nickel 2800;SF 300;SF-Ni;SFR-Ni;SNP-YH 6;SO 100A;SO 250G;SO 850;T123;T 123 (metal);T 210H;T 287;Trimag;UT3PM;YH 641;YH-623;Alcan 756;
EINECS:	231-111-4
Density:	8.9 g/cm³
Melting Point:	212 °C (dec.)(lit.)
Boiling Point:	2732 °C(lit.)
Solubility:	It is insoluble in water.
Appearance:	silver white, hard, malleable metal chunks or grey powder
Hazard Symbols:	Xn, Xi, C, F
Risk Codes:	34-50/53-43-40-10-17
Safety:	26-45-60-61-36-22-36/37-16-15-5
Transport Information:	UN 1493 5.1/PG 2
PSA:	0.00000
LogP:	0.00000

Synthetic route

: nickel(II) chloride hexahydrate

: 7803-57-8
hydrazine hydrate

: 1310-73-2
sodium hydroxide

: 7440-02-0
nickel

Conditions

Conditions	Yield
In water N2H4H2O (80%) added to aq. soln. of NiCl26H2O (temp. increased to 65°C) under vigorous stirring, cooling to 50°C, aq. NaOH (50%)added (temp. increased to 54°C), 1 h; ppt. washed with water and dried at room temp. for 16 h;	100%
In water; ethylene glycol byproducts: N2, H2O; other Radiation; soln. of Ni compd. in ethylene glycol treated with hydrazine hydrate andNaOH under external magnetic field (0.13-0.35 T) with vigorous stirring , react at 60°C; pptd., septd., washed (ethanol), dried (vac., 40°C, 24 h), SEM, XRD;

...Expand

: 1333-74-0
hydrogen

: nickel(II) hydroxide

: 7440-02-0
nickel

Conditions

Conditions	Yield
In not given at 205°C, H2 pressure 14 atm, 45 min, form of product is powder;	99.8%
In not given at 200-300°C, 10 h, form of product is powder;	85%
at 270-320°C;

: 7440-23-5
sodium

: nickel dichloride

: 7440-02-0
nickel

Conditions

Conditions	Yield
Na-emulsion in organic solvent, at 220°C, form of product is powder;	99.2%
Na-emulsion in organic solvent, at 220°C, form of product is powder;	99.2%
explosive reaction;

: ((CO)NiNCN(CH3)2)2

A: 7440-02-0
nickel

B: 1467-79-4
NCNMe2

Conditions

Conditions	Yield
byproducts: CO; thermal dissociation in high vacuum;	A 99% B 99%

: {(CO)NiNCN(CH2)4}2

A: 1530-88-7
pyrrolidine-1-carbonitrile

B: 7440-02-0
nickel

Conditions

Conditions	Yield
byproducts: CO; thermal dissociation in high vacuum;	A 99% B 99%

: {(CO)NiNCN(CH2)2O(CH2)2}2

A: 1530-89-8
N-cyanomorpholine

B: 7440-02-0
nickel

Conditions

Conditions	Yield
byproducts: CO; thermal dissociation in high vacuum;	A 99% B 99%

: {(CO)NiNCN(CH2)4C(CH3)H}2

A: 5321-87-9
2-methylpiperidine-1-carbonitrile

B: 7440-02-0
nickel

Conditions

Conditions	Yield
byproducts: CO; thermal dissociation in high vacuum;	A 99% B 99%

: {(CO)NiNCN(CH2)2C6H4(CH2)}2

A: 1705-22-2
3,4-dihydro-2(1H)-isoquinolinecarbonitrile

B: 7440-02-0
nickel

Conditions

Conditions	Yield
byproducts: CO; thermal dissociation in high vacuum;	A 99% B 99%

: {(CO)NiNCN(CH2)6}2

A: 5321-89-1
hexahydroazepin-1-yl cianide

B: 7440-02-0
nickel

Conditions

Conditions	Yield
byproducts: CO; thermal dissociation in high vacuum;	A 99% B 99%

: [((C6H5)3P)3NiCl]2

A: 14264-16-5, 53996-95-5, 62075-39-2, 39716-73-9
bis(triphenylphosphine)nickel(II) chloride

B: 7440-02-0
nickel

C: nickel dichloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: triphenylphosphine; Ar-atmosphere; 140-180°C, 1 h; extn. (ether, CH2Cl2, H2O), evapn. of extract;	A 97.7% B 94.7% C 87.5%

...Expand

Raw Materials

603-35-0

637-27-4

Downstream Products

124-38-9

Total:191 Page 1 of 6 1 2 3 4 5 6 Next>>

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Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 264.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 11 ,1976,p. 75.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 2 ,1973,p. 126.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Community Right-To-Know List. Reported in EPA TSCA Inventory.

Standards and Recommendations

OSHA PEL: TWA Soluble Compounds: 0.1 mg(Ni)/m³; Insoluble Compounds: 1 mg(Ni)/m³
ACGIH TLV: TWA 0.1 mg(Ni)/m³; Not Suspected as a Human Carcinogen
DFG MAK: DFG TRK: Human Carcinogen
NIOSH REL: (Inorganic Nickel) TWA 0.015 mg(Ni)/m³

Analytical Methods

For occupational chemical analysis use OSHA: #ID-125G or NIOSH: Elements (ICP), 7300; Metals in Urine (ICP), 8310.

Specification

The Nickel, with the cas registry number 7440-02-0, has the systematic name of nickel(2+). For being a kind of silver white, hard, malleable metal chunks or grey powder, it is stable in massive form and may react violently with titanium, ammonium nitrate, potassium perchlorate, hydrazoic acid. Besides, it is incompatible with acids, oxidizing agents, sulfur.

The characteristics of this chemical are as follows: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 0; (5)Exact Mass: 57.935348; (6)MonoIsotopic Mass: 57.935348; (7)Heavy Atom Count: 1; (8)Covalently-Bonded Unit Count: 1.

As to its usage, it is used widely to make coins and nickel steel for armor plates and a component in Nichrome(R), and is also used as the burglar-proof vaultsPermalloy(R) and constantan. Besides, it is extensively used for making stainless steel and other corrosion-resistant alloys, such as Inconel(R),Invar(R),and the Hastelloys(R).

When you are dealing with this chemical, you should be very cautious. For one thing, it is irritant which may cause inflammation to the skin or other mucous membranes and may cause sensitization by skin contact. For another thing, it is harmful which may cause damage to health and may have limited evidence of a carcinogenic effect. In addition, it is corrosive which may destroy living tissue on contact and it may causes burns. Beside all these, it is highly flammable which may catch fire in contact with air, only needing brief contact with an ignition source, and it has a very low flash point or evolve highly flammable gases in contact with water. Then for being very toxic to aquatic organisms, it may cause long-term adverse effects in the aquatic environment.

Therefore, you should take different measures to deal with different cases. First important thing is to wear suitable protective clothing and gloves. And if in case of contact with eyes, rinse immediately with plenty of water and seek medical advice and if in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) When comes to its storage, keep it away from sources of ignition and heat. Then remember that this material and its container must be disposed of as hazardous waste. What's more, avoid releasing to the environment and you could also refer to special instructions / safety data sheets.

In addition, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: [Ni]
(2)InChI: InChI=1S/Ni
(3)InChIKey: PXHVJJICTQNCMI-UHFFFAOYSA-N

Below are the toxicity information of this chemical:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
cat	LDLo	subcutaneous	12500ug/kg (12.5mg/kg)		National Technical Information Service. Vol. PB158-508,
guinea pig	LDLo	oral	5mg/kg (5mg/kg)		Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 22, Pg. 455, 1980.
mouse	LDLo	intravenous	50mg/kg (50mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: FLUID INTAKE KIDNEY, URETER, AND BLADDER: PROTEINURIS	Farmakologiya i Toksikologiya Vol. 23, Pg. 549, 1960.
rabbit	LDLo	intraperitoneal	7mg/kg (7mg/kg)		National Technical Information Service. Vol. PB158-508,
rabbit	LDLo	subcutaneous	7500ug/kg (7.5mg/kg)		National Technical Information Service. Vol. PB158-508,
rat	LD50	intraperitoneal	250mg/kg (250mg/kg)	VASCULAR: REGIONAL OR GENERAL ARTERIOLAR OR VENOUS DILATION LIVER: OTHER CHANGES BLOOD: OTHER CHANGES	Industrial Medicine. Vol. 15, Pg. 482, 1946.
rat	LDLo	intratracheal	12mg/kg (12mg/kg)		National Technical Information Service. Vol. AEC-TR-6710,
rat	LDLo	oral	5gm/kg (5000mg/kg)		Food & Drug Research Laboratories, Inc., Papers. Vol. 7684D, Pg. 1983,