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76-84-6

Basic Information
CAS No.: 76-84-6
Name: Triphenylmethanol
Article Data: 607
Cas Database
Molecular Structure:
Molecular Structure of 76-84-6 (Triphenylmethanol)
Formula: C19H16O
Molecular Weight: 260.335
Synonyms: Methanol,triphenyl- (8CI);BL 3756;Hydroxytriphenylmethane;NSC 4050;Triphenylcarbinol;Triphenylmethyl alcohol;Tritanol;Tritylalcohol;U 45483;a,a-Diphenylbenzenemethanol;
EINECS: 200-988-5
Density: 1.13 g/cm3
Melting Point: 160-163 °C(lit.)
Boiling Point: 380 °C at 760 mmHg
Flash Point: 168.7 °C
Solubility: insoluble in water
Appearance: white powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 22-24/25-36-26
Transport Information: N/A
PSA: 20.23000
LogP: 3.97080
Synthetic route
76-83-5

trityl chloride

76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With water In tetrachloromethane100%
With water Kinetics; Rate constant; Mechanism; Two-phase systems;
With water In acetone at 25℃; Kinetics; ΔS, ΔH (excit.);
596-43-0

bromo-triphenyl-methane

691-88-3

di-sec-butyl mercury

A

76-84-6

triphenylmethyl alcohol

B

53213-46-0, 868-82-6

secondary-butyl mercury(II) bromide

C

78504-79-7

sec-butyl triphenylmethyl peroxide

Conditions
ConditionsYield
With oxygen; tetrabutylammomium bromide In 1,2-dichloro-ethane; benzene Product distribution; other reaction conditions;A n/a
B n/a
C 100%
With oxygen; tetrabutylammomium bromide In 1,2-dichloro-ethane Yields of byproduct given;A n/a
B n/a
C 76%
50653-07-1

trimethylsilyl triphenyl methyl ether

76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
Stage #1: trimethylsilyl triphenyl methyl ether With nitrogen dioxide at 20℃; for 0.833333h;
Stage #2: With water
100%
With methanol; 1,3-disulfonic acid imidazolium hydrogen sulfate at 20℃; for 0.0833333h; Green chemistry;99%
With montmorillonite K-10 In methanol for 4h; Ambient temperature;98%

2-(trityloxy)tetrahydro-2H-pyran

76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With acid-washed bentonite In acetone at 40 - 50℃; for 0.166667h;100%
519-73-3

triphenylmethane

76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With chromyl chloride In tetrachloromethane at 22℃; for 0.5h; ultrasound sonication;99%
With potassium hydroxide; 18-crown-6 ether; oxygen; dimethyl sulfoxide In 1,2-dimethoxyethane at 20℃; for 1.5h;97%
With chromium(VI) oxide; tetrabutylammonium periodite In dichloromethane; acetonitrile at -40℃; for 0.166667h;97%
18909-18-7

1-diphenylmethylene-4-trityl-2,5-cyclohexadiene

C41H48FeN7O(2+)*2CF3O3S(1-)

A

76-84-6

triphenylmethyl alcohol

C42H47F3FeN7O3S(1+)*CF3O3S(1-)

Conditions
ConditionsYield
In tetrahydrofuran; acetonitrile at 20℃; for 0.5h; Reagent/catalyst; Inert atmosphere; Glovebox;A 99%
B 83%
77134-74-8

4,5-dihydroxymethyl-1-triphenylmethylimidazole

A

33457-48-6

4,5-dihydroxymethylimidazole

B

76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With acetic acid for 1.5h; Heating;A 98.5%
B n/a
13141-87-2

N-benzyl-N’-(4-nitrophenyl)urea

71-43-2

benzene

76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With trifluorormethanesulfonic acid at 50℃; for 12h; Inert atmosphere;98%
93-58-3

benzoic acid methyl ester

591-51-5

phenyllithium

76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
In water at 25℃; for 0.00555556h; Solvent;98%
595-91-5

triphenylacetic acid

76-84-6

triphenylmethyl alcohol

Conditions
ConditionsYield
With potassium 12-tungstocobaltate(III) In water; acetonitrile for 0.2h; Microwave irradiation;96%
With 1H-imidazole; C17H16ClMnN2O2; tetrabutylammonium periodite In chloroform at 20℃; for 0.333333h;95%
With oxygen; mercury(II) oxide In methanol; acetonitrile at 25℃; UV-irradiation;88%
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Specification

Triphenylmethanol is also known as Trityl alcohol, Triphenylcarbinol, 76-84-6, Methanol, triphenyl-, Tritanol, Triphenylmethyl alcohol, triphenylmethan-1-ol. With the Molecular Formula C19H16O, it is an organic compound and a white crystalline solid that is insoluble in water and petroleum ether, but well soluble in ethanol, diethyl ether, and benzene. It reacts with acetyl chloride to give triphenylmethyl chloride.

Physical properties about Triphenylmethanol are: (1)ACD/LogP: 3.836; (2)ACD/LogD (pH 5.5): 3.84; (3)ACD/LogD (pH 7.4): 3.84; (4)ACD/BCF (pH 5.5): 484.72; (5)ACD/BCF (pH 7.4): 484.71; (6)ACD/KOC (pH 5.5): 2909.88; (7)ACD/KOC (pH 7.4): 2909.86; (8)#H bond acceptors: 1; (9)#H bond donors: 1; (10)#Freely Rotating Bonds: 4; (11)Index of Refraction: 1.622; (12)Molar Refractivity: 81.072 cm3; (13)Molar Volume: 230.289 cm3; (14)Polarizability: 32.14 10-24cm3; (15)Surface Tension: 46.4389991760254 dyne/cm; (16)Density: 1.13 g/cm3; (17)Flash Point: 168.744 °C; (18)Enthalpy of Vaporization: 66.255 kJ/mol; (19)Boiling Point: 379.999 °C at 760 mmHg

Preparation of Triphenylmethanol: The preparation of triphenylmethanol from methyl benzoate or benzophenone and bromobenzene is a common laboratory experiment for teaching the Grignard reaction. An alternative starting material is diethyl carbonate.

Synthesis_of_triphenylmethanol.png

When you are using this chemical, please be cautious about it as the following:
1. Do not breathe dust;
2. Avoid contact with skin and eyes;
3. Wear suitable protective clothing;
4. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice;

You can still convert the following datas into molecular structure:
(1)InChI=1S/C19H16O/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,20H;
(2)InChIKey=LZTRCELOJRDYMQ-UHFFFAOYSA-N;
(3)SmilesC(c1ccccc1)(c1ccccc1)(c1ccccc1)O;