Products Categories
| CAS No.: | 76189-55-4 |
|---|---|
| Name: | (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl |
| Article Data: | 43 |
| Cas Database | |
| Molecular Structure: | |
|
|
|
| Formula: | C44H32P2 |
| Molecular Weight: | 622.686 |
| Synonyms: | Phosphine,(1R)-[1,1'-binaphthalene]-2,2'-diylbis[diphenyl- (9CI);Phosphine,[1,1'-binaphthalene]-2,2'-diylbis[diphenyl-, (R)-;(+)-(1R)-[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine];(+)-BINAP;(1R)-[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine]; |
| EINECS: | -0 |
| Melting Point: | 239-242 °C |
| Boiling Point: | 724.3 °C at 760 mmHg |
| Flash Point: | 419 °C |
| Solubility: | insoluble in water |
| Appearance: | white to light yellow crystal powder |
| Hazard Symbols: |
 Xi, Xn
|
| Risk Codes: | 36/37/38-20/21/22 |
| Safety: | 22-24/25-37/39-26-36 |
| PSA: | 27.18000 |
| LogP: | 10.92580 |
- 76189-56-5Phosphine,1,1'-[(1S)-[1,1'-binaphthalene]-2,2'-diyl]bis[1,1-diphenyl-
- 761-89-7Carbamic acid,(aminocarbonyl)-, methyl ester (9CI)
- 76195-82-9Hydrazine,(2,4,6-trimethylphenyl)-, hydrochloride (1:?)
- 76-19-7Propane,1,1,1,2,2,3,3,3-octafluoro-
- 76197-35-82,3-Anthracenedicarboxaldehyde
- 76198-36-2Bicyclo[2.2.1]heptane-2-carboxylicacid, 3-amino-
- 76199-85-4Acetamide,2-cyano-2-[2,3-dihydro-3-(tetrahydro-2,4,6-trioxo-5(2H)-pyrimidinylidene)-1H-isoindol-1-ylidene]-N-methyl-
- 76202-21-6Ibogamine-18-methanol,14-[(3aR,6R)-2,3,3a,4,5,6-hexahydro-1H-indolo[3,2,1-de][1,5]naphthyridin-6-yl]-13-hydroxy-(9CI)
- 76202-23-8Ibogamine-18-carboxylicacid, 13-hydroxy-, methyl ester (9CI)
- 7620-28-2Hexanedioic acid,2-amino-, (2R)-
- 1079-66-9
chloro-diphenylphosphine
- 86688-08-6
(R)-2,2'-dibromo-1,1'-binaphthyl
- 76189-55-4
(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthalene
| Conditions | Yield |
|---|---|
| With n-butyllithium 1.) acetonitrile, -44 deg C, 30 min. 2.) -131 deg C, 30 min.; Yield given. Multistep reaction; |
- 76189-55-4
(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthalene
| Conditions | Yield |
|---|---|
| With dihydrogen peroxide In water; acetone | 92% |
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Chemistry
Molecular structure of (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (CAS NO.76189-55-4) is:
Product Name: (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
CAS Registry Number: 76189-55-4
Molecular Formula: C44H32P2
Molecular Weight: 622.68
Melting point: 239-242 °C
Water solubility: insoluble
Sensitive: Air Sensitive
Flash Point: 419 °C
Enthalpy of Vaporization: 102.01 kJ/mol
Boiling Point: 724.3 °C at 760 mmHg
Vapour Pressure: 5.55E-20 mmHg at 25°C
Product Categories: Biphenyl derivatives;chiral;Chiral Reagents;Asymmetric Synthesis;Phosphine Ligands;Synthetic Organic Chemistry;Adamantanes;B (Classes of Boron Compounds);Ligands;N-Heterocyclic Carbene Ligands;Tetrafluoroborates;Peptide;Chiral Compound
Safety Profile
Safty information about (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (CAS NO.76189-55-4) is:
Hazard Codes: 
Xi,Xn
Risk Statements: 36/37/38-20/21/22
R36/37/38:Irritating to eyes, respiratory system and skin.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
Safety Statements: 22-24/25-37/39-26-36
S22:Do not breathe dust.
S24/25:Avoid contact with skin and eyes.
S37/39:Wear suitable gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
WGK Germany: 3
F: 8-10-23
Specification
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl , its cas register number is 76189-55-4. It also can be called (R)-(+)-BINAP ; (R)-BINAP ; R-BINAP .It is a white to light yellow crystal powder.