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76674-21-0

Basic Information
CAS No.: 76674-21-0
Name: Flutriafol
Article Data: 7
Molecular Structure:
Molecular Structure of 76674-21-0 (Flutriafol)
Formula: C16H13F2N3O
Molecular Weight: 301.296
Synonyms: 1H-1,2,4-Triazole-1-ethanol, alpha-(2-fluorophenyl)-alpha-(4-fluorophenyl)-;Flutriafol [BSI:ISO];R 152450;(RS)-2,4-Difluoro-alpha-(1H-1,2,4-triazol-1-ylmethyl)benzhydryl alcohol;Flutriafol Tech;alpha-(2-Fluorophenyl)-alpha-(4-fluorophenyl)-1H-1,2,4-triazole-1-ethanol;1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1,2,4-triazol-1-yl)ethanol;Impact (pesticide);1H-1,2,4-Triazole-1-ethanol,R-(2-fluorophenyl)- R-(4-fluorophenyl)-;PP 450;
Density: 1.29 g/cm3
Melting Point: 130oC
Boiling Point: 506.5 °C at 760 mmHg
Flash Point: 260.1 °C
Solubility: 130 mg l-1 (pH 7,20 °C)
Appearance: solid
Hazard Symbols: HarmfulXn, FlammableF
Risk Codes: 22-36-20/21/22-11
Safety: 22-24/25-36-26
Transport Information: UN 1648 3/PG 2
PSA: 50.94000
LogP: 2.49240
Synthetic route
288-88-0

1,2,4-Triazole

1-(2-fluorophenyl)-1-(4-fluorophenyl)ethylene oxide

76674-21-0

flutriafol

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 140℃; for 0.333333h; Temperature;93.5%
With dimethyl sulfoxide at 130 - 140℃; for 2h; Temperature; Green chemistry;186 g
342-25-6

2,4'-difluorobenzophenone

76674-21-0

flutriafol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: dimethyl sulfoxide / Heating; Green chemistry
1.2: 3 h / 30 - 40 °C / Green chemistry
2.1: dimethyl sulfoxide / 2 h / 130 - 140 °C / Green chemistry
View Scheme
76674-21-0

flutriafol

A

586965-70-0

(S)-(+)-flutriafol

B

(R)-flutriafol

Conditions
ConditionsYield
In methanol; water; acetonitrile at 20℃; Reagent/catalyst; Solvent; Resolution of racemate;
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    Name: Flutriafol CAS: 76674-21-0 Molecular Formula: C16H13F2N3O Molecular Weight: 301.3 Properties: The pure article is white crystal; Melting point is 130℃;Solubility: At 20℃,solubility in water 130mg/L(PH7),in acetone 190g/L,in dichloromethan

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    Product Name: Flutriafol Synonyms: 1H-1,2,4-Triazole-1-ethanol, .alpha.-(2-fluorophenyl)-.alpha.-(4-fluorophenyl)-;flutriafol (ansi,bsi,iso);flutriafol solution;FLUTRIAFOLE;ALTOSUPER;1-(2-Fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-

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Chemistry

IUPAC Name: 1-(2-Fluorophenyl)-1-(4-fluorophenyl)-2-(1,2,4-triazol-1-yl)ethanol
Synonyms of Flutriafol (CAS NO.76674-21-0): (RS)-2,4'-Difluoro-alpha-(1H-1,2,4-triazol-1-ylmethyl)benzhydryl alcohol ; Impact (pesticide) ; PP 450 ; R 152450 ; alpha-(2-Fluorophenyl)-alpha-(4-fluorophenyl)-1H-1,2,4-triazole-1-ethanol ; 1H-1,2,4-Triazole-1-ethanol, alpha-(2-fluorophenyl)-alpha-(4-fluorophenyl)-
CAS NO: 76674-21-0
Classification Code: Agricultural Chemical ; Fungicide, bactericide, wood preservative
Molecular Formula of Flutriafol (CAS NO.76674-21-0): C16H13F2N3O
Molecular Weight: 301.2907
Molecular Structure:

Polar Surface Area: 39.94 Å2
Index of Refraction: 1.6
Molar Refractivity: 79.82 cm3
Molar Volume: 233.3 cm3
Surface Tension: 44.4 dyne/cm
Density of Flutriafol (CAS NO.76674-21-0): 1.29 g/cm3
Flash Point: 260.1 °C
Enthalpy of Vaporization: 81.75 kJ/mol
Boiling Point: 506.5 °C at 760 mmHg
Vapour Pressure: 4.43E-11 mmHg at 25°C
 

Uses

 Flutriafol (CAS NO.76674-21-0) is a major fungicide used in many world crops. It is used as the major active ingredient in the range of global seed treatments.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 oral 200mg/kg (200mg/kg)   Defense des Vegetaux. Vol. 38, Pg. 77, 1984.
mouse LD50 oral 179mg/kg (179mg/kg)   Defense des Vegetaux. Vol. 38, Pg. 77, 1984.
rabbit LD50 oral 200mg/kg (200mg/kg)   Defense des Vegetaux. Vol. 38, Pg. 77, 1984.
rabbit LD50 skin > 2gm/kg (2000mg/kg)   Pesticide Manual. Vol. 9, Pg. 427, 1991.
rat LD50 oral 1140mg/kg (1140mg/kg)   Pesticide Manual. Vol. 9, Pg. 427, 1991.
rat LD50 skin > 1gm/kg (1000mg/kg)   Pesticide Manual. Vol. 9, Pg. 427, 1991.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes: HarmfulXn,FlammableF
Risk Statements: 36-20/21/22-11 
R36: Irritating to eyes. 
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. 
R11: Highly flammable.
Safety Statements: 22-24/25-36-26 
S22: Do not breathe dust. 
S24/25: Avoid contact with skin and eyes. 
S36: Wear suitable protective clothing. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RIDADR: UN 1648 3/PG 2
RTECS: XZ4825000
A poison by ingestion. Moderately toxic by skin contact. When heated to decomposition it emits toxic vapors of NOx and F