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7681-65-4

Basic Information
CAS No.: 7681-65-4
Name: Copper(I) iodide
Article Data: 243
Molecular Structure:
Molecular Structure of 7681-65-4 (Copper(I) iodide)
Formula: CuI
Molecular Weight: 190.451
Synonyms: Coppermonoiodide;Copper(1+) iodide;Copper(I) iodide;Cuprous iodide(CuI);Copper iodide (CuI);
EINECS: 231-674-6
Density: 5.62 g/cm3
Melting Point: 605 °C(lit.)
Boiling Point: 1290 °C
Flash Point: 1290°C
Solubility: insoluble in water
Appearance: white to grey or tan powder
Hazard Symbols: HarmfulXn,DangerousN,IrritantXi
Risk Codes: 22-36/37/38-50/53
Safety: 22-24/25-26-61
Transport Information: UN 3077 9/PG 3
PSA: 0.00000
LogP: -2.99850
Synthetic route
Conditions
ConditionsYield
In tetrahydrofuran all operations in sealed evacuated tubes with thoroughly dried and degassed solvents; soln. of t-BuOCu added to a blue-green soln. of Sm complex; ppt. sepd. and washed with 10% HNO3; ppt. of CuI insoluble in HNO3 sepd. off; remaining soln. concd. and kept at 80° until complete dissolution of a fine ppt.; cooled slowly to ca. 20°; crystal sepd.; dried; identified by elem. anal., IR;A 100%
B 97.7%
C 92.3%
147312-03-6

LaI3(tetrahydrofuran)3

35342-67-7, 35342-68-8

copper (I) tert-butoxide

A

7681-65-4

copper(l) iodide

B

lanthanum tert-butoxycuprate

Conditions
ConditionsYield
In tetrahydrofuran all operations in sealed evacuated tubes with thoroughly dried and degassed solvents; soln. of the cuprate added to a soln. of La complex; stirred for 0.5 h at ca. 20° and for 2 h at 60°; ppt. of CuI sepd. by centrifugation; reaction mixt. concd. and kept at 80° until complete dissolution of a finely dispersed ppt.; cooledslowly to 20°; crystals sepd. and dried in vacuo; identified by elem. anal. and IR spectrum;A 90.2%
B 95%
113316-94-2

tris(tetrahydrofurane)triiodidoneodymium(III)

35342-67-7, 35342-68-8

copper (I) tert-butoxide

A

7681-65-4

copper(l) iodide

B

neodymium tert-butoxycuprate

Conditions
ConditionsYield
In tetrahydrofuran all operations in sealed evacuated tubes with thoroughly dried and degassed solvents; soln. of the cuprate added to a soln. of Nd complex; stirred for 0.5 h at ca. 20° and for 2 h at 60°; ppt. of CuI sepd. by centrifugation; reaction mixt. concd. and kept at 80° until complete dissolution of a finely dispersed ppt.; cooledslowly to 20°; crystals sepd. and dried in vacuo; identified by elem. anal. and IR spectrum;A n/a
B 90.3%

copper(II) choride dihydrate

7681-11-0

potassium iodide

7681-65-4

copper(l) iodide

Conditions
ConditionsYield
In water pptg. from a CuCl2*2H2O soln. with an excess of KI soln.; Debye-Scherrer XRD;
7553-56-2

iodine

7681-65-4

copper(l) iodide

Conditions
ConditionsYield
With copper(II) sulfate In not given iodine containing compounds used;
With alkali sulfite; copper(II) sulfate In not given iodine containing compounds used;
7553-56-2

iodine

7787-70-4

copper(I) bromide

7681-65-4

copper(l) iodide

Conditions
ConditionsYield
In water; xylene byproducts: CuBr2; shaking a soln. of CuBr in concd. Br(1-) soln. with I2 in xylol, reversible react.;;
7553-56-2

iodine

copper(l) chloride

7681-65-4

copper(l) iodide

Conditions
ConditionsYield
In water; xylene byproducts: CuCl2; shaking a soln. of CuCl in concd. Cl(1-) soln. with I2 in xylol, reversible react.;;
7553-56-2

iodine

copper(l) chloride

A

7681-65-4

copper(l) iodide

B

CuClI

Conditions
ConditionsYield
In ethanol Kinetics; alcoholic soln. of iodine addn. to AgCl in container with ground stopper, keeping for 2, 4 or 8 h at 60°C; X-ray diffraction;
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    Synonyms: Copper iodide (CuI);CuI;Hydro-giene;Marshite;COPPER(+1)IODIDE;COPPER IODIDE;COPPER(I) IODIDE;Ciras CAS: 7681-65-4 MF: CuI MW: 190.45 EINECS: 231-674-6 Product Categories: Inorganics;metal halide Mol File: 7681-65-4.mol Cuprous iodi

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Chemistry

IUPAC Name:copper(1+) iodide
Molecular Formula:CuI
Molecular Weight:190.45 
EINECS:231-674-6 
Density:5.62 g/mL at 25 °C(lit.)
Melting Point:605 °C
Boiling Point:1290 °C
Solubility:Insoluble in water
Sensitive:Air & Moisture Sensitive
Appearance:Off white powder
Cuprous iodide's(7681-65-4) Synonyms: Copper iodide (CuI);CuI;Hydro-giene;Marshite;COPPER(+1)IODIDE;COPPER IODIDE;COPPER(I) IODIDE;Ciras
Cuprous iodide's(7681-65-4) Molecular Structure:

Uses

Cuprous iodide(7681-65-4) can be used as a catalyst in organic reactions.

Safety Profile

When heated to decomposition it emits toxic fumes of I.

Safety Information of Cuprous iodide(7681-65-4)
Hazard Codes  Xn,N,Xi
Risk Statements  22-36/37/38-50/53
Safety Statements  22-24/25-26-61
RIDADR  UN 3077 9/PG 3
WGK Germany  3
F  8
HS Code  28276000

Standards and Recommendations

ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3

Specification

Stability and Reactivity of Cuprous iodide(7681-65-4)
【Disposal Code】15
【Incompatibilities】Oxidizing agents, alkali metals, potassium, acetylene.
【Stability】Stable under normal temperatures and pressures.
【Decomposition】Hydrogen iodide, iodine.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.