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7704-98-5

Basic Information
CAS No.: 7704-98-5
Name: Titanium hydride
Article Data: 2
Molecular Structure:
Molecular Structure of 7704-98-5 (Titanium hydride)
Formula: H2Ti
Molecular Weight: 49.8959
Synonyms: Hydrogen(-1) anion; titanium(+2) cation;Titanium hydride (TiH2);Ventron 89183;Titanium dihydride;
EINECS: 231-726-8
Density: 3.91
Melting Point: 225 °C
Flash Point: >400°C
Solubility: Insoluble in water and denser than water, soluble in absolute ethyl alcohol, ethyl ether, benzene and chloroform
Appearance: grey to black powder
Hazard Symbols: FlammableF
Risk Codes: 15-11
Safety: 7/8-43A-24/25-36/37/39-33-16
PSA: 0.00000
LogP: 0.00000
Synthetic route
7440-32-6

titanium

1333-74-0

hydrogen

A

20338-08-3

titanium(IV) hydroxide

B

7704-98-5

titanium dihydride

C

956378-98-6

[TiH(OH)3]

D

42765-12-8

titanium dihydroxide

E

HTiO(OH)

Conditions
ConditionsYield
In neat (no solvent) Irradiation (UV/VIS); laser ablated Zr co-deposited with H2+O2 in excess Ar onto a 10K CsI window, UV-irradiated, annealed at 22-34 K (mechanism discussed); not isolated, detected by IR;
7440-32-6

titanium

1333-74-0

hydrogen

32767-18-3

oxygen-18

A

7704-98-5

titanium dihydride

B

872215-20-8

Ti((18)OH)2

C

HTi(18)O((18)OH)

D

HTi((18)OH)3

E

872207-84-6

Ti((18)OH)4

Conditions
ConditionsYield
In neat (no solvent) laser ablated Zr co-deposited with H2+(18)O2 in excess Ar onto a 10K CsIwindow, annealed at 20 K (mechanism discussed); not isolated, detected by IR;
7440-32-6

titanium

1333-74-0

hydrogen

7704-98-5

titanium dihydride

Conditions
ConditionsYield
500°C, p(H2)= 1.5-2 MPa, according to: K. N. Semenenko, V. P. Malyshev, L. A. Petrova, et al., Izv. Akad. Nauk SSSR, Neorg. Mater. 13 (1977) 2009;

lanthanum nickel

7704-98-5

titanium dihydride

LaNi5H7.0

Conditions
ConditionsYield
components mixt. placing in glass vac. apparatus of Sieberts type, 20-25°C, P<1 atm; chem. anal.; X-ray diffraction, thermogravimetric and differential thermal anal.;
7704-98-5

titanium dihydride

1333-74-0

hydrogen

H0.71Ti

Conditions
ConditionsYield
TiH2 grinding (argon atmosphere), loading into autoclave, Ar traces removal (room temp., vac. until ca. 1 Pa reached), heating to 500-750°C, admitting calulated hydrogen amount, sytem equilibration (500°C, 1 h); gas volumetric anal.;
7704-98-5

titanium dihydride

1333-74-0

hydrogen

TiH0.85

Conditions
ConditionsYield
TiH2 grinding (argon atmosphere), loading into autoclave, Ar traces removal (room temp., vac. until ca. 1 Pa reached), heating to 500-750°C, admitting calulated hydrogen amount, sytem equilibration (500°C, 1 h); gas volumetric anal.;
7704-98-5

titanium dihydride

LaNi2.00

LaNi2H4.2

Conditions
ConditionsYield
components mixt. placing in glass vac. apparatus of Sieberts type, 20-25°C, P<1 atm; chem. anal.; X-ray diffraction, thermogravimetric and differential thermal anal.;

lanthanum nickel

7704-98-5

titanium dihydride

LaNiH3.1

Conditions
ConditionsYield
components mixt. placing in glass vac. apparatus of Sieberts type, 20-25°C, P<1 atm; chem. anal.; X-ray diffraction, thermogravimetric and differential thermal anal.;
7704-98-5

titanium dihydride

La3Ni

La3NiH8.5

Conditions
ConditionsYield
components mixt. placing in glass vac. apparatus of Sieberts type, 20-25°C, P<1 atm; chem. anal.; X-ray diffraction, thermogravimetric and differential thermal anal.;
7704-98-5

titanium dihydride

1333-74-0

hydrogen

titanium hydride

Conditions
ConditionsYield
TiH2 grinding (argon atmosphere), loading into autoclave, Ar traces removal (room temp., vac. until ca. 1 Pa reached), heating to 500-750°C, admitting calulated hydrogen amount, sytem equilibration (500°C, 1 h); gas volumetric anal.;
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Specification

The Titanium hydride, with the CAS registry number 7704-98-5, is also known as Hydrogen(-1) anion; titanium(+2) cation. It belongs to the product categories of Materials for Hydrogen Storage; Metal Hydrides; Metal Hydrides Alternative Energy; Reduction; Synthetic Reagents; Catalysis and Inorganic Chemistry; Metal Hydrides Chemical Synthesis; Titanium; Metal hydrides. Its EINECS number is 231-726-8. This chemical's molecular formula is H2Ti and molecular weight is 49.88. What's more, its systematic name is Titanium(2+) dihydride. This chemical should be sealed and stored in a cool and dry place. Moreover, it should be protected from oxides, acids, halogens, water and moisture. This chemical can be used in the manufacture of powder titanium, and it is also used for welding. It can be used as the catalyst of polymerization. Moreover, it is used as foaming agent in production of metal foams. It is also used to coat badminton racket string to improve durability.

When you are using this chemical, please be cautious about it as the following:
This chemical is highly flammable, so you should keep it away from sources of ignition - No smoking. When it contacts with water, it will liberate extremely flammable gases. You should keep the container tightly closed and dry, and you need to take precautionary measures against static discharges. When using it, you need wear suitable protective clothing, gloves and eye/face protection, and must avoid contact with skin and eyes.

You can still convert the following datas into molecular structure:
(1)SMILES: [H-].[H-].[Ti+2]
(2)Std. InChI: InChI=1S/Ti.2H/q+2;2*-1
(3)Std. InChIKey: KAZWGWWZKAHTKC-UHFFFAOYSA-N