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| CAS No.: | 7733-02-0 |
|---|---|
| Name: | Zinc sulphate |
| Article Data: | 240 |
| Molecular Structure: | |
|
|
|
| Formula: | ZnSO4 |
| Molecular Weight: | 161.454 |
| Synonyms: | Zinc sulfate (1:1);Zinc sulfate (ZnSO4);Zinc vitriol;Zinc(II) sulfate;Zincaps;Zincate;Zinco;Zincomed;Zin Sulphate Mono/Hepta;BiolectraZink;Bonazen;Bufopto Zinc Sulfate;Complexonat;Honny Fresh 10P;Kreatol;Op-Thal-Zin;Optraex;Solvazinc;Solvezink;Sulfuric acid zinc salt;Verazinc;White vitriol;Z-Span;Zinc sulfate; |
| EINECS: | 231-793-3 |
| Density: | 1.31 g/mL at 20 °C |
| Melting Point: | 100 °C |
| Boiling Point: | 330 °C at 760 mmHg |
| Solubility: | soluble in water |
| Appearance: | colorless solid |
| Hazard Symbols: |
 Xn, N, Xi
|
| Risk Codes: | 52-50-41-22-51/53 |
| Safety: | 61-39-26-60 |
| Transport Information: | UN 3082 9/PG 3 |
| PSA: | 82.98000 |
| LogP: | 0.42550 |
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| Conditions | Yield |
|---|---|
| In solid byproducts: H2O; mixt. heating in derivatograph in Pt crucible at 10 K/min in air up to 850°C; TG, DTG, DTA; | A 15.6% B n/a |
| In solid byproducts: H2O; mixt. heating in derivatograph in Pt crucible at 10 K/min in air up to 1000°C; TG, DTG, DTA; | A 0% B n/a |
| Conditions | Yield |
|---|---|
| byproducts: (CH3)2O; on react. of ZnCO3 with dimethyl sulfate in vacuum, evaporating of formed dimethyl ether (method of Recoura);; compd. free of H2O is obtained;; |
| Conditions | Yield |
|---|---|
| In water |
| Conditions | Yield |
|---|---|
| In water suspension of ZnS in H2O; reaction is fast in acidic H2O or an ozon dissolving liquid (eg. rosin oil);; | |
| In neat (no solvent) reaction with luminescence;; | |
| In neat (no solvent) reaction with luminescence;; |
| Conditions | Yield |
|---|---|
| In water slow oxidation with aq. K2S2O8;; | |
| In water slow oxidation with aq. K2S2O8;; |
| Conditions | Yield |
|---|---|
| With iron(II) sulfate In not given byproducts: Fe(OH)3; Zn production from industrial wastes; detailed description given;; ZnCl2 not isolated;; | |
| With FeSO4 In not given byproducts: Fe(OH)3; Zn production from industrial wastes; detailed description given;; ZnCl2 not isolated;; | |
| With iron(II) sulfate In not given byproducts: Fe(OH)3; Zn production from industrial wastes; detailed description given;; ZnCl2 not isolated;; |
- 7733-02-0
zinc(II) sulfate
| Conditions | Yield |
|---|---|
| With sulfur dioxide In neat (no solvent) in presence of O2, starting of react. at 350 °C;; | |
| With sulfuric acid In sulfuric acid leaching the oxide roast with sulfuric acid; amt. of formed ZnSo4 is depending on temp. of H2SO4;; | |
| With sulfuric acid In sulfuric acid leaching the oxide roast with sulfuric acid;; |
| Conditions | Yield |
|---|---|
| With oxygen Kinetics; 920 - 1200 K, in a fixed bed reactor; |
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Chemistry
IUPAC Name:zinc sulfate
Molecular Formula: O4SZn
Molecular Weight: 161.471600 g/mol
Appearance: Colorless to slightly green, odorless solid
Melting Point: 100°C
Boiling Point: 330 °C at 760 mmHg
EINECS: 231-793-3
Density: 1.31 g/mL at 20 °C
Water Solubility: Soluble
Merck: 14,10159
Synonyms of Zinc sulfate (CAS NO.7733-02-0): AI3-03967 ; Bonazen ; Bufopto zinc sulfate ; CCRIS 3664 ; Caswell No. 927 ; Complexonat ; EINECS 231-793-3 ; EPA Pesticide Chemical Code 089001 ; HSDB 1063 ; Medizinc ; NSC 135806 ; NSC 32677 ; NU-Z ; Neozin ; OP-Thal-zin ; Optised ; Optraex ; Orazinc ; Prefrin-Z ; Solvezinc ; Solvezink ; Sulfate de zinc ; Sulfate de zinc [French] ; Sulfuric acid zinc salt (VAN) ; Sulfuric acid, zinc salt ; Sulfuric acid, zinc salt (1:1) ; UNII-0J6Z13X3WO ; Verazinc ; Visine-ac ; White copperas ; White vitriol ; White vitriol (VAN) ; Zinc sulfate (1:1) ; Zinc sulfate (ZnSO4) ; Zinc sulfate anhydrous ; Zinc sulphate ; Zinc vitriol ; Zinc vitriol (VAN) ; Zinc-200 ; Zincate ; Zinci Sulfas ; Zincomed ; Zincum Sulfuricum ; Zink-Gro ; Zinklet ; Zinkosite ; component of Phenylzin
Categories: Inorganics;Volumetric Solutions ; BioUltraProtein Structural Analysis ; Molecular Biology ; Molecular Biology Reagents ; Optimization Reagents ; X-Ray Crystallography ; Complexometric Solutions (IDRANAL)Volumetric Solutions ; Complexometric Titration (IDRANAL) ; S - Z;Salt Solutions ; Titration ; Complexometric Concentrates (IDRANAL)Titration ; Concentrates (e.g. FIXANAL) ; Salt Concentrates
Uses
Zinc sulfate (CAS NO.7733-02-0) is used to supply zinc in fertilizers, animal feeds , and agricultural sprays. it is used in making lithopone, in electrolytes for zinc plating, as a mordant in dyeing, as a preservative for skins and leather and in medicine as an emetic.
Production
Zinc sulfate (CAS NO.7733-02-0) can be prepared by adding solid zinc to a copper(II) sulfate solution. Zn + CuSO4 → ZnSO4 + Cu
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| dog | LDLo | intravenous | 66mg/kg (66mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
| dog | LDLo | subcutaneous | 78mg/kg (78mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
| human | TDLo | oral | 45mg/kg/7D-C (45mg/kg) | CARDIAC: PULSE RATE INCREASE WITHOUT FALL IN BP GASTROINTESTINAL: OTHER CHANGES BLOOD: NORMOCYTIC ANEMIA | British Medical Journal. Vol. 1, Pg. 754, 1978. |
| human | TDLo | oral | 106mg/kg (106mg/kg) | VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" | British Medical Journal. Vol. 1, Pg. 1390, 1977. |
| man | TDLo | oral | 180mg/kg/6W-I (180mg/kg) | BLOOD: OTHER CHANGES | JAMA, Journal of the American Medical Association. Vol. 252, Pg. 1443, 1984. |
| mouse | LD50 | intraperitoneal | 29060ug/kg (29.06mg/kg) | Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 256, Pg. 1043, 1963. | |
| mouse | LD50 | intravenous | 23300ug/kg (23.3mg/kg) | Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991. | |
| mouse | LD50 | oral | 245mg/kg (245mg/kg) | Yaoxue Tongbao. Bulletin of Pharmacology. Vol. 22, Pg. 230, 1987. | |
| mouse | LD50 | subcutaneous | 781mg/kg (781mg/kg) | GASTROINTESTINAL: CHANGES IN PANCREATIC WEIGHT BLOOD: "CHANGES IN SERUM COMPOSITION (E.G., TP, BILIRUBIN, CHOLESTEROL)" | Japanese Journal of Toxicology and Environmental Health. Vol. 44, Pg. 305, 1998. |
| rabbit | LD50 | oral | 2gm/kg (2000mg/kg) | International Polymer Science and Technology. Vol. 3, Pg. 93, 1976. | |
| rabbit | LDLo | intravenous | 23mg/kg (23mg/kg) | Toxicology and Applied Pharmacology. Vol. 9, Pg. 269, 1966. | |
| rabbit | LDLo | subcutaneous | 300mg/kg (300mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
| rat | LD50 | intraperitoneal | 196mg/kg (196mg/kg) | Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991. | |
| rat | LD50 | intravenous | 69900ug/kg (69.9mg/kg) | Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991. | |
| rat | LD50 | oral | 1710mg/kg (1710mg/kg) | Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991. | |
| rat | LDLo | subcutaneous | 330mg/kg (330mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
| women | TDLo | oral | 3120mg/kg/43W (3120mg/kg) | BLOOD: MICROCYTOSIS WITH OR WITHOUT ANEMIA BLOOD: AGRANULOCYTOSIS | Gastroenterology. Vol. 94, Pg. 508, 1988. |
Safety Profile
Safety Information of Zinc sulfate (CAS NO.7733-02-0):
Hazard Codes:Xn,Xi 
,N 
Risk Statements:52/53-50/53-41-22-51/53
52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
41:Risk of serious damage to eyes
22:Harmful if swallowed
51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements:61-39-26-60
61:Avoid release to the environment. Refer to special instructions safety data sheet
39:Wear eye/face protection
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
60:This material and/or its container must be disposed of as hazardous waste
RIDADR:UN 3082 9/PG 3
WGK Germany:3
RTECS:ZH5260000
Specification
First Aid Measures of Zinc sulfate (CAS NO.7733-02-0):
Ingestion:Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
Inhalation:If fumes or combustion products are inhaled, remove to fresh air. Lay victim down and keep warm and rested. If breathing is shallow, or has stopped, ensure clear airway and apply resuscitation. Transport to a hospital or doctor immediately.
Skin:If this product comes into contact with skin, wash skin with soap and water. Remove contaminated clothing and footwear. Ensure contaminated clothing is thoroughly washed before using again. Transport to hospital or doctor if symptoms develop.
Eyes:If this product comes into contact with eyes, hold eyes open and wash continuously for 15 minutes with running water. Ensure irrigation under eyelids by occasionally lifting eyelids. Do not attempt to remove contact lenses unless trained. Transport to a hospital or doctor immediately.
Storage of Zinc sulfate (CAS NO.7733-02-0): Keep well closed.