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7758-94-3

Basic Information
CAS No.: 7758-94-3
Name: Iron(II) chloride
Article Data: 3
Cas Database
Molecular Structure:
Molecular Structure of 7758-94-3 (Iron(II) chloride)
Formula: FeCl2
Molecular Weight: 126.753
Synonyms: Ferrous chloride (FeCl2);Iron dichloride;Iron protochloride;Iron(2+) chloride;Iron(II)chloride;Iron chloride;
EINECS: 231-843-4
Density: 3.16 g/mL at 25 °C(lit.)
Melting Point: 677 °C(lit.)
Boiling Point: 1023 °C
Flash Point: 1023oC
Appearance: greenish white crystalline solid
Hazard Symbols: CorrosiveC
Risk Codes: 22-34
Safety: 26-36/37/39-45
Transport Information: UN 3260 8/PG 3
PSA: 0.00000
LogP: -5.99450
Synthetic route

silver(I) chloride

7758-94-3

iron(II)chloride

Conditions
ConditionsYield
In solid matrix mixt. of metal (tenfold excess) and AgCl heated in Ar (400 Torr) until react. was complete; cooled, evacuated, co-condensed with solid matrix (N2, Ar);
27846-09-9

iron monochloride

10049-05-5

chromium (II) chloride

A

49681-65-4

chromium monochloride

B

7758-94-3

iron(II)chloride

Conditions
ConditionsYield
In neat (no solvent, gas phase) equilibrium reaction was studied at 1349-1596 K;
7647-01-0

hydrogenchloride

7758-94-3

iron(II)chloride

Conditions
ConditionsYield
In neat (no solvent) isolation in N2 solid matrix;
201230-82-2

carbon monoxide

7758-94-3

iron(II)chloride

Conditions
ConditionsYield
In neat (no solvent) FeCl2 vapor cocondensed with argon doped with CO;
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    Name Ferrous chloridee Synonyms Iron dichloride CAS NO. 7758-94-3 Molecular Formula FeCl2 Molecular Weight 126.75

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  • Iron(II) chloride(FeCl2)

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    7758-94-3

    Iron(II) chloride(FeCl2)

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  • Ferrous chloride

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    7758-94-3

    Ferrous chloride

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  • Ferrous chloride

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    7758-94-3

    Ferrous chloride

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  • CAS: 7758-94-3 Ferrous chloride

  • Casno:

    7758-94-3

    CAS: 7758-94-3 Ferrous chloride

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  • Ferrous Chloride Anhydrous

  • Casno:

    7758-94-3

    Ferrous Chloride Anhydrous

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Consensus Reports

Ferrous chloride(7758-94-3) is reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Standards and Recommendations

OSHA PEL: TWA 1 mg(Fe)/m3
ACGIH TLV: TWA 1 mg(Fe)/m3
DOT Classification:  8; Label: Corrosive

Specification

The Ferrous chloride with CAS registry number of 7758-94-3 is also called Iron chloride. The IUPAC name is dichloroiron. Its EINECS registry number is 231-843-4. In addition, the molecular formula is Cl2Fe and the molecular weight is 126.75. It is a kind of off-white solid and belongs to the class of Inorganics. And it is soluble in water, methanol and ethanol, and slightly soluble in acetone and benzene. But it is insoluble in ether. What's more, it should be stored in sealed container, and put in a cool and dry place.

Preparation of Ferrous chloride: it can be prepared by ferric chloride and dry hydrogen. The equation as follows: 2FeCl3 + H2 → 2FeCl2 + 2HCl. In addition, it can be obtained from hydrochloric acid and iron. The equation as follows: Fe + 2HCl → FeCl2 + H2. Besides, it is conveniently prepared by addition of iron powder to a solution of methanol and concentrated hydrochloric acid under an inert atmosphere. An alternative laboratory synthesis of FeCl2 entails the reaction of FeCl3 with chlorobenzene: 2FeCl3 + C6H5Cl → 2FeCl2 + C6H4Cl2 + HCl.

Uses of Ferrous chloride: it can be used as a reducing flocculating agent in wastewater treatment, especially for wastes containing chromate. And it can be used for mordant, analytical reagent and unleaded gasoline additives. In addition, it can react with two molar equivalents of [(C2H5)4N]Cl to give the salt [(C2H5)4N]2[FeCl4].

When you are using this chemical, please be cautious about it as the following:
This chemical is harmful if swallowed and can cause burns. During using it, wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. And in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.).

You can still convert the following datas into molecular structure:
(1)SMILES: Cl[Fe]Cl
(2)InChI: InChI=1/2ClH.Fe/h2*1H;/q;;+2/p-2
(3)InChIKey: NMCUIPGRVMDVDB-NUQVWONBAL

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 59mg/kg (59mg/kg)   Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 244, Pg. 17, 1962.
rat LD50 oral 450mg/kg (450mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 39(5), Pg. 16, 1974.