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7789-67-5

Basic Information
CAS No.: 7789-67-5
Name: TIN(IV) BROMIDE
Article Data: 100
Molecular Structure:
Molecular Structure of 7789-67-5 (TIN(IV) BROMIDE)
Formula: Br4Sn
Molecular Weight: 438.326
Synonyms: Tin bromide(SnBr4) (6CI,8CI); Stannic bromide; Tetrabromostannane; Tetrabromotin; Tintetrabromide; Tin(IV) bromide
Density: 3.34 g/mL at 25 °C(lit.)
Melting Point: 11414oC
Boiling Point: 202 °C(lit.)
Flash Point: 202°C/734mm
Solubility: Very soluble in water. Soluble in ethyl alcohol.
Hazard Symbols: Irritant to skin and eyes. TLV: 2 mg(Sn)/m3.
Risk Codes: R34;
Safety: Poison by intravenous route. Violent reaction with NO2Cl. When heated to decomposition it emits toxic fumes of Br. See also BROMIDES and TIN COMPOUNDS.
PSA: 0.00000
LogP: 3.00160
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Chemistry


IUPAC Name: tetrabromostannane
Molecular Weight: 438.326 g/mol
Molecular Formula: Br4Sn
Density: 3.34 g/mL at 25 °C(lit.)
Flash Point: 202°C/734 mmHg 
Melting Point: 31 °C(lit.)
Boiling Point: 202 °C(lit.)
Appreance: white to light yellow crystalline solid
EINECS: 232-184-5 
Merck: 14,8773
Mol File: 7789-67-5.mol
Canonical SMILES: Br[Sn](Br)(Br)Br
InChI: InChI=1S/4BrH.Sn/h4*1H;/q;;;;+4/p-4
InChIKey: LTSUHJWLSNQKIP-UHFFFAOYSA-J
Exact Mass: 439.571454
MonoIsotopic Mass: 435.575547
Heavy Atom Count: 5
Complexity: 19.1 
Sensitive: Tin(iv) bromide (1:4) (CAS NO.7789-67-5) is sensitive to air and moisture
Synonyms of Tin(iv) bromide (1:4) (CAS NO.7789-67-5): Stannic bromide ; Stannic tetrabromide ; Tin tetrabromide ; Tin bromide

Toxicity Data With Reference

1.    

ivn-mus LD50:18 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#02222 .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intravenous route. Violent reaction with NO2Cl. When heated to decomposition it emits toxic fumes of Br. See also BROMIDES and TIN COMPOUNDS.
Hazard Codes: CorrosiveC
Risk Statements: 14-34-37 
R14: Reacts violently with water
R34: Causes burns 
R37: Irritating to respiratory system
Safety Statements: 26-36/37/39-45-7/8 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible) 
S7: Keep container tightly closed
S8: Keep container dry
RIDADR UN: 3260 8/PG 2
WGK Germany: 3
RTECS XP: 8300000
F: 1-10
TSCA: Yes
HazardClass: 8
PackingGroup: II 

Standards and Recommendations

OSHA PEL: TWA 2 mg(Sn)/m3
ACGIH TLV: TWA 2 mg(Sn)/m3

Specification

 Tin(iv) bromide (1:4) (CAS NO.7789-67-5) is high toxic.It can  produce toxic gases on contact with water.It also can produce toxic gases by heat.The hydrolyzate of  Tin(iv) bromide (1:4) (CAS NO.7789-67-5) is corrosive to skin and cornea. So the storage environment should be ventilate, low-temperature and dry.