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7790-86-5

Basic Information
CAS No.: 7790-86-5
Name: Cerium(III) chloride
Article Data: 96
Cas Database
Molecular Structure:
Molecular Structure of 7790-86-5 (Cerium(III) chloride)
Formula: CeCl3
Molecular Weight: 246.479
Synonyms: Cerium trichloride;Cerium chloride (CeCl3);Cerous chloride;Cerous(III) chloride;
EINECS: 232-227-8
Density: 3.97 g/mL at 25 °C(lit.)
Melting Point: 848 °C(lit.)
Boiling Point: 1727 °C
Flash Point: 1727°C
Solubility: N/A
Appearance: white powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36
Transport Information: N/A
PSA: 0.00000
LogP: -8.98800
Synthetic route

([Ce(μ-Cl)(H2O)7](Cl)2)2

7790-86-5

cerium chloride

Conditions
ConditionsYield
In neat (no solvent, solid phase) byproducts: H2O; Schlenk techniques; heating Ce compd. under vacuum (1E-3 Torr);99%

cerium(III) sulfate pentahydrate

ammonium chloride

7790-86-5

cerium chloride

Conditions
ConditionsYield
In neat (no solvent, solid phase) byproducts: H2O, NH3; a mixt. of Ce-contg. compd. and NH4Cl (2.5-fold excess) was gradually heated to 830°C under He for 12 h; chem. anal.;96.4%

cerium(IV) oxide

7790-86-5

cerium chloride

Conditions
ConditionsYield
With HCl In hydrogenchloride; formic acid (N2 or Ar); stirring the mixt. of CeO2, HCl (37 %) and HCOOH under reflux for 24 h;; evapn. of the soln. to dryness; dehydration of the remaining solid under vacuum (0.01 mm Hg) at ca. 170°C; for 48 h; elem. anal.;;96%
With complex compd. of PCl5 and AlCl3 according to: L. A. Nisel'son, Yu. N. Lyzlov, K. V. Tret'yakova, Zh. Neorg. Khim.20 (1975) 2362; elem. anal., X-ray diffraction;
In not given

cerium(IV) oxide

aluminium chloride dimer

A

aluminum oxochloride

B

7790-86-5

cerium chloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: Cl2; Al2Cl6 prepd. from Al and Cl2; in Duran tube, at 500°C (Cl2); chemical vapour phase transport with Al2Cl6 from 500 to 400°C, 24 h;A n/a
B 41%
917-54-4

methyllithium

A

34557-54-5

methane

B

7790-86-5

cerium chloride

C

1310-65-2

lithium hydroxide

Conditions
ConditionsYield
In tetrahydrofuran (vac.);A 40%
B n/a
C n/a

cerium(III) chloride heptahydrate

ammonium chloride

7790-86-5

cerium chloride

Conditions
ConditionsYield
In neat (no solvent) absence of moisture; large excess NH4Cl, evacuated quartz tube, 500-600 K; sublimation off of excess NH4Cl (vac., 700 K);
cerium chloride monohydrate

cerium chloride monohydrate

7790-86-5

cerium chloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2O; sample heating at 120-140°C until weight loss reached the calculated value; gravimetric monitoring;

cerium(III) chloride hydrate

7790-86-5

cerium chloride

Conditions
ConditionsYield
With ammonium chloride In neat (no solvent) byproducts: H2O; mixing CeCl3*99H2O with an excess of NH4Cl, firing at 500°C for 1 h in a H2 atmosphere;
With NH4Cl Taylor M.D., Carter C.P., J. Inorg. Nucl. Chem. 1962, 24, 387;

cerium(III) oxide

potassium chloride

A

7790-86-5

cerium chloride

B

potassium oxide

Conditions
ConditionsYield
In melt 1100°C;
In melt 1100°C;
75-44-5

phosgene

cerium(III) oxide

7790-86-5

cerium chloride

Conditions
ConditionsYield
In neat (no solvent) passing stream of COCl2 over Ce2O3 at 600 °C;;
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Specification

The Cerium chloride, with the CAS registry number 7790-86-5, is also known as Cerous chloride. It belongs to the product categories of Inorganics; Ce (Cerium) Compounds; Classes of Metal Compounds; Transition Metal Compounds; Metal Halide. Its EINECS registry number is 232-227-8. This chemical's molecular formula is CeCl3 and molecular weight is 246.48. What's more, its systematic name is called Cerium(3+) trichloride. It can be made by dehydration of the hydrate either by slowly heating to 400 °C with 4-6 equivalents of ammonium chloride under high vacuum, or by heating with an excess of thionyl chloride for three hours. Cerium(III) chloride can be used as a starting point for the preparation of other cerium salts, such as the Lewis acid, cerium(III) trifluoromethanesulfonate, used for Friedel-Crafts acylations. It is also used itself as a Lewis acid, for example as a catalyst in Friedel-Crafts alkylation reactions.

Physical properties about Cerium chloride are: (1)Density: 3.97 g/cm3; (2)Flash Point: 1727 °C; (3)Melting point: 848 °C(lit.); (4)Boiling Point: 1727 °C at 760 mmHg.

Uses of Cerium chloride: it is used to produce other chemicals. For example, it can react with sodium borohydride to get allylic alcohol.

Cerium chloride can react with sodium borohydride to get allylic alcohol.

When you are dealing with this chemical, you should be very careful. This chemical is inflammation to the skin, eyes and respiratory system or other mucous membranes. Therefore, you should wear suitable protective clothing. In case of contacting with eyes, you should rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1) SMILES: [Cl-].[Cl-].[Cl-].[Ce+3]
(2) InChI: InChI=1S/Ce.3ClH/h;3*1H/q+3;;;/p-3
(3) InChIKey: VYLVYHXQOHJDJL-UHFFFAOYSA-K

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LDLo intravenous 60mg/kg (60mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
frog LD50 subcutaneous 211mg/kg (211mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
guinea pig LD50 intraperitoneal 104mg/kg (104mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ANOREXIA (HUMAN

BEHAVIORAL: MUSCLE WEAKNESS
AMA Archives of Industrial Health. Vol. 15, Pg. 9, 1957.
mouse LD50 intraperitoneal 97849ug/kg (97.849mg/kg)   Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 256, Pg. 1043, 1963.
mouse LD50 oral 5277mg/kg (5277mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
mouse LDLo subcutaneous 4gm/kg (4000mg/kg)   Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 188, Pg. 465, 1938.
rat LD50 intravenous 6262ug/kg (6.262mg/kg) LIVER: "HEPATITIS (HEPATOCELLULAR NECROSIS), DIFFUSE" Acta Physiologica Polonica. Vol. 32, Pg. 205, 1981.
rat LD50 oral 2111mg/kg (2111mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LDLo subcutaneous 4gm/kg (4000mg/kg) BEHAVIORAL: TREMOR

BEHAVIORAL: EXCITEMENT

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 100, Pg. 230, 1923.