CAS No.7790-98-9,Ammonium perchlorate Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	7790-98-9
Name:	Ammonium perchlorate
Article Data:	33

Formula:	H₄ClNO₄
Molecular Weight:	117.489
Synonyms:	Perchloricacid, ammonium salt (8CI,9CI);Ammonium perchlorate(NH4ClO4);Arcadene 426;Arcite 155;Arcite 322;Dyno AP;HT 398;NK 270;PChA;PKhA;Perchloricacid,ammoniumsalt;
EINECS:	232-235-1
Density:	1.95 g/cm³
Melting Point:	°Cd ec.)
Appearance:	white crystalline solid or powder
Hazard Symbols:	O
Risk Codes:	9-44
Safety:	17-36/37-27-16-14
Transport Information:	UN 1442
PSA:	74.27000
LogP:	0.59050

Synthetic route

: 7601-90-3
perchloric acid

: 302-01-2
hydrazine

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
ammonium molybdate In perchloric acid Kinetics; byproducts: N2, HCl; 90°C;

: 7601-90-3
perchloric acid

: ammonium nitrate

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In sulfuric acid; water heating;;

: 7601-90-3
perchloric acid

: 7664-41-7
ammonia

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In water
In not given
In not given pure NH3 introduced in dild. soln. of HClO4;

: ammonium chloride

: sodium perchlorate

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In not given
In not given

: ammonium chloride

: calcium perchlorate

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
With calcium hydroxide In not given byproducts: CaCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;
With Ca(OH)2 In not given byproducts: CaCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;

: magnesium(II) perchlorate

: ammonium chloride

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
With calcium hydroxide In not given byproducts: MgCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;
With Ca(OH)2 In not given byproducts: MgCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;

: 7601-90-3
perchloric acid

: 103809-62-7
bisamminesilver(I) perchlorate

A: 7790-98-9
ammonium perchlorate

B: silver perchlorate

Conditions

Conditions	Yield
In water
In water

...Expand

: ammonium carbonate

: 7601-90-3
perchloric acid

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In water addn. of a calcd. amt. of HClO4 to aq. soln. of (NH4)2CO3 made in freshly distd. water; recrystn. from water, dried in vac. above P2O5 at 110 °C;

: 15588-62-2
hydroxylammonium perchlorate

A: 7601-90-3
perchloric acid

B: 7790-98-9
ammonium perchlorate

C: 7732-18-5
water

D: 7782-50-5
chlorine

E: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
With perchloric acid; ammonia In solid Kinetics; further products; in sealed glass at 80°C; rate of decomp. depends on reagent concn.;
With perchloric acid; ammonia In neat (no solvent) Kinetics; further reagents, further products; in sealed glass (P=25-30 atm.) at 113.5-150.0°C; rate of decomp. depends on conditions and reagent concn.; MAS, IR;

...Expand

: 15588-62-2
hydroxylammonium perchlorate

: calcium carbonate

A: 7790-98-9
ammonium perchlorate

B: calcium perchlorate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: N2, CO2, H2O; molar ratio (NH3OH)ClO4:CaCO3=3:1, heating in vac. (110-130°C, 3.5 h, then 130-145°C, 2 h);

...Expand

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Chemistry

IUPAC Name: Azanium perchlorate
Molecular Formula: NH₄ClO₄
Molecular Weight: 117.49
EINECS: 232-235-1
Density: 1.95 g/cm³
Polar Surface Area: 71.44 Å²
Appearance: A white, crystalline solid or powder
Solubility: Freely soluble in water. Soluble in methanol. Slightly soluble in ethanol, acetone. Insoluble in ether, ethyl acetate
Stability: Explosive when mixed with combustible material. Incompatible with organics, paper, wood shavings, etc. May explode if heated under confinement or as a result of friction. Incompatible with metals, reducing agents, strong acids.
Synonyms of Perchloricacid,ammoniumsalt (CAS NO.7790-98-9): Ammoniumperchlorate(nh4clo4) ; Ammoniumperchlorate,[highexplosive] ; Perchlorated’ammonium ; Perchloricacid,ammoniumsalt ; Perchloricacidammoniumsalt ; Pkha ; Ammonium Perchlorate ; Ammonium perchorate
Product Categories: Industrial/Fine Chemicals ; Inorganics ; Synthetic Reagents ; Ammonium SaltsSynthetic Reagents ; Metal and Ceramic Science ; Oxidation ; Perchlorates ; Salts
Following is the molecular structure of Perchloricacid,ammoniumsalt (CAS NO.7790-98-9):

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
guinea pig	LD50	oral	3310mg/kg (3310mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: ATAXIA BEHAVIORAL: COMA	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 28(8), Pg. 8, 1963.
mouse	LC	inhalation	> 300mg/m3 (300mg/m3)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD GASTROINTESTINAL: NAUSEA OR VOMITING LIVER: LIVER FUNCTION TESTS IMPAIRED	"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 15, 1999.
mouse	LD50	oral	1900mg/kg (1900mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: ATAXIA BEHAVIORAL: COMA	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 28(8), Pg. 8, 1963.
mouse	LD50	subcutaneous	940mg/kg (940mg/kg)		"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 15, 1999.
mouse	LDLo	parenteral	2gm/kg (2000mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: EXCITEMENT LUNGS, THORAX, OR RESPIRATION: DYSPNEA	Russian Pharmacology and Toxicology Vol. 32, Pg. 159, 1969.
rabbit	LD50	oral	1900mg/kg (1900mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: ATAXIA BEHAVIORAL: COMA	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 28(8), Pg. 8, 1963.
rabbit	LDLo	parenteral	750mg/kg (750mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: EXCITEMENT LUNGS, THORAX, OR RESPIRATION: DYSPNEA	Russian Pharmacology and Toxicology Vol. 32, Pg. 159, 1969.
rat	LC	inhalation	> 300mg/m3 (300mg/m3)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD GASTROINTESTINAL: NAUSEA OR VOMITING LIVER: LIVER FUNCTION TESTS IMPAIRED	"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 15, 1999.
rat	LD50	oral	4200mg/kg (4200mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: ATAXIA BEHAVIORAL: COMA	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 28(8), Pg. 8, 1963.
rat	LD50	subcutaneous	1600mg/kg (1600mg/kg)		"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 15, 1999.
rat	LDLo	parenteral	3500mg/kg (3500mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: EXCITEMENT LUNGS, THORAX, OR RESPIRATION: DYSPNEA	Russian Pharmacology and Toxicology Vol. 32, Pg. 159, 1969.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Safety Information of Perchloricacid,ammoniumsalt (CAS NO.7790-98-9):
Hazard Codes: O
O: Oxidizing
Risk Statements: 9-44
9: Explosive when mixed with combustible material
44: Risk of explosion if heated under confinement
Safety Statements: 17-36/37-27-16-14
17: Keep away from combustible material
36/37: Wear suitable protective clothing and gloves
27: Take off immediately all contaminated clothing
16: Keep away from sources of ignition - No smoking
14: Keep away from ... (incompatible materials to be indicated by the manufacturer)
RIDADR: 1442
WGK Germany: 1
Moderately toxic by ingestion and parenteral routes. Flammable when exposed to heat or flame or by spontaneous chemical reaction with reducing materials. A very powerful oxidizer that has caused explosions in industry. Ignites violently with combustibles. Severe explosion hazard; decomposes at 130° and explodes at 380°. When contaminated by powdered carbon, ferrocene, S, organic matter, powdered metals, nitryl perchlorate, potassium periodate, potassium permanganate, it becomes impact sensitive. Potentially explosive reactions with carbon (above 240°C), dichrom-ium trioxide (at 270°C), cadmium oxide (at 260°C), zinc oxide (at 200°C), copper chromite, copper oxide, iron oxide, potassium permanganate, potassium dichromate, mono-, di-, tri-, or tetra-methylammonium perchlorates, metal perchlorates (e.g., lithium perchlorate, zinc perchlorate), nitrophenol-formaldehyde polymer. Mixtures with aluminum or copper burn violently when ignited. Mixtures with ethylene dinitrate ignite when stored at 60°C. When heated to decomposition it emits toxic fumes of NH₃ and Cl⁻.

Standards and Recommendations

DOT Classification: 5.1; Label: Oxidizer; DOT Class: EXPLOSIVE 1.1D; Label: EXPLOSIVE 1.1D