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7790-98-9

Basic Information
CAS No.: 7790-98-9
Name: Ammonium perchlorate
Article Data: 33
Cas Database
Molecular Structure:
Molecular Structure of 7790-98-9 (Ammonium perchlorate)
Formula: H4ClNO4
Molecular Weight: 117.489
Synonyms: Perchloricacid, ammonium salt (8CI,9CI);Ammonium perchlorate(NH4ClO4);Arcadene 426;Arcite 155;Arcite 322;Dyno AP;HT 398;NK 270;PChA;PKhA;Perchloricacid,ammoniumsalt;
EINECS: 232-235-1
Density: 1.95 g/cm3
Melting Point: °Cd ec.)
Boiling Point: N/A
Flash Point: N/A
Solubility: N/A
Appearance: white crystalline solid or powder
Hazard Symbols: OxidizingO
Risk Codes: 9-44
Safety: 17-36/37-27-16-14
Transport Information: UN 1442
PSA: 74.27000
LogP: 0.59050
Synthetic route
7601-90-3

perchloric acid

302-01-2

hydrazine

7790-98-9

ammonium perchlorate

Conditions
ConditionsYield
ammonium molybdate In perchloric acid Kinetics; byproducts: N2, HCl; 90°C;
7601-90-3

perchloric acid

ammonium nitrate

7790-98-9

ammonium perchlorate

Conditions
ConditionsYield
In sulfuric acid; water heating;;
7601-90-3

perchloric acid

7664-41-7

ammonia

7790-98-9

ammonium perchlorate

Conditions
ConditionsYield
In water
In not given
In not given pure NH3 introduced in dild. soln. of HClO4;

ammonium chloride

sodium perchlorate

7790-98-9

ammonium perchlorate

Conditions
ConditionsYield
In not given
In not given

ammonium chloride

calcium perchlorate

7790-98-9

ammonium perchlorate

Conditions
ConditionsYield
With calcium hydroxide In not given byproducts: CaCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;
With Ca(OH)2 In not given byproducts: CaCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;

magnesium(II) perchlorate

ammonium chloride

7790-98-9

ammonium perchlorate

Conditions
ConditionsYield
With calcium hydroxide In not given byproducts: MgCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;
With Ca(OH)2 In not given byproducts: MgCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;
7601-90-3

perchloric acid

103809-62-7

bisamminesilver(I) perchlorate

A

7790-98-9

ammonium perchlorate

B

silver perchlorate

Conditions
ConditionsYield
In water
In water

ammonium carbonate

7601-90-3

perchloric acid

7790-98-9

ammonium perchlorate

Conditions
ConditionsYield
In water addn. of a calcd. amt. of HClO4 to aq. soln. of (NH4)2CO3 made in freshly distd. water; recrystn. from water, dried in vac. above P2O5 at 110 °C;
15588-62-2

hydroxylammonium perchlorate

A

7601-90-3

perchloric acid

B

7790-98-9

ammonium perchlorate

C

7732-18-5

water

D

7782-50-5

chlorine

E

10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
With perchloric acid; ammonia In solid Kinetics; further products; in sealed glass at 80°C; rate of decomp. depends on reagent concn.;
With perchloric acid; ammonia In neat (no solvent) Kinetics; further reagents, further products; in sealed glass (P=25-30 atm.) at 113.5-150.0°C; rate of decomp. depends on conditions and reagent concn.; MAS, IR;
15588-62-2

hydroxylammonium perchlorate

calcium carbonate

A

7790-98-9

ammonium perchlorate

B

calcium perchlorate

Conditions
ConditionsYield
In neat (no solvent) byproducts: N2, CO2, H2O; molar ratio (NH3OH)ClO4:CaCO3=3:1, heating in vac. (110-130°C, 3.5 h, then 130-145°C, 2 h);
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  • Ammonium Perchlorate CAS NO.7790-98-9

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    CAS No. : 7790-98-9 EINECS No. : 232-235-1 H.S. Code : 2829.900090 (Non-Spherical Type) / 2829.900010 (Spherical Type) Formula : NH4ClO4 Molecular Weight : 117.49 Applications : Used in Solid Rocket Propellants.- Space Launch (including the

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Chemistry

IUPAC Name: Azanium perchlorate
Molecular Formula: NH4ClO4
Molecular Weight: 117.49
EINECS: 232-235-1
Density: 1.95 g/cm3 
Polar Surface Area: 71.44 Å2
Appearance: A white, crystalline solid or powder
Solubility: Freely soluble in water. Soluble in methanol. Slightly soluble in ethanol, acetone. Insoluble in ether, ethyl acetate
Stability: Explosive when mixed with combustible material. Incompatible with organics, paper, wood shavings, etc. May explode if heated under confinement or as a result of friction. Incompatible with metals, reducing agents, strong acids.
Synonyms of Perchloricacid,ammoniumsalt (CAS NO.7790-98-9): Ammoniumperchlorate(nh4clo4) ; Ammoniumperchlorate,[highexplosive] ; Perchlorated’ammonium ; Perchloricacid,ammoniumsalt ; Perchloricacidammoniumsalt ; Pkha ; Ammonium Perchlorate ; Ammonium perchorate
Product Categories: Industrial/Fine Chemicals ; Inorganics ; Synthetic Reagents ; Ammonium SaltsSynthetic Reagents ; Metal and Ceramic Science ; Oxidation ; Perchlorates ; Salts
Following is the molecular structure of Perchloricacid,ammoniumsalt (CAS NO.7790-98-9):

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 oral 3310mg/kg (3310mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: ATAXIA

BEHAVIORAL: COMA
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 28(8), Pg. 8, 1963.
mouse LC inhalation > 300mg/m3 (300mg/m3) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

GASTROINTESTINAL: NAUSEA OR VOMITING

LIVER: LIVER FUNCTION TESTS IMPAIRED
"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 15, 1999.
mouse LD50 oral 1900mg/kg (1900mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: ATAXIA

BEHAVIORAL: COMA
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 28(8), Pg. 8, 1963.
mouse LD50 subcutaneous 940mg/kg (940mg/kg)   "Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 15, 1999.
mouse LDLo parenteral 2gm/kg (2000mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: EXCITEMENT

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Russian Pharmacology and Toxicology Vol. 32, Pg. 159, 1969.
rabbit LD50 oral 1900mg/kg (1900mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: ATAXIA

BEHAVIORAL: COMA
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 28(8), Pg. 8, 1963.
rabbit LDLo parenteral 750mg/kg (750mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: EXCITEMENT

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Russian Pharmacology and Toxicology Vol. 32, Pg. 159, 1969.
rat LC inhalation > 300mg/m3 (300mg/m3) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

GASTROINTESTINAL: NAUSEA OR VOMITING

LIVER: LIVER FUNCTION TESTS IMPAIRED
"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 15, 1999.
rat LD50 oral 4200mg/kg (4200mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: ATAXIA

BEHAVIORAL: COMA
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 28(8), Pg. 8, 1963.
rat LD50 subcutaneous 1600mg/kg (1600mg/kg)   "Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 15, 1999.
rat LDLo parenteral 3500mg/kg (3500mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: EXCITEMENT

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Russian Pharmacology and Toxicology Vol. 32, Pg. 159, 1969.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Safety Information of Perchloricacid,ammoniumsalt (CAS NO.7790-98-9):
Hazard Codes: O
O: Oxidizing
Risk Statements: 9-44
9: Explosive when mixed with combustible material 
44: Risk of explosion if heated under confinement 
Safety Statements: 17-36/37-27-16-14
17: Keep away from combustible material 
36/37: Wear suitable protective clothing and gloves 
27: Take off immediately all contaminated clothing 
16: Keep away from sources of ignition - No smoking 
14: Keep away from ... (incompatible materials to be indicated by the manufacturer) 
RIDADR: 1442
WGK Germany: 1
Moderately toxic by ingestion and parenteral routes. Flammable when exposed to heat or flame or by spontaneous chemical reaction with reducing materials. A very powerful oxidizer that has caused explosions in industry. Ignites violently with combustibles. Severe explosion hazard; decomposes at 130° and explodes at 380°. When contaminated by powdered carbon, ferrocene, S, organic matter, powdered metals, nitryl perchlorate, potassium periodate, potassium permanganate, it becomes impact sensitive. Potentially explosive reactions with carbon (above 240°C), dichrom-ium trioxide (at 270°C), cadmium oxide (at 260°C), zinc oxide (at 200°C), copper chromite, copper oxide, iron oxide, potassium permanganate, potassium dichromate, mono-, di-, tri-, or tetra-methylammonium perchlorates, metal perchlorates (e.g., lithium perchlorate, zinc perchlorate), nitrophenol-formaldehyde polymer. Mixtures with aluminum or copper burn violently when ignited. Mixtures with ethylene dinitrate ignite when stored at 60°C. When heated to decomposition it emits toxic fumes of NH3 and Cl

Standards and Recommendations

DOT Classification:  5.1; Label: Oxidizer; DOT Class: EXPLOSIVE 1.1D; Label: EXPLOSIVE 1.1D