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CAS No.: | 78-00-2 |
---|---|
Name: | TETRAETHYLLEAD |
Article Data: | 109 |
Molecular Structure: | |
Formula: | C8H20 Pb |
Molecular Weight: | 323.447 |
Synonyms: | Lead,tetraethyl-; NSC 22314; TEL; Tetraethyllead; Tetraethylplumbane |
EINECS: | 201-075-4 |
Density: | 1.653 g/mL at 25 ºC(lit.) |
Melting Point: | -136.8 C |
Boiling Point: | 84 - 85 C (Decomposes) |
Flash Point: | 77 C |
Solubility: | Insoluble Light yellow liquid |
Hazard Symbols: | |
Risk Codes: | 61-26/27/28-33-50/53-62-38-10 |
Transport Information: | 250kgs |
PSA: | 0.00000 |
LogP: | 3.51480 |
(η5-cyclopentadienyl)W(CO)3PbEt3
A
{(η5-cyclopentadienyl)W(CO)3}2PbEt2
B
tetraethyllead(IV)
Conditions | Yield |
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heated in vac. to 60°C for 8 h, under nitrogen, yellow-orange liquid became solid and darker orange in colour; dissolved in CH2Cl2/hexane solution, placed upon alumina column, elutedwith hexane, then hexane/CH2Cl2 solution, concentrated and placed refrigerator; | A 58% B n/a |
Conditions | Yield |
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Irradiation (UV/VIS); 12 h; | A 50% B n/a |
Conditions | Yield |
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With pyridine; lead sodium | |
With pyridine; tetrasodium-monoplumbide; water at 38℃; | |
With lead; sodium at 70℃; im geschlossenen Gefaess; |
Conditions | Yield |
---|---|
With lead sodium; water; toluene; potassium iodide |
Conditions | Yield |
---|---|
With lead sodium; hydrogen at 100℃; under 7355.08 Torr; |
Conditions | Yield |
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With lead; lead(II) iodide at 100 - 130℃; | |
With lead sodium | |
With hydrogenchloride; lead sodium |
Conditions | Yield |
---|---|
With lead(IV) chloride; Petroleum ether anfangs unter Kuehlung; |
Conditions | Yield |
---|---|
With PbS | |
With lead(II) chloride | |
With lead(II) oxide |
Conditions | Yield |
---|---|
Electrolysis.an einer Bleianode; |
Conditions | Yield |
---|---|
With lead(II) chloride | |
With lead(II) chloride |
IUPAC Name: tetraethylplumbane
Molecular Formula:C8H20Pb
Molecular Weight:323.4444
Appearance:colorless, viscous liquid
Melting Point:136 °C(lit.)
Boiling Point:84-85 °C15 mm Hg(lit.)
density:1.653 g/mL at 25 °C(lit.)
refractive index:n20/D 1.519(lit.)
Fp:84 °F
Solubility:slightly soluble in ethanol;
soluble in benzene, petroleum ether, toluene, gasoline
Insolubility:Water
Synonyms of TETRAETHYL LEAD(78-00-2):TEL;TETRAETHYLLEAD;
(C2H5)4Pb;Czteroetylek olowiu;czteroetylekolowiu;czteroetylekolowiu(polish);Lead tetraethyl;lead,tetraethyl-
Categories of TETRAETHYL LEAD(78-00-2): Organometallics;Organolead;Organometallic Reagents;Others
Merck 13,9277
1. | otr-ham:emb 12,500 µg/L | AETODY Advances in Modern Environmental Toxicology. 1 (1980),241. | ||
2. | ihl-hmn TCLo:1749 g/m3/30M:NOSE,EYE,GIT | SAIGBL Sangyo Igaku. Japanese Journal of Industrial Health. 17 (1975),223. | ||
3. | unr-man LDLo:1470 µg/kg | 85DCAI Poisoning; Toxicology, Symptoms, Treatments. 2 (1970),73. | ||
4. | orl-rat LD50:12,300 µg/kg | EXPEAM Experientia. 28 (1972),923. | ||
5. | ihl-rat LC50:850 mg/m3/60M | BJIMAG British Journal of Industrial Medicine. 18 (1961),277. | ||
6. | ipr-rat LD50:15 mg/kg | MELAAD Medicina del Lavoro. Industrial Medicine. 54 (1963),486. | ||
7. | ivn-rat LD50:14,400 µg/kg | MELAAD Medicina del Lavoro. Industrial Medicine. 54 (1963),486. | ||
8. | par-rat LD50:15 mg/kg | AOHYA3 Annals of Occupational Hygiene. 3 (1961),226. | ||
9. | ihl-mus LCLo:650 mg/m3/7H | SAIGBL Sangyo Igaku. Japanese Journal of Industrial Health. 15 (1973),3. | ||
10. | skn-dog LDLo:547 mg/kg | SAIGBL Sangyo Igaku. Japanese Journal of Industrial Health. 15 (1973),3. |