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| CAS No.: | 8018-01-7 |
|---|---|
| Name: | Mancozeb |
| Article Data: | 3 |
| Molecular Structure: | |
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| Formula: | C4 H6 Mn N2 S4 |
| Molecular Weight: | 541.066 |
| Synonyms: | MICENE;CRITTOX;marzin;fore;MANCO;Manaeb;MANZEB;f2966; |
| Density: | 1.92 g/cm3 |
| Melting Point: | 192-194 ºC |
| Boiling Point: | 308.2 °C at 760 mmHg |
| Flash Point: | 140.2 °C |
| Solubility: | practically insoluble in most organic solvents |
| Appearance: | Grayish-yellow powder |
| Hazard Symbols: |
|
| Risk Codes: | R37;R43 |
| Safety: | 8-24/25-46 |
| Transport Information: | UN 2210 |
| PSA: | 88.24000 |
| LogP: | 0.60850 |
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Consensus Reports
Standards and Recommendations
ACGIH TLV: TWA 5 mg(Mn)/m3
Specification
Mancozeb, with the CAS No.8018-01-7, has the Synonyms of Dithane; MANCOZEB; 1,2-Ethanedicarbamic acid, tetrathio-; CID3034368; ethylenebisdithiocarbamate manganese-zinc; NCGC00168344-01; LS-63091; C013099; manganese(2+) ethane-1,2-diylbis(dithiocarbamate) zinc ethane-1,2-diylbis(dithiocarbamate). Mancozeb, a ethylenebis(dithiocarbamate) fungicide, is widely used in agriculture, including moriculture and sericulture. It is registered as a foliar application to fruit (pears, apples, grapes), vegetables (tomatoes,potatoes, onions, carrots, celery, melons), sugar beets, ginseng, wheat and ornamentals.
Physical properties about Mancozeb are: (1)ACD/LogP: 1.656; (2)ACD/LogD (pH 5.5): -3.09; (3)ACD/LogD (pH 7.4): -3.09; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)ACD/KOC (pH 5.5): 1.00; (7)ACD/KOC (pH 7.4): 1.00; (8)#H bond acceptors: 2; (9)#H bond donors: 2; (10)#Freely Rotating Bonds: 3; (11)Flash Point: 140.2 °C; (12)Enthalpy of Vaporization: 54.88 kJ/mol; (13)Boiling Point: 308.2 °C at 760 mmHg; (14)Vapour Pressure: 0.000692 mmHg at 25°C
When you are using this chemical, please be cautious about it as the following:
1. Keep container dry;
2. Avoid contact with skin and eyes;
3. If swallowed, seek medical advice immediately and show this container or label;
You can still convert the following datas into molecular structure:
(1)SMILES:[Mn+2].[Zn+2].[S-]C(=S)NCCNC(=S)[S-].[S-]C(=S)NCCNC([S-])=S;
(2)Std. InChI:InChI=1S/2C4H8N2S4.Mn.Zn/c2*7-3(8)5-1-2-6-4(9)10;;/h2*1-2H2,(H2,5,7,8)(H2,6,9,10);;/q;;2*+2/p-4;
(3)Std. InChIKey:CHNQZRKUZPNOOH-UHFFFAOYSA-J
The toxicity data is as follows:
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| rabbit | LD50 | skin | > 5gm/kg (5000mg/kg) | Pesticide Manual. Vol. 9, Pg. 530, 1991. | |
| rat | LD50 | oral | 5gm/kg (5000mg/kg) | "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A251, Pg. 1986, | |
| rat | LD50 | skin | > 10gm/kg (10000mg/kg) | "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A251, Pg. 1986, |