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837-08-1

Basic Information
CAS No.: 837-08-1
Name: o-[1-(4-hydroxyphenyl)-1-methylethyl]phenol
Article Data: 26
Molecular Structure:
Molecular Structure of 837-08-1 (o-[1-(4-hydroxyphenyl)-1-methylethyl]phenol)
Formula: C15H16 O2
Molecular Weight: 228.291
Synonyms: Phenol,2,4'-isopropylidenedi- (8CI); 2,4'-Bisphenol A;2,4'-Dihydroxydiphenyldimethylmethane; 2,4'-Isopropylidenebisphenol;2,4'-Isopropylidenediphenol; 2-(2-Hydroxyphenyl)-2-(4-hydroxyphenyl)propane;4-[2-(2-Hydroxyphenyl)-2-propyl]phenol; o,p-Diphenylolpropane; o,p'-BisphenolA; o,p'-Dian
Density: 1.143g/cm3
Melting Point: 110.5 °C
Boiling Point: 381.8°C at 760 mmHg
Flash Point: 181.5°C
PSA: 40.46000
LogP: 3.42370
Synthetic route
67-64-1

acetone

108-95-2

phenol

B

141-79-7

4-methyl-pent-3-en-2-one

C

837-08-1

2-[1-(4-hydroxyphenyl)-1-methylethyl]-phenol

Conditions
ConditionsYield
beta zeolite acidic form at 120℃; under 760.051 Torr; for 12h;A 63.2%
B 0.01%
C 11.43%
67-64-1

acetone

108-95-2

phenol

B

7559-72-0

2,2-bis(2-hydroxyphenyl)-propane

C

5026-12-0

2-(2-hydroxyphenyl)-2,4,4-trimethylchroman

D

63661-69-8

4'-hydroxy-2,4,4-trimethylflavan

E

837-08-1

2-[1-(4-hydroxyphenyl)-1-methylethyl]-phenol

Conditions
ConditionsYield
With aluminium(III) phenoxide at 140 - 160℃; for 1h; Product distribution; oth. temperature, oth. ratio of reactants, solvents;A 8.1%
B 1.5%
C 7%
D 21.6%
E 50.3%
67-64-1

acetone

108-95-2

phenol

B

837-08-1

2-[1-(4-hydroxyphenyl)-1-methylethyl]-phenol

Conditions
ConditionsYield
With hydrogenchloride In water at 19.9℃; Rate constant; varying concentrations of reagents;
With MCM-41 silica anchored at 70℃; for 24h; Product distribution; Further Variations:; Reagents; Temperatures; atmospheric pressure;
With EPMO at 85℃; for 24h; Product distribution; Further Variations:; Reagents;
74-93-1

methylthiol

67-64-1

acetone

108-95-2

phenol

B

287110-79-6

C27H30O3

C

6156-18-9

2,2-bis(methylthio)propane

D

7559-72-0

2,2-bis(2-hydroxyphenyl)-propane

E

10527-11-4

5-hydroxy-3-(4-hydroxyphenyl)-1,1,3-trimethylindane

F

2300-15-4

2,4-bis[1-(4-hydroxyphenyl)-1-methylethyl]phenol

G

23550-40-5

4-methyl-4-methylthio-2-pentanone

H

837-08-1

2-[1-(4-hydroxyphenyl)-1-methylethyl]-phenol

I

109252-41-7

5-hydroxy-1-(4'-hydroxyphenyl)-1,3,3-trimethylindan

Conditions
ConditionsYield
strongly acidic 2percent cross linked sulfonated styrene divinylbenzene cationic gel exchange resin CT122 In water at 75℃; for 3h; Product distribution / selectivity;
6156-18-9

2,2-bis(methylthio)propane

67-64-1

acetone

108-95-2

phenol

B

287110-79-6

C27H30O3

C

74-93-1

methylthiol

D

7559-72-0

2,2-bis(2-hydroxyphenyl)-propane

E

10527-11-4

5-hydroxy-3-(4-hydroxyphenyl)-1,1,3-trimethylindane

F

2300-15-4

2,4-bis[1-(4-hydroxyphenyl)-1-methylethyl]phenol

G

23550-40-5

4-methyl-4-methylthio-2-pentanone

H

837-08-1

2-[1-(4-hydroxyphenyl)-1-methylethyl]-phenol

I

109252-41-7

5-hydroxy-1-(4'-hydroxyphenyl)-1,3,3-trimethylindan

Conditions
ConditionsYield
strongly acidic 2percent cross linked sulfonated styrene divinylbenzene cationic gel exchange resin CT122 In water at 75℃; for 3h; Product distribution / selectivity;
67-64-1

acetone

108-95-2

phenol

B

7559-72-0

2,2-bis(2-hydroxyphenyl)-propane

C

10527-11-4

5-hydroxy-3-(4-hydroxyphenyl)-1,1,3-trimethylindane

D

2300-15-4

2,4-bis[1-(4-hydroxyphenyl)-1-methylethyl]phenol

E

837-08-1

2-[1-(4-hydroxyphenyl)-1-methylethyl]-phenol

F

109252-41-7

5-hydroxy-1-(4'-hydroxyphenyl)-1,3,3-trimethylindan

G

C27H30O3

Conditions
ConditionsYield
Stage #1: phenol With water at 75℃; Autoclave;
Stage #2: acetone; 2,2-bis(methylthio)propane In water for 3h; Product distribution / selectivity;
Stage #1: phenol With water at 75℃; Autoclave;
Stage #2: acetone; methylthiol In water for 3h; Product distribution / selectivity;
technical CHP

technical CHP

67-64-1

acetone

108-95-2

phenol

B

837-08-1

2-[1-(4-hydroxyphenyl)-1-methylethyl]-phenol

Conditions
ConditionsYield
Stage #1: technical CHP; acetone; zirconia, sulfated at 55 - 65℃;
Stage #2: phenol at 75℃; for 12h;
A 94 %Chromat.
B n/a
Stage #1: technical CHP; acetone; zirconia, sulfated at 50 - 90℃; under 0 - 517.162 Torr; for 24h;
Stage #2: phenol at 75℃; for 12h;
A 92.1 %Chromat.
B n/a
63661-69-8

4'-hydroxy-2,4,4-trimethylflavan

108-95-2

phenol

B

837-08-1

2-[1-(4-hydroxyphenyl)-1-methylethyl]-phenol

Conditions
ConditionsYield
ion exchange T-66 resin at 93℃; Product distribution / selectivity;
940-71-6

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

A

4286-23-1

4-isopropenylphenol

B

10527-11-4

5-hydroxy-3-(4-hydroxyphenyl)-1,1,3-trimethylindane

C

2300-15-4

2,4-bis[1-(4-hydroxyphenyl)-1-methylethyl]phenol

D

837-08-1

2-[1-(4-hydroxyphenyl)-1-methylethyl]-phenol

E

108-95-2

phenol

Conditions
ConditionsYield
With potassium carbonate In chlorobenzene at 170℃; for 2h;
837-08-1

2-[1-(4-hydroxyphenyl)-1-methylethyl]-phenol

C17H20O2

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