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846-48-0

Basic Information
CAS No.: 846-48-0
Name: Boldenone
Molecular Structure:
Molecular Structure of 846-48-0 (Boldenone)
Formula: C19H26O2
Molecular Weight: 286.41
Synonyms: Androsta-1,4-dien-3-one,17b-hydroxy- (6CI,8CI);1,2-Dehydrotestosterone;1,2-Didehydrotestosterone;1,4-Androstadien-17b-ol-3-one;1-Dehydrotestosterone;17b-Boldenone;17b-Hydroxy-1,4-androstadiene-3-one;17b-Hydroxyandrost-1,4-dien-3-one;17b-Hydroxyandrost-1,4-diene-3-one;17b-Hydroxyandrosta-1,4-dien-3-one;Androsta-1,4-diene-17b-ol-3-one;Boldane;Dehydrotestosterone;NSC 79102;RU 18761;D1-Testosterone;b-Boldenone;Androsta-1,4-dien-3-one,17-hydroxy-, (17b)-;
EINECS: 212-686-0
Density: 1.14 g/cm3
Melting Point: 164-166 °C
Boiling Point: 435.6 °C at 760 mmHg
Flash Point: 185.8 °C
Solubility:
Appearance: crystalline solid
Hazard Symbols: F,Xn
Risk Codes: 11-20/21/22-36
Safety: 16-36/37
Transport Information:
PSA: 37.30000
LogP: 3.65520
Synthetic route
58-22-0

testosterone

846-48-0

1-dehydrotestosterone

Conditions
ConditionsYield
With tert-butyldimethylsilyl chloride; 2,3-dicyano-5,6-dichloro-p-benzoquinone In 1,4-dioxane at 0 - 20℃; for 40h;74%
With selenium(IV) oxide
With selenious acid
With old yellow enzyme from Geobacillus kaustophilus at 70℃; for 48h; pH=7; aq. phosphate buffer; Enzymatic reaction; regioselective reaction;
mit Hilfe von Corynebacterium simplex;
897-06-3

Androsta-1,4-diene-3,17-dione

846-48-0

1-dehydrotestosterone

Conditions
ConditionsYield
for 336h; Rhodotorula mucilaginosa;64%
With potato dextrose broth medium In ethanol at 24 - 26℃; for 96h; Penicillium decumbens ATCC 10436;3%
57-88-5

cholesterol

A

58-22-0

testosterone

B

63-05-8

Androstenedione

C

897-06-3

Androsta-1,4-diene-3,17-dione

D

846-48-0

1-dehydrotestosterone

E

79694-52-3

2-[(8S,9S,10R,13S,14S)-10,13-Dimethyl-3-oxo-3,6,7,8,9,10,11,12,13,14,15,16-dodecahydro-cyclopenta[a]phenanthren-(17Z)-ylidene]-propionic acid methyl ester

F

71658-22-5

22-hydroxy-23,24-bisnor-1,4-choladien-3-one

Conditions
ConditionsYield
With Mycobacterium sp. CCM 3529 Product distribution;A 0.01 g
B 0.03 g
C 51%
D 0.06 g
E n/a
F 0.38 g
897-06-3

Androsta-1,4-diene-3,17-dione

A

846-48-0

1-dehydrotestosterone

B

30915-20-9

11α,17β-dihydroxyandrosta-1,4-dien-3-one

Conditions
ConditionsYield
With phosphate buffer; Beauveria sp. culture at 28℃; for 24h;A 38%
B 46%
With phosphate buffer; Beauveria sp. culture at 28℃; for 24h; Yield given. Yields of byproduct given;
481-29-8

Epiandrosterone

A

58-22-0

testosterone

B

25848-75-3

3β,11α-dihydroxy-5α-androstan-17-one

C

25848-68-4

3beta-7alpha-Dihydroxy-5alpha-androstane-17-one

D

25848-69-5

3beta-7beta-Dihydroxy-5alpha-androstane-17-one

E

2260-01-7

1α,3β-dihydroxy-5α-androstan-17-one

F

897-06-3

Androsta-1,4-diene-3,17-dione

G

846-48-0

1-dehydrotestosterone

I

571-40-4

5α-androst-1-ene-3,17-dione

J

63-00-3

6β-hydroxy-4-androstene-3,17-dione

Conditions
ConditionsYield
With malt extract; disodium hydrogenphosphate; calcium(II) chloride dihydrate; magnesium(II) chloride hexahydrate; strontium (III) chloride hexahydrate; potassium chloride; boric acid; sodium hydrogencarbonate; sodium sulfate; sodium chloride; potassium bromide; potassium hydroxide In water; N,N-dimethyl-formamide at 32℃; for 168h; pH=8; Enzymatic reaction;A 2%
B 2%
C 2%
D 3%
E 5%
F 5%
G 3%
H 2%
I 2%
J 32%
108-75-8

2,4,6-trimethyl-pyridine

119369-73-2

2α,4α-dibromo-17β-hydroxy-5α-androstan-3-one

846-48-0

1-dehydrotestosterone

897-06-3

Androsta-1,4-diene-3,17-dione

A

58-22-0

testosterone

B

63-05-8

Androstenedione

C

846-48-0

1-dehydrotestosterone

Conditions
ConditionsYield
at 25℃; for 72h; stereoselective reduction in the biotransformation by cell suspension cultures of Marchantia Polymorpha, other androsterone derivative;
With Mycobacterium sp. No. 22 for 24h; Microbiological reaction;A n/a
B n/a
C 0.5 g
With unidentified fungal species isolated from grinded corn In water at 37℃; for 1h; pH=7; aq. phosphate buffer; Microbiological reaction; Enzymatic reaction;
57-83-0

Progesterone

A

58-22-0

testosterone

B

1162-54-5

pregna-1,4-diene-3,20-dione

C

63-05-8

Androstenedione

D

1045-69-8

testosterone acetate

E

80-75-1

11-alpha-hydroxyprogesterone

F

846-48-0

1-dehydrotestosterone

Conditions
ConditionsYield
With immobilized spores of Aspergillus ochraceus; Tris-maleate buffer at 30℃; for 48h; Product distribution; Mechanism; various water activity of the biocatalysts;
17β-acetoxy-androstadien-(1.4)-one-(3)

17β-acetoxy-androstadien-(1.4)-one-(3)

846-48-0

1-dehydrotestosterone

Conditions
ConditionsYield
With potassium hydroxide
2α.4α-dibromo-17β-hydroxy-androstanone-(3)

2α.4α-dibromo-17β-hydroxy-androstanone-(3)

846-48-0

1-dehydrotestosterone

Conditions
ConditionsYield
With 2,3,5-trimethyl-pyridine
With Potassium benzoate; toluene; butan-1-ol Erhitzen des Reaktionsprodukts unter 6 Torr auf 220-230grad;
63-05-8

Androstenedione

A

58-22-0

testosterone

B

846-48-0

1-dehydrotestosterone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction
2: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction
View Scheme
846-48-0

1-dehydrotestosterone

Conditions
ConditionsYield
With zinc In tetrahydrofuran Heating;96%
846-48-0

1-dehydrotestosterone

968-93-4

testolactone

Conditions
ConditionsYield
With Penicillium notatum KCH 904 In water; acetone at 27℃; for 96h; Enzymatic reaction;90%
846-48-0

1-dehydrotestosterone

18162-48-6

tert-butyldimethylsilyl chloride

102054-23-9

17β-O-tert-butyldimethylsilylandrosta-1,4-dien-3-one

Conditions
ConditionsYield
With 1H-imidazole In N,N-dimethyl-formamide Ambient temperature;89%
With 1H-imidazole In N,N-dimethyl-formamide for 4.5h; Ambient temperature;83%
846-48-0

1-dehydrotestosterone

64-19-7

acetic acid

17a-acetoxy-androst-1,4-dien-3-one

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 40℃; for 0.5h;83%
64-18-6

formic acid

846-48-0

1-dehydrotestosterone

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 40℃; for 0.5h;82%
846-48-0

1-dehydrotestosterone

21085-72-3

1-bromo-2,3,4-tri-O-acetyl-α-D-glucuronic acid methyl ester

1177368-54-5

methyl (androsta-1,4-dien-17β-ol-3-one)-17-O-2,3,4-tri-O-acetyl-β-D-glucuronate

Conditions
ConditionsYield
With cadmium(II) carbonate In toluene for 6h; Koenigs-Knorr synthesis; Heating;80%
846-48-0

1-dehydrotestosterone

65-85-0

benzoic acid

150054-81-2

3-oxoandrosta-1,4-dien-17α-yl benzoate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 40℃; for 0.5h;80%
846-48-0

1-dehydrotestosterone

13551-83-2

bis-(2-methyl-1H-imidazol-1-yl)methanone

1138159-98-4

3-oxoandrosta-1,4-dien-17β-yl-2'-methyl-1H-imidazole-1-carboxylate

Conditions
ConditionsYield
In dichloromethane for 28h; Heating;73%
846-48-0

1-dehydrotestosterone

98406-40-7

2-(1,1-Dimethyl-prop-2-ynylperoxy)-2-methyl-pentane

920-46-7

Methacryloyl chloride

3,17β-dimethacryloyloxy-3-(3-methyl-3-tert-pentylperoxybut-1-ynyl)-androsta-1,4-diene

Conditions
ConditionsYield
Stage #1: 2-(1,1-Dimethyl-prop-2-ynylperoxy)-2-methyl-pentane With n-butyllithium In hexane at -40 - -20℃; for 1h;
Stage #2: 1-dehydrotestosterone In diethyl ether; hexane at 15 - 20℃; for 18h;
Stage #3: Methacryloyl chloride In diethyl ether; hexane at 0 - 20℃; for 19h;
66%
846-48-0

1-dehydrotestosterone

897-06-3

Androsta-1,4-diene-3,17-dione

Conditions
ConditionsYield
for 336h; Rhodotorula mucilaginosa;54%
846-48-0

1-dehydrotestosterone

A

58105-34-3

14α,17β-dihydroxyandrosta-1,4-dien-3-one

B

6β,17β-dihydroxyandrosta-1,4-dien-3-one

Conditions
ConditionsYield
With fungus Cephalosporium aphidicola In ethanol for 120h; hydroxylation;A 2%
B 48%
846-48-0

1-dehydrotestosterone

507-09-5

thioacetic acid

A

99371-90-1

1α-acetylthio-17β-hydroxy-4-androsten-3-one

B

116104-58-6

1α-acetylthio-17β-hydroxy-4-androsten-3-one 17-acetat

Conditions
ConditionsYield
In chloroform at 40℃; for 24h;A 47%
B 16%
846-48-0

1-dehydrotestosterone

A

[1-2H]4-methylestra-1,3,5(10)-trien-17β-ol

B

[1α-2H]testosterone

C

898529-69-6

[1α,3ξ-2H2]androst-4-ene-3ξ,17β-diol

Conditions
ConditionsYield
With lithium aluminium deuteride In tetrahydrofuran for 0.25h; Heating;A 31%
B 18%
C 28%
846-48-0

1-dehydrotestosterone

A

[1α-2H]testosterone

B

898529-69-6

[1α,3ξ-2H2]androst-4-ene-3ξ,17β-diol

Conditions
ConditionsYield
With sodium borodeuteride In tetrahydrofuran for 0.25h; Heating;A 15%
B 30%
846-48-0

1-dehydrotestosterone

108-98-5

thiophenol

1α-phenylthio-17β-hydroxyandrost-4-ene-3-one

Conditions
ConditionsYield
With sodium ethanolate In ethanol for 3h; Heating;20%
846-48-0

1-dehydrotestosterone

30915-20-9

11α,17β-dihydroxyandrosta-1,4-dien-3-one

Conditions
ConditionsYield
for 72h; Rhizopus arrhizus ATCC 11145;13%
91-22-5

quinoline

846-48-0

1-dehydrotestosterone

50-28-2

estradiol

Conditions
ConditionsYield
at 370 - 390℃;
at 370 - 390℃;
106-31-0

butanoic acid anhydride

846-48-0

1-dehydrotestosterone

17β-butyryloxy-androsta-1,4-dien-3-one

Conditions
ConditionsYield
With pyridine
119-64-2

tetralin

846-48-0

1-dehydrotestosterone

50-28-2

estradiol

Conditions
ConditionsYield
at 370 - 390℃;
at 370 - 390℃;
507-09-5

thioacetic acid

846-48-0

1-dehydrotestosterone

99371-90-1

1α-acetylthio-17β-hydroxy-4-androsten-3-one

2082-59-9

pentanoic anhydride

846-48-0

1-dehydrotestosterone

17β-valeryloxy-androsta-1,4-dien-3-one

Conditions
ConditionsYield
at 130℃;
447-53-0

1,2-Dihydronaphthalene

846-48-0

1-dehydrotestosterone

50-28-2

estradiol

Conditions
ConditionsYield
at 370 - 390℃;
at 370 - 390℃;
776-35-2

9,10-dihydrophenanthrene

846-48-0

1-dehydrotestosterone

A

50-28-2

estradiol

B

3597-39-5

4-methyl-estratriene-(1.3.5(10))-diol-(1.17β)

Conditions
ConditionsYield
at 390℃;
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Specification

1. Introduction of Boldenone
Boldenone is one kind of white or kind of white crystal powder or crystalline solid. The IUPAC Name of this chemical is (8R,9S,10R,13S,14S,17S)-17-Hydroxy-10,13-dimethyl-6,7,8,9,11,12,14,15,16,17-decahydrocyclopenta[a]phenanthren-3-one. Its Classification Code isAnabolic Agents ; Hormone ; Hormones ; Hormones, Hormone Substitutes, and Hormone Antagonists ; Reproductive Effect. It belongs to Intermediates & Fine Chemicals;Pharmaceuticals;Steroids;Steroid and Hormone.

2. Properties of Boldenone
Physical properties about Boldenone are:
(1)Melting point: 164-166°C; (2)Polar Surface Area: 26.3 Å2; (3)Index of Refraction: 1.577; (4)Molar Refractivity: 83.02 cm3; (5)Molar Volume: 250.2 cm3; (6)Surface Tension: 45.8 dyne/cm; (7)Density of Boldenone (CAS NO.846-48-0): 1.14 g/cm3; (8)Flash Point: 185.8 °C; (9)Enthalpy of Vaporization: 79.87 kJ/mol; (10)Boiling Point: 435.6 °C at 760 mmHg; (11)Vapour Pressure: 2.04E-09 mmHg at 25°C.

3. Structure Descriptors of Boldenone
(1)InChI: InChI=1S/C19H26O2/c1-18-9-7-13(20)11-12(18)3-4-14-15-5-6-17(21)19(15,2)10-8-16(14)18/h7,9,11,14-17,21H,3-6,8,10H2,1-2H3/t14-,15-,16-,17-,18-,19-/m0/s1
(2)InChIKey: InChIKey=RSIHSRDYCUFFLA-DYKIIFRCSA-N
(3)Smiles: C1[C@@H]2[C@@H]([C@@]3(C(=CC(=O)C=C3)C1)C)CC[C@@]1([C@H]2CC[C@@H]1O)C

4. Safety information of Boldenone
RTECS of Boldenone (CAS NO.846-48-0): BV7994400

5. Uses of Boldenone
Boldenone is used as controlled substance and anabolic steroid. It is a controlled substance. It belongs to anabolic steroid developed for veterinary use, mostly for treatment of horses. In the US it is not indicated for use in humans and is only available through veterinary clinics.