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85-68-7

Basic Information
CAS No.: 85-68-7
Name: Benzyl butyl phthalate
Molecular Structure:
Molecular Structure of 85-68-7 (Benzyl butyl phthalate)
Formula: C19H20O4
Molecular Weight: 312.39
Synonyms: 1,2-Benzenedicarboxylicacid, butyl phenylmethyl ester (9CI);Phthalic acid, benzyl butyl ester (6CI,8CI);BBP;Benzyl n-butyl phthalate;Diacizer D 160;Ketjenflex 160;NSC 71001;Palatinol BB;S 160;Sant 160;Santicizer 160;Santicizer C 160;Santicizer S 106;Sicol160;Spatozoate;Unimoll BB;n-Butyl benzyl phthalate;n-Butyl benzyl phthalatediester;1,2-Benzenedicarboxylicacid, 1-butyl 2-(phenylmethyl) ester;
EINECS: 201-622-7
Density: 1.134 g/cm3
Melting Point: <-35 ºC
Boiling Point: 408.3 ºC at 760 mmHg
Flash Point: 198.3 ºC
Solubility: 0.000269 g/100 mL in water
Appearance: colourless oily liquid
Hazard Symbols: ToxicT,DangerousN
Risk Codes: 61-50/53-62
Safety: 53-45-60-61
Transport Information: UN 3082 9/PG 3
PSA: 52.60000
LogP: 4.00050
Synthetic route
131-70-4

phthalic acid monobutyl ester

100-39-0

benzyl bromide

85-68-7

benzyl n-butyl phthalate

Conditions
ConditionsYield
With potassium carbonate In acetone for 3h; Heating;88%
131-70-4

phthalic acid monobutyl ester

100-44-7

benzyl chloride

85-68-7

benzyl n-butyl phthalate

Conditions
ConditionsYield
With water
With ethanol
84-74-2

Phthalic acid dibutyl ester

100-51-6

benzyl alcohol

85-68-7

benzyl n-butyl phthalate

Conditions
ConditionsYield
With sodium benzoate Erhitzen bei vermindertem Druck unter Entfernen des entstehenden Butanols-(1);
85-44-9

phthalic anhydride

(+-)-erythro-4-phenyl-hexan-3-ol

(+-)-erythro-4-phenyl-hexan-3-ol

85-68-7

benzyl n-butyl phthalate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 59.6 percent / H2SO4 / H2O / 0.25 h / Heating
2: 88 percent / K2CO3 / acetone / 3 h / Heating
View Scheme
85-44-9

phthalic anhydride

85-68-7

benzyl n-butyl phthalate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
2: alcohol
View Scheme
129-00-0

pyrene

A

85-44-9

phthalic anhydride

B

90-47-1

xanth-9-one

C

629-62-9

pentadecane

D

629-97-0

n-docosane

E

630-01-3

n-hexacosane

F

629-59-4

tetradecane

G

544-76-3

Hexadecane

H

112-34-5

Diethylene glycol monobutyl ether

I

97-87-0

n-butyl isobutyrate

J

629-94-7

heneicosane

K

638-67-5

n-tricosane

L

646-31-1

tetracosane

M

629-99-2

n-pentacosane

N

203-63-4

cyclopenta[def]phenanthrene

O

1,2-benzenedicarboxylic acid diisooctyl ether

P

128-37-0

2,6-di-tert-butyl-4-methyl-phenol

Q

84-66-2

Diethyl phthalate

R

84-74-2

Phthalic acid dibutyl ester

S

203-64-5

4H-Cyclopenta[def]phenanthrene

T

85-68-7

benzyl n-butyl phthalate

U

4371-26-0

1,1'-Biphenyl-2,2',6,6'-tetracarboxaldehyde

V

16162-34-8

4,5-phenanthrene-8,9-dicarbaldehyde

W

57-10-3

1-hexadecylcarboxylic acid

X

6-propyltridecane

Conditions
ConditionsYield
With oxygen; ozone In water for 0.25 - 2h;
85-68-7

benzyl n-butyl phthalate

140-11-4

Benzyl acetate

Conditions
ConditionsYield
Stage #1: benzyl n-butyl phthalate With aminosulfonic acid; acetic acid In toluene at 110℃; Autoclave;
Stage #2: With acetic anhydride at 140 - 150℃; Reagent/catalyst; Temperature; Solvent; Autoclave;
71.2%
104-76-7

2-Ethylhexyl alcohol

85-68-7

benzyl n-butyl phthalate

18750-05-5

Benzyl 2-ethylhexyl phthalate

Conditions
ConditionsYield
With sodium hydroxide
1653-40-3

6-methylheptanol

85-68-7

benzyl n-butyl phthalate

phthalic acid benzyl ester-(6-methyl-heptyl ester)

Conditions
ConditionsYield
With sodium hydroxide
112-30-1

1-Decanol

85-68-7

benzyl n-butyl phthalate

1252-12-6

phthalic acid benzyl ester-decyl ester

Conditions
ConditionsYield
With sodium methylate
Downstream Products
18750-05-5
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    Benzyl butyl phthalate Basic information Product Name: Benzyl butyl phthalate CAS: 85-68-7 MF: C19H20O4 MW: 312.36 EINECS: 201-622-7 Mol File: 85-68-7.mol Benzyl butyl phthalate Structure Benzyl butyl phthalate Chemical Properties

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  • Butyl benzyl phthalate CAS NO.85-68-7 CAS NO.85-68-7

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Chemistry


IUPAC Name: 2-O-Benzyl 1-O-butyl benzene-1,2-dicarboxylate
Molecular formula: C19H20O4
Molar mass: 312.36 g/mol 
EINECS: 201-622-7
Product Categories: Industrial/Fine Chemicals; Phthalates; Phthalates (Environmental Endocrine Disruptors); Analytical Chemistry; Environmental Endocrine Disruptors; Functional Materials; Phthalates (Plasticizer); Plasticizer; BA - BHMethod Specific; Endocrine Disruptors (Draft)Cosmetics; 2000/60/ECMore...Close...; A-BAlphabetic; Allergens; Alpha Sort; B; EPA; European Community: ISO and DIN; Oeko-Tex Standard 100; PhthalatesMethod Specific; Plasticizers (phthalates)Method Specific; Volatiles/ Semivolatiles; Plasticizers; Polymer Additives; Polymer Science
Water Solubility: 0.000269 g/100 mL
FreezingPoint: -35 °C 
Index of Refraction: 1.553
Molar Refractivity: 88.18 cm3
Molar Volume: 275.4 cm
Surface Tension: 43.7 dyne/cm
Density: 1.134 g/cm3
Flash Point: 198.3 °C
Enthalpy of Vaporization: 66.03 kJ/mol
Boiling Point: 408.3 °C at 760 mmHg
Vapour Pressure: 7.09E-07 mmHg at 25 °C 
Appearance: clear colorless liquid with a mild odor
Melting Point: <-35 °C
Classification Code of Benzyl butyl phthalate (CAS NO.85-68-7): Mutation data; Noxae; Reproductive Effect; Teratogens; Tumor data

Uses

 Benzyl butyl phthalate is mostly used as a plasticizer for PVC. Benzyl butyl phthalate is commonly used as a plasticizer for vinyl foams, which are often used as floor tiles. Other uses are in traffic cones, food conveyor belts, and artificial leather.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 oral 13750mg/kg (13750mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: WITHDRAWAL
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 24(3), Pg. 25, 1980.
mouse LD50 intraperitoneal 3160mg/kg (3160mg/kg)   EHP, Environmental Health Perspectives. Vol. 4, Pg. 3, 1973.
mouse LD50 oral 4170mg/kg (4170mg/kg)   IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. Vol. 29, Pg. 193, 1982.
mouse LD50 skin 6700mg/kg (6700mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 39(6), Pg. 25, 1974.
mouse LD50 unreported 13700ug/kg (13.7mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 32(7), Pg. 52, 1988.
rabbit LD50 skin > 10gm/kg (10000mg/kg)   Toxicology and Industrial Health. Vol. 3, Pg. 79, 1987.
rat LD50 oral 2330mg/kg (2330mg/kg)   IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. Vol. 29, Pg. 193, 1982.
rat LD50 skin 6700mg/kg (6700mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 39(6), Pg. 25, 1974.

Consensus Reports

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 29 (1982),p. 193.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; NTP Carcinogenesis Bioassay (feed); No Evidence: mouse NTPTR*    National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-213,82 . ; Clear Evidence: rat NTPTR*    National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-213,82 . . Reported in EPA TSCA Inventory. Community Right-To-Know List.

Safety Profile

Questionable carcinogen with experimental carcinogenic data. Moderately toxic by ingestion, skin contact, and intraperitoneal routes. Experimental reproductive effects. Combustible when exposed to heat or flame; can react with oxidizers. To fight fire, use spray or mist, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes: ToxicT,DangerousN
Risk Statements: 61-50/53-62 
R61:May cause harm to the unborn child. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R62:Risk of impaired fertility.
Safety Statements: 53-45-60-61 
S53:Avoid exposure - obtain special instructions before use. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 3082 9/PG 3
WGK Germany: 2
RTECS: TH9990000
HazardClass: 9
PackingGroup: III

Specification

  Benzyl butyl phthalate (CAS NO.85-68-7), its Synonyms are 1,2-Benzenedicarboxylic acid, butyl phenylmethyl ester ; Butyl benzyl phthalate ; Butylbenzyl phthalate ; Benzyl n-butyl phthalate ; Benzyl-butylester kyseliny ftalove ; Palatinol BB ; Phthalic acid, benzyl butyl ester ; Santicizer 160 ; Sicol ; Sicol 160 ; Unimoll BB ; n-Butyl benzyl phthalate .