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87-11-6

Basic Information
CAS No.: 87-11-6
Name: THIOLUTIN
Molecular Structure:
Molecular Structure of 87-11-6 (THIOLUTIN)
Formula: C8H8 N2 O2 S2
Molecular Weight: 228.296
Synonyms: 1,2-Dithiolo[4,3-b]pyrrol-5(4H)-one,6-acetamido-4-methyl- (6CI,7CI); 1,2-Dithiolo[4,3-b]pyrrole, acetamide deriv.;3-Acetamido-5-methylpyrrolin-4-one[4,3-d]-1,2-dithiole; Acetopyrrothin;N-(4,5-Dihydro-4-methyl-5-oxo-1,2-dithiolo[4,3-b]pyrrol-6-yl)acetamide; NSC3927; Thiolutin
Density: 1.55g/cm3
Melting Point: 273-276℃
Boiling Point: 478.6°C at 760 mmHg
Flash Point: 243.3°C
Hazard Symbols:
Risk Codes: 28
Safety: Poison by ingestion and subcutaneous routes. When heated to decomposition it emits very toxic fumes of NOx and SOx.
PSA: 107.58000
LogP: 1.64450
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Chemistry

Molecular Structure of Acetopyrrothine (CAS NO.87-11-6):

IUPAC Name: N-(4-methyl-5-oxodithiolo[4,3-b]pyrrol-6-yl)acetamide
Empirical Formula: C8H8N2O2S
Molecular Weight: 228.2913 
Index of Refraction: 1.72 
Surface Tension: 70.8 dyne/cm
Density: 1.55 g/cm3 
Flash Point: 243.3 °C
Enthalpy of Vaporization: 74.28 kJ/mol 
Boiling Point: 478.6 °C at 760 mmHg
Vapour Pressure: 2.53E-09 mmHg at 25°C 
Synonyms of Acetopyrrothine (CAS NO.87-11-6): hiolutin ; n-(4,5-dihydro-4-methyl-5-oxo-1,2-dithiolo[4,3-b]pyrrol-6-yl)acetamide ; 3-acetamido-5-methylpyrrolin-4-one(4,3-d)-1,2-dithiole;6-(acetylamino)-4-methyl-1,2-dithiolo(4,3-b)pyrrol-5(4h)-one ; 6-acetamido-4-methyl-1,2-dithiolo(4,3-b)pyrrol-5(4h)-one ; 6-acetamido-4-methyl-2-dithiolo(4.3-b)pyrrol-5(4h)-one ; acetopyrrothine;6-acetamido-4-methyl-1,2-dithiolo[4,3-b]pyrrol-5-one

Toxicity Data With Reference

1.    

orl-mus LD50:25 mg/kg

    MEIEDD    Merck Index. 10 (1983),1338.
2.    

scu-mus LD50:25 mg/kg

    ANTCAO    Antibiotics and Chemotherapy. 2 (1952),357.

Safety Profile

Poison by ingestion and subcutaneous routes. When heated to decomposition it emits very toxic fumes of NOx and SOx.

Hazard Codes :VeryT+ToxicT
Risk Statements :28 
R28:Very toxic if swallowed.
Safety Statements :45 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
 

 

Specification

 Acetopyrrothine (CAS NO.87-11-6) is a toxic pesticides, flammable, thermal decomposition would release fumes of nitrogen oxides and sulfur oxides, it should be stored in low temperature, ventilation, drying environmental conditions, separated with food and raw materials, besides water, carbon oxides and oxidation of toxic carbon dioxide, dry powder, sand, water mist fire extinguishing agent can be used if emergency.