Products Categories
CAS No.: | 873-66-5 | ||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Name: | TRANS-BETA-METHYLSTYRENE | ||||||||||||||||
Article Data: | 531 | ||||||||||||||||
Molecular Structure: | |||||||||||||||||
Formula: | C9H10 | ||||||||||||||||
Molecular Weight: | 118.178 | ||||||||||||||||
Synonyms: | Benzene,(1E)-1-propenyl- (9CI); Benzene, 1-propenyl-, (E)-; Benzene, propenyl-, (E)-(8CI); (1E)-1-Propenylbenzene; (E)-(1-Propenyl)benzene; (E)-1-Phenyl-1-propene;(E)-1-Phenylpropene; (E)-1-Propenylbenzene; (E)-Propenylbenzene; (E)-b-Methylstyrene; NSC 73958;Trans-1-Propenylbenzene; trans-1-Methyl-2-phenylethene;trans-1-Phenyl-1-propene; trans-1-Phenylpropene; trans-1-Propenylbenzene; trans-3-Phenyl-2-propene;trans-Propenylbenzene; trans-b-Methylstyrene | ||||||||||||||||
Density: | 0.911 g/mL at 25 °C(lit.) | ||||||||||||||||
Melting Point: | -29°C(lit.) | ||||||||||||||||
Boiling Point: | 175 °C(lit.) | ||||||||||||||||
Flash Point: | 127 °F | ||||||||||||||||
Solubility: | Insoluble in water | ||||||||||||||||
Appearance: | clear colourless to very faintly yellow liquid | ||||||||||||||||
Hazard Symbols: | |||||||||||||||||
Risk Codes: | 10-37/38-41-43-51/53-65 | ||||||||||||||||
Safety: |
|
||||||||||||||||
PSA: | 0.00000 | ||||||||||||||||
LogP: | 2.71970 |
Conditions | Yield |
---|---|
With tetramethyldialuminoxane; [Zr(NPhPPh2)4] In tetrahydrofuran-d8 at 20℃; for 0.25h; Isomerization; | 100% |
With tetramethyldialuminoxane; [{N(SiMe3)C(Ph)}2CH]2TiCl2 In (2)H8-toluene at 25℃; for 1h; Kinetics; Further Variations:; Catalysts; | 99.5% |
With C44H58Cl2N4Pd In isopropyl alcohol at 70℃; for 3h; optical yield given as %de; diastereoselective reaction; | 98% |
Conditions | Yield |
---|---|
With [(PPh3)3Co(N2)][Li(THF)3] In benzene-d6 at 65℃; for 24h; Kinetics; Temperature; Inert atmosphere; Sealed tube; Darkness; | 100% |
With tri-tert-butyl phosphine; isobutyryl chloride; bis(dibenzylideneacetone)-palladium(0) In toluene at 80℃; for 24h; Inert atmosphere; | 95% |
Stage #1: cis-1-phenyl-1-propylene With cobalt(II) chloride; 2,2'-bis(diphenylphosphino)diphenylamine In toluene at 20℃; for 0.0833333h; Schlenk technique; Inert atmosphere; Stage #2: With sodium triethylborohydride In toluene at 20℃; for 1h; Schlenk technique; Inert atmosphere; diastereoselective reaction; | 92% |
1-propenylbenzene
Conditions | Yield |
---|---|
With potassium hydride In tetrahydrofuran for 0.5h; Ambient temperature; | 100% |
1-propenylbenzene
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride In tetrahydrofuran for 1h; Ambient temperature; | 100% |
With lithium aluminium tetrahydride; potassium hydride Yield given. Multistep reaction; |
1-propenylbenzene
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride In tetrahydrofuran for 1h; Ambient temperature; | 100% |
Conditions | Yield |
---|---|
With phenol In acetonitrile Electrochemical reaction; | A 100% B n/a |
Conditions | Yield |
---|---|
In diethyl ether; benzene for 17h; Ambient temperature; | 98% |
Cinnamyl acetate
1-propenylbenzene
Conditions | Yield |
---|---|
With RhCl(PPh3)3; lithium perchlorate In acetonitrile for 17h; | 97% |
With tetraethylammonium tosylate; tetrakis(triphenylphosphine) palladium(0) In acetonitrile Electrochemical reaction, Pb cathode, Pt anode; | 58% |
With iron(III)-acetylacetonate; tert-butylmagnesium chloride In tetrahydrofuran at 0℃; for 1.5h; Inert atmosphere; | 25% |
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine)palladium dichloride In benzene at 80℃; for 5h; | 97% |
trans-3-phenylprop-2-enyl chloride
1-propenylbenzene
Conditions | Yield |
---|---|
With RhCl(PPh3)3; lithium perchlorate In acetonitrile for 17h; | 96% |