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9003-35-4

Basic Information
CAS No.: 9003-35-4
Name: Phenol, polymer with formaldehyde
Molecular Structure:
Molecular Structure of 9003-35-4 (Phenol, polymer with formaldehyde)
Formula: (C6H6O.CH2O)x
Molecular Weight: 124.13700
Synonyms: Formaldehyde phenol polymer;Paraformaldehyde, formaldehyde, phenol polymer;Paraformaldehyde, phenol polymer;Phenol-formaldehyde resin;Phenol-formaldehyde resin;Phenolic moulding powder;
EINECS: 1533716-785-6
Density: 1.10 g/cm3
Melting Point: 94 °C
Boiling Point:
Flash Point:
Solubility:
Appearance: light yellow granule
Hazard Symbols:
Risk Codes:
Safety:
Transport Information:
PSA: 37.30000
LogP: 1.84320
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    Phenol Formaldehyde CAS NO.9003-35-4

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    MSDS/COA Download

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  • Phenolic resin,water-soluble

  • Casno:

    9003-35-4

    Phenolic resin,water-soluble

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

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  • Phenol, polymer with formaldehyde

  • Casno:

    9003-35-4

    Phenol, polymer with formaldehyde

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

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    Business Type:Trading Company

    Tel:86-571-56972507

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  • PHENOL-FORMALDEHYDE RESIN

  • Casno:

    9003-35-4

    PHENOL-FORMALDEHYDE RESIN

    Min.Order: 1 Gram

    FOB Price:  USD $ 0.0-0.0/Gram

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  • Phenol-formaldehyde resin

  • Casno:

    9003-35-4

    Phenol-formaldehyde resin

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

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    Business Type:Other

    Tel:86-29-86107037-8015

    Address:No.11 Daqing Road,Lianhu District,Xi’an 710082,China

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  • Phenolic Resin

  • Casno:

    9003-35-4

    Phenolic Resin

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

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History

Phenolic resins(9003-35-4), copolymers of phenol and formaldehyde, were the first fully synthetic polymers made. They were discovered in 1910 by Leo Baekeland and given the trade name Bakelite.

Specification

The Phenol-formaldehyde resin, with the CAS registry number 9003-35-4,is also known as 2-Phenylethylamine; 3-Aminoethylbenzene. It belongs to the product categories of Polymers. This chemical's molecular formula is (C6H6O)n.(CH2O)n.What's more,Its systematic name is Phenol,polymer with formaldehyde.It is Stable,incompatible with strong oxidizing agents.It can be used to make molded products including pool balls, laboratory countertops, and as coatings and adhesives.

Production of Phenol-formaldehyde resin:
Two processes, both involving step growth polymerization, are used for the manufacture of phenolic resins.
 A one-stage resin may be obtained by using an alkaline catalyst and excess formaldehyde to form linear, low-molecular-weight resol resins. Acidification and further heating causes the curing process to give a highly cross-linked thermoset polymer. The o- and p-ethylolphenols are more reactive toward formaldehyde than the original phenol and rapidly undergo further reaction to give di- and trimethylol derivatives. The methylolphenols will react to form di- and trinuclear phenols at still-free ortho and para positions. The final structure of the product involves a high degree of branching. Most linkages between aromatic rings are methylone (CH2) groups, though some other (CH2.OCH2) linkages are present.
 The second process (Fig. l) uses an acid catalyst and excess phenol to give a linear polymer (novolac) that has no free methylol groups for cross-linking. In a separate second part of this two-stage process, a cross-linking agent is added and further reaction occurs. In many instances, hexamethylenetetramine is used, which decomposes to formaldehyde and ammonia.
 Other modifications in making phenolic polymers are the incorporation of cresols or resorcinol as the phenol (Fig. 1) and acetaldehyde or furfural as the phenol.

FIGURE 1 Manufacture of phenolic resins.

The toxicity data of Phenol-formaldehyde resin are as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 oral > 5gm/kg (5000mg/kg)   National Technical Information Service. Vol. OTS0556084,
rat LD50 skin > 2gm/kg (2000mg/kg)   National Technical Information Service. Vol. OTS0556084,