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Basic Information
| CAS No.: | 9011-14-7 |
|---|---|
| Name: | POLY(METHYL METHACRYLATE) |
| Article Data: | 273 |
| Molecular Structure: | |
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|
|
| Formula: | C5 H8 O2 |
| Molecular Weight: | 100.117 |
| Synonyms: | Methacrylicacid methyl ester, polymers (8CI); Methacrylic acid, Me ester, homopolymer(6CI); 01DH-LE-P; 1000L; 1000L (methacrylic polymer); 100B; 1H830; 50N; 50N(polymer); 560F; 821T; 8N; 950K-C4; 9D; A 21LV; A 3-950K; A 5.5; AC 050S; AC956; AO 120; AS 08; ASC 08; Acrigel DHLE; Acrivue; Acron; Acronal S 320D; AcrySirup DR 510; Acry Sirup SY 102; Acry Sirup SY 102C; Acry Sirup SY 430; AcryaceE; Acrybase 24; Acrybase LH 101; Acrycon ACPI; Acryfix; Acrylar 2416; Acrylite001; Acrylite 240; Acrylite AR; Acrylite E 001; Acrylite EX; Acrylite FF;Acrylite GP; Acrylite H 12; Acrylite H 15-003; Acrylite HR; Acrylite IR;Acrylite L; Acrylite L 001; Acrylite LN 084; Acrylite MR; Acrylite OP 1;Acrylite OP 4; Acrylite S; Acrylite S 001; Acrylite S 10/8N; Acrylite VH;Acrylite XE 001; Acryloid A 101; Acryloid A 102; Acryloid A 15; Acryloid A 21;Acrylub 101; Acrylub 102; Acrypet 001S; Acrypet E; Acrypet G; Acrypet HBX 189;Acrypet IR-G 504; Acrypet IR-VH; Acrypet IRS 404; Acrypet M; Acrypet M 001;Acrypet M 100; Acrypet MD 50; Acrypet MF 001; Acrypet SVK; Acrypet TF; AcrypetTF 3; Acrypet TF 8; Acrypet UT 100; Acrypet V; Acrypet V 001; Acrypet VA;Acrypet VF; Acrypet VH 01; Acrypet VH 101; Acrypet VH 3; Acrypet VH 5; AcrypetVH 5-000; Acrypet VH 5-001; Acrypet VH 60; Acrypet VHF; Acrypet VHK; AcrypetVHS; Acrypet VM; Acrypet VR; Acryplen HBS 001; Acryplen Pellet HBS 001; Acrypol876G; Acrypol 932HR; Acrypol P 8015; Acryrex CM 205; Acryrex CM 207; Acryrex CM211; Agomet U 4; Akronil; Akrylon; Akurirusande; Altufix P 103; Altuglas;Altuglas 20010; Altuglas 8000; Altuglas 9DFG; Altuglas BS 9EL; Altuglas DR 2T;Altuglas GR 5; Altuglas GR 9E; Altuglas M 70; Altuglas V 020; Altuglas V825T101; Altuglas V 920T; Altulite 2774; Altulor M 70; Amatis; Aropol Q 701C;Art Pearl G 7P; Art Pearl SE 15; Art Resin M 4005; Artecoll; Arteplast;Asterite; Atoglas V 020; Atoglas V 920; Atoglas V 920T; Autoflex; B 000; B 85;BA 40; BG 1.6U; BK 1.0F; BK 1.6U; BM 310; BR 100; BR 100Dianal BR 100; BR 106;BR 60; BR 78; |
| Density: | 1.2 g/mL at 25 °C(lit.) |
| Melting Point: | 105oC |
| Boiling Point: | 108 °C |
| Flash Point: | 250 °C |
| Solubility: | Soluble in tetrahydrofuran, toluene, cyclohexanone, ethyl acetate and chloroform. Insoluble in water, alcohols and aliphatic hydrocarbons. |
| Hazard Symbols: | Xn |
| Risk Codes: | 20/22 |
| Safety: | Questionable carcinogen with experimental tumorigenic data by implant route. When heated to decomposition it emits acrid smoke and irritating fumes. Used as the main constituent of acrylic sheet, molding, and extrusion powders. |
| PSA: | 26.30000 |
| LogP: | 0.73550 |
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POLY(METHYL METHACRYLATE)
Chemistry
Poly(methyl methacrylate) (PMMA) poly(methyl 2-methylpropenoate) is a thermoplastic and transparent plastic.
it is the synthetic polymer of methyl methacrylate. It is commonly called acrylic glass, simply acrylic, perspex or plexiglas. Acrylic, or acrylic fiber, can also refer to polymers or copolymers containing polyacrylonitrile. It is brittle,so should becareful when loaded, especially under an impact force.
polymethyl methacrylate ignites at 460 °C and burns, forming carbon dioxide, water, carbon monoxide and low molecular weight hydrocarbons, including formaldehyde.
it is the synthetic polymer of methyl methacrylate. It is commonly called acrylic glass, simply acrylic, perspex or plexiglas. Acrylic, or acrylic fiber, can also refer to polymers or copolymers containing polyacrylonitrile. It is brittle,so should becareful when loaded, especially under an impact force.
polymethyl methacrylate ignites at 460 °C and burns, forming carbon dioxide, water, carbon monoxide and low molecular weight hydrocarbons, including formaldehyde.
History
POLYMETHYLMETHACRYLATE,The material was developed in 1928 in various laboratories and was brought to market in 1933 by Rohm and Haas Company.
Uses
PMMA or Acrylic is a versatile material and has been used in a wide range of fields and applications.It is often used as an alternative to glass, and in competition with polycarbonate (PC). polymethyl methacrylate is often preferred because of its moderate properties, easy handling and processing, and low cost.
Production
Synthesis:PMMA is routinely produced by emulsion polymerization, solution polymerization and bulk polymerization. Generally radical initiation is used (including living polymerization methods), but anionic polymerization of PMMA can also be performed.To produce 1 kg of PMMA, need about 2 kg of petroleum.
Consensus Reports
IARC Cancer Review: Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 19 ,1979,p. 187.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 19 ,1979,p. 187.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory.
Safety Profile
Questionable carcinogen with experimental tumorigenic data by implant route. When heated to decomposition it emits acrid smoke and irritating fumes.