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CAS No.: | 917-57-7 |
---|---|
Name: | VINYL LITHIUM |
Article Data: | 28 |
Molecular Structure: | |
Formula: | C2H3 Li |
Molecular Weight: | 33.9868 |
Synonyms: | Lithium,vinyl- (6CI,7CI,8CI); Ethenyllithium; Lithioethene; Vinyllithium |
Density: | g/cm3 |
Boiling Point: | °Cat760mmHg |
Flash Point: | °C |
Safety: | Ignites spontaneously and burns violently in air. See also LITHIUM COMPOUNDS and ORGANOMETALS. |
PSA: | 0.00000 |
LogP: | 0.67920 |
Conditions | Yield |
---|---|
With n-butyllithium In pentane for 2.5h; Inert atmosphere; Glovebox; | 87% |
With n-butyllithium In hexane at 21℃; for 2h; | 84% |
With phenyllithium |
Conditions | Yield |
---|---|
With lithium; zinc(II) chloride; 2,5-Diphenyl-6a-thiathiophthen In tetrahydrofuran at 0℃; under 750.06 Torr; for 6h; Product distribution; | A 75% B n/a |
With lithium; 2,5-Diphenyl-6a-thiathiophthen; zinc(II) chloride In tetrahydrofuran at 0℃; under 750.06 Torr; for 6h; Yields of byproduct given; | A 75% B n/a |
Conditions | Yield |
---|---|
With lithium | |
With tert.-butyl lithium In diethyl ether; pentane at -78℃; for 2h; |
Conditions | Yield |
---|---|
With lithium |
Conditions | Yield |
---|---|
With diethyl ether | |
Ambient temperature; |
1,1-Dilithioethan
vinyllithium
Conditions | Yield |
---|---|
With chloro-trimethyl-silane In tetrahydrofuran for 8h; Ambient temperature; Yield given; |
1,2-dilithioethane
vinyllithium
1,2-dilithioethane
A
vinyllithium
B
1,4-dilithiobutane
C
hexanediyl dilithium
Conditions | Yield |
---|---|
With lithium at -196℃; under 0.005 Torr; Mechanism; |
cis-1,2-Dilithioethylen
A
vinyllithium
B
dilithium acetylide
Conditions | Yield |
---|---|
Title compound not separated from byproducts; |
trans-1,2-Dilithioethylen
A
vinyllithium
B
dilithium acetylide
Conditions | Yield |
---|---|
Title compound not separated from byproducts; |
Product Name: Vinyllithium (CAS NO.917-57-7)
Molecular Formula: C2H3Li
Molecular Weight: 33.99g/mol
Mol File: 917-57-7.mol
Einecs: 213-028-5
Enthalpy of Vaporization: 15.7 kJ/mol
Vapour Pressure: 43300 mmHg at 25°C
H-Bond Donor: 0
H-Bond Acceptor: 1
Heavy Atom Count: 3
Complexity: 2.8
Covalently-Bonded Unit Count: 2
Ignites spontaneously and burns violently in air. See also LITHIUM COMPOUNDS and ORGANOMETALS.
Vinyllithium ,its CAS NO. is 917-57-7,the synonyms is Ethenyllithium .