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917-65-7

Basic Information
CAS No.: 917-65-7
Name: ALUMINUM METHYL DICHLORIDE
Article Data: 21
Molecular Structure:
Molecular Structure of 917-65-7 (ALUMINUM METHYL DICHLORIDE)
Formula: CH3AlCl2
Molecular Weight: 112.922
Synonyms: Methylaluminiumdichlorid;
EINECS: 213-032-7
Density: 0.729 g/mL at 25 °C
Melting Point: 72.7℃ [CRC10]
Boiling Point: 95℃ [CRC10]
Flash Point: −9 °F
Solubility: Soluble bz, eth, hydrocarbon solvents [CRC10]
Hazard Symbols: FlammableF;CorrosiveC
Risk Codes: 11-14-34-48/20-51/53-62-65-67
Safety: 16-26-36/37/39-43-45
Transport Information: UN 3399
PSA: 0.00000
LogP: 1.96280
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    The Aluminum,dichloromethyl-, with the CAS registry number of 917-65-7, is also known as Methylaluminiumdichlorid. It belongs to the product categories of Chemical Synthesis; Organoaluminum; Organometallic Reagents. Its EINECS registry number is 21

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Specification

The Aluminum,dichloromethyl-, with the CAS registry number of 917-65-7, is also known as Methylaluminiumdichlorid. It belongs to the product categories of Chemical Synthesis; Organoaluminum; Organometallic Reagents. Its EINECS registry number is 213-032-7. This chemical's molecular formula is CH3AlCl2 and molecular weight is 112.92. What's more, its IUPAC name is Dichloro(methyl)alumane. In addition, it must be stored in airtight containers and placed in a dry, ventilated place at room temperature. Meanwhile, it should be avoided contact with light.

Physical properties about the Aluminum,dichloromethyl- are: (1)ACD/LogP: 1.09; (2)# of Rule of 5 Violations: 0; (3)#H bond acceptors: 0; (4)#H bond donors: 0; (5)#Freely Rotating Bonds: 0; (6)Polar Surface Area: 0 Å2; (7)Enthalpy of Vaporization: 8.17 kJ/mol; (8)Vapour Pressure: 205000 mmHg at 25 °C.

Uses: it is used to produce other chemicals. For example, it is used to produce 1-Methylsulfanyl-propan-2-one. This reaction needs solvent CH2Cl2. The reaction time is 2 h with reaction temperature of -20 °C. The yield is about 66 %.

The Aluminum,dichloromethyl- can react with Methylsulfanyl-acetyl chloride to get 1-Methylsulfanyl-propan-2-one

When you are using this chemical, please be cautious about it as the following:
As a chemical, it is highly flammable. It reacts violently with water. If contact with eyes accidently, rinse immediately with plenty of water and seek medical advice. In addition, during using it, wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible). Besides, it may causes burns.

You can still convert the following datas into molecular structure:
(1) SMILES: Cl[Al+]Cl.[CH3-]
(2) InChI: InChI=1/CH3.Al.2ClH/h1H3;;2*1H/q-1;+3;;/p-2
(3) InChIKey: IYIMDBFPUIXMJD-NUQVWONBAQ