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CAS No.: | 919-31-3 |
---|---|
Name: | 2-CYANOETHYLTRIETHOXYSILANE |
Article Data: | 20 |
Molecular Structure: | |
Formula: | C9H19 N O3 Si |
Molecular Weight: | 217.34 |
Synonyms: | Propionitrile,3-(triethoxysilyl)- (6CI,7CI,8CI); (2-Cyanoethyl)triethoxysilane; (b-Cyanoethyl)triethoxysilane;3-(Triethoxysilyl)propionitrile; Cyanoethyltriethoxysilane; NSC 77092 |
Density: | 0.964g/cm3 |
Boiling Point: | 250.4°Cat760mmHg |
Flash Point: | 105.3°C |
Solubility: | Hydrolyzes in water. |
Hazard Symbols: | |
Risk Codes: | 36/37/38 |
Safety: | Mildly toxic by ingestion and skin contact. A skin irritant. See also CYANIDE. When heated to decomposition it emits toxic fumes of NOx and CN−. |
PSA: | 51.48000 |
LogP: | 1.94848 |
Conditions | Yield |
---|---|
Stage #1: tetraethoxy orthosilicate at 100 - 105℃; for 2h; Molecular sieve; Large scale; Stage #2: With titanium tetrachloride In water at 40 - 98℃; Large scale; Stage #3: acrylonitrile Large scale; Further stages; | 94.6% |
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide at 56 - 59℃; for 2h; Large scale; | 94.5% |
With lithium perchlorate at 25℃; for 2h; electrolysis; | 66% |
Conditions | Yield |
---|---|
In dichloromethane for 3h; Heating; | 85% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 0 - 25℃; | 67% |
Conditions | Yield |
---|---|
With dihydrogen hexachloroplatinate; platinum |
ethanol
1,1,3,3-Tetraethoxy-1,3-bis-<2-cyan-ethyl>-disiloxan
2-cyanoethyltriethoxysilane
Conditions | Yield |
---|---|
With potassium hydroxide at 240℃; for 3h; Autoclave; Molecular sieve; |
bis(tetrahydrofurane)dichloridodioxidomolybdenum(VI)
2-cyanoethyltriethoxysilane
Conditions | Yield |
---|---|
In dichloromethane mixed, stirred (30 min); filtered, concd. (to dryness), washed (hexane), dried (in vac.), elem. anal.; | 96% |
2-cyanoethyltriethoxysilane
tetrabutyl ammonium fluoride
tetra-n-butylammonium octakis(2-cyanoethyl)octasilsesquioxane fluoride
Conditions | Yield |
---|---|
In tetrahydrofuran; water; toluene at 25℃; for 16h; Solvent; Inert atmosphere; | 96% |
18-crown-6 ether
2-cyanoethyltriethoxysilane
Conditions | Yield |
---|---|
Stage #1: 18-crown-6 ether With potassium fluoride In toluene; acetonitrile at 20℃; for 0.25h; Inert atmosphere; Stage #2: 2-cyanoethyltriethoxysilane In water; toluene; acetonitrile at 20℃; Inert atmosphere; | 96% |
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IUPAC Name: 3-Triethoxysilylpropanenitrile
Synonyms: (.beta.-Cyanoethyl)triethoxysilane ; (2-Cyanoethyl)triethoxysilane ; 3-(Triethoxysilyl)propionitrile ; Propanenitrile, 3- (triethoxysilyl)- ; Propionitrile, 3- (triethoxysilyl)-
Product Categories: Functional Materials;Si (Classes of Silicon Compounds);Silane Coupling Agents;Silane Coupling Agents (Intermediates);Si-O Compounds;Trialkoxysilanes
CAS NO:919-31-3
Molecular Formula of (2-Cyanoethyl)triethoxysilane (CAS NO.919-31-3) :C9H19NO3Si
Molecular Weight of (2-Cyanoethyl)triethoxysilane (CAS NO.919-31-3) :217.34
Molecular structure of (2-Cyanoethyl)triethoxysilane (CAS NO.919-31-3) :
Index of Refraction:1.425
Surface Tension: 27.6 dyne/cm
Density: 0.964 g/cm3
Flash Point: 105.3 °C
Enthalpy of Vaporization: 48.77 kJ/mol
Boiling Point: 250.4 °C at 760 mmHg
Vapour Pressure: 0.0216 mmHg at 25°C
Sensitive : Moisture Sensitive
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rabbit | LD50 | skin | 5950uL/kg (5.95mL/kg) | American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. | |
rat | LD50 | oral | 5630mg/kg (5630mg/kg) | American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. |
Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community Right-To-Know List.
Mildly toxic by ingestion and skin contact. A skin irritant. See also CYANIDE. When heated to decomposition it emits toxic fumes of NOx and CN−.
Hazard Codes Xi
Risk Statements 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 26
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany 2
RTECS VV2750000
F 10-21
TSCA Yes