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929-06-6

Basic Information
CAS No.: 929-06-6
Name: 2-Aminoethoxyethanol
Article Data: 38
Molecular Structure:
Molecular Structure of 929-06-6 (2-Aminoethoxyethanol)
Formula: C4H11NO2
Molecular Weight: 105.137
Synonyms: 1-Amino-2-(2-hydroxyethoxy)ethane;2-(2-Aminoethoxy)ethanol;2-(2-Hydroxyethoxy)ethylamine;2-(Hydroxyethoxy)ethylamine;2-Amino-2'-hydroxydiethyl ether;2-Aminoethyl2-hydroxyethyl ether;5-Amino-3-oxapentan-1-ol;5-Hydroxy-3-oxapentylamine;Diethylene glycol amine;Diethylene glycol monoamine;Diglycolamine;Diglycolamine Agent;NSC 86108;b-(b-Hydroxyethoxy)ethylamine;b-Hydroxy-b'-aminodiethyl ether;
EINECS: 213-195-4
Density: 1.029 g/cm3
Melting Point: -12.5 °C
Boiling Point: 221 °C at 760 mmHg
Flash Point: 76.6 °C
Solubility: miscible in water
Appearance: colourless to faintly yellow liquid
Hazard Symbols: CorrosiveC
Risk Codes: 21-34
Safety: 26-36/37/39-45-24/25
Transport Information: UN 3055 8/PG 3
PSA: 55.48000
LogP: -0.34570
Synthetic route
139115-90-5

2-(2-azidoethoxy)ethanol

929-06-6

2-(2-Aminoethoxy)ethanol

Conditions
ConditionsYield
With water; triphenylphosphine In tetrahydrofuran for 4h; Ambient temperature;99%
With 10% palladium on activated charcoal; hydrogen In methanol under 760.051 Torr; for 8h;98.3%
With palladium on activated charcoal; hydrogen In methanol19.4 g
69676-63-7

2-(2-phthalimidoethoxy)ethanol

929-06-6

2-(2-Aminoethoxy)ethanol

Conditions
ConditionsYield
With hydrazine hydrate In ethanol at 90℃; for 24h;74%
1548723-17-6

C23H21F17N2O7

929-06-6

2-(2-Aminoethoxy)ethanol

Conditions
ConditionsYield
With benzylamine In dichloromethane for 1.5h; UV-irradiation;15%
118974-46-2

N-(2-(2-hydroxyethoxy)ethyl)acetamide

929-06-6

2-(2-Aminoethoxy)ethanol

Conditions
ConditionsYield
With hydrogenchloride; ethanol
111-46-6

diethylene glycol

929-06-6

2-(2-Aminoethoxy)ethanol

Conditions
ConditionsYield
With nickel kieselguhr; ammonia at 205℃;
iron-containing catalyst Product distribution / selectivity;
With ammonia; hydrogen; (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] In toluene at 155℃; under 44254.4 Torr; for 12h; Product distribution / selectivity; Autoclave; Cooling;
20132-16-5

2-(2-nitro-ethoxy)-ethanol

929-06-6

2-(2-Aminoethoxy)ethanol

Conditions
ConditionsYield
With hydrogen; nickel In ethanol
628-89-7

2-(2-Chloroethoxy)ethanol

929-06-6

2-(2-Aminoethoxy)ethanol

Conditions
ConditionsYield
With ammonia In ethanol
207116-18-5

C5H10NO4(1-)

A

124-38-9

carbon dioxide

B

929-06-6

2-(2-Aminoethoxy)ethanol

Conditions
ConditionsYield
In water at 33.6 - 75.9℃; Thermodynamic data; Equilibrium constant; ΔH,ΔG, ΔS;

N,N'-bis(2,3-dihydroxypropyl)-5-(2-{[2-(2-hydroxyethoxy)ethyl]amino}-2-oxoethoxy)-1,3-benzenedicarboxamide

A

[3,5-Bis-(2,3-dihydroxy-propylcarbamoyl)-phenoxy]-acetic acid

B

929-06-6

2-(2-Aminoethoxy)ethanol

Conditions
ConditionsYield
With water at 95℃; Rate constant;
7664-41-7

ammonia

111-46-6

diethylene glycol

nickel

nickel

kieselguhr

kieselguhr

A

110-91-8

morpholine

B

929-06-6

2-(2-Aminoethoxy)ethanol

C

amine

amine

Conditions
ConditionsYield
at 205℃;
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  • 929-06-6           C4H11NO2            2-(2-Aminoethoxy)ethanol

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Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

DOT Classification:  8; Label: Corrosive

Specification

The 2-(2-Aminoethoxy)ethanol, with the CAS registry number 929-06-6 and EINECS registry number 213-195-4, is also called β-(β-Hydroxyethoxy)ethylamine. And the molecular formula of this chemical is C4H11NO2. It is a kind of colourless to faintly yellow liquid, and belongs to the following product categries: Ethylene Glycols & Monofunctional Ethylene Glycols;Monofunctional Ethylene Glycols.

The physical properties of 2-(2-Aminoethoxy)ethanol are as following: (1)ACD/LogP: -1.37; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -4.22; (4)ACD/LogD (pH 7.4): -2.69; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 3; (10)#H bond donors: 3; (11)#Freely Rotating Bonds: 6; (12)Polar Surface Area: 21.7 Å2; (13)Index of Refraction: 1.449; (14)Molar Refractivity: 27.39 cm3; (15)Molar Volume: 102.1 cm3; (16)Polarizability: 10.86×10-24cm3; (17)Surface Tension: 39.9 dyne/cm; (18)Density: 1.029 g/cm3; (19)Flash Point: 76.6 °C; (20)Enthalpy of Vaporization: 53.19 kJ/mol; (21)Boiling Point: 221 °C at 760 mmHg; (22)Vapour Pressure: 0.0227 mmHg at 25°C.

Preparation and uses of 2-(2-Aminoethoxy)ethanol: It is metabolite of morpholine degradation in Mycobacterium aurum, and it also can be prepared by DGA. What's more, it is used as acid gas absorber, and it is also used as surface active agent and wetting agent. It is used as the material of polymer as well.

You should be cautious while dealing with this chemical. It is harmful in contact with skin, and may also cause burns. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; Avoid contact with skin and eyes; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: OCCOCCN
(2)InChI: InChI=1/C4H11NO2/c5-1-3-7-4-2-6/h6H,1-5H2
(3)InChIKey: GIAFURWZWWWBQT-UHFFFAOYAI

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 2825mg/kg (2825mg/kg) BEHAVIORAL: GENERAL ANESTHETIC

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 32(9), Pg. 50, 1988.
rabbit LD50 skin 1190uL/kg (1.19mL/kg)   AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 4, Pg. 119, 1951.
rat LD50 oral 3gm/kg (3000mg/kg) BEHAVIORAL: GENERAL ANESTHETIC

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 32(9), Pg. 50, 1988.