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| CAS No.: | 93-61-8 |
|---|---|
| Name: | N-Methylformanilide |
| Article Data: | 278 |
| Molecular Structure: | |
|
|
|
| Formula: | C8H9NO |
| Molecular Weight: | 135.166 |
| Synonyms: | Formanilide,N-methyl- (6CI,7CI,8CI);Methylphenylformamide;N-Formyl-N-methylaniline;N-Methyl-N-formylaniline;N-Methyl-N-phenylformamide;N-Phenyl-N-methylformamide;NSC 3828; |
| EINECS: | 202-262-3 |
| Density: | 1.083 g/cm3 |
| Melting Point: | 8-13 °C(lit.) |
| Boiling Point: | 243 °C at 760 mmHg |
| Flash Point: | 126.7 °C |
| Solubility: | immiscible with water |
| Appearance: | clear colourless to yellow liquid |
| Hazard Symbols: |
 Xn,  Xi
|
| Risk Codes: | 22-43-38 |
| Safety: | 36/37 |
| PSA: | 20.31000 |
| LogP: | 1.91510 |
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| Conditions | Yield |
|---|---|
| With copper (II) carbonate hydroxide; phenylsilane; cyclohexyldiphenylphosphine In acetonitrile at 60℃; for 12h; | 99% |
| In toluene for 0.0833333h; Reflux; | 96% |
| In toluene at 88 - 108℃; | 96% |
| Conditions | Yield |
|---|---|
| With zinc(II) phthalocyanine; carbon dioxide; phenylsilane at 25℃; under 3750.38 Torr; for 6h; Reagent/catalyst; Temperature; Pressure; Autoclave; chemoselective reaction; | 99% |
| With 1H-imidazole; nickel oxinate at 150℃; | 85% |
| With t-butyldimethylsiyl triflate at 20℃; for 24h; | 82% |
| With 1,2,4-Triazole; 8-quinolinol; copper(II) choride dihydrate at 150℃; | 74% |
| With methyl benzylphosphonic chloride at 130℃; for 3.5h; | 59% |
| Conditions | Yield |
|---|---|
| With copper(II) acetate dihydrate; phenylsilane; 1,2-bis-(diphenylphosphino)ethane In toluene at 25℃; under 760.051 Torr; for 2h; | 99% |
| With Zn(salen); phenylsilane at 25℃; under 3750.38 Torr; for 7h; Reagent/catalyst; Pressure; Temperature; | 99% |
| With Al(salen); phenylsilane at 100℃; under 37503.8 Torr; for 3h; Reagent/catalyst; Pressure; Temperature; Autoclave; | 99% |
| Conditions | Yield |
|---|---|
| In acetonitrile at 30℃; | 99% |
| Conditions | Yield |
|---|---|
| With formaldehyd; sodium hydroxide In ethanol; water at 27℃; for 9h; | 97% |
| With ethanol; oxalic acid anschliessend man erhitzt das abgeschiedene Salz bis zur Beendung der Gasentwicklung auf 160-180grad; |
- 36325-39-0
N-phenylthioacetamide
- 93-61-8
N-methyl-N-phenylformamide
| Conditions | Yield |
|---|---|
| With hydrogenchloride; sodium nitrite In water at 20℃; for 0.5h; | 97% |
| With triphenyltin(IV) hydroxide In benzene-d6 at 90℃; for 3h; | 50% |
| Conditions | Yield |
|---|---|
| With sodium hydroxide In ethanol; water at 27℃; for 9h; | 97% |
| With sodium hydroxide In water; toluene at 20℃; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; chemoselective reaction; | 94% |
| With sodium hydroxide In water at 25℃; for 6h; | 93% |
| Conditions | Yield |
|---|---|
| With phenylsilane; C19H37N2(1+)*Br(1-) In neat (no solvent) at 20℃; under 3750.38 Torr; for 6h; Autoclave; | 95% |
| With 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In toluene at 100℃; under 22502.3 Torr; for 20h; Autoclave; | 70% |
| diethylzinc at 100℃; under 34200 Torr; for 18h; | 30% |
| With Wilkinson's catalyst; copper diacetate; lithium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 130℃; under 760.051 Torr; for 36h; Schlenk technique; |
- 121-69-7
N,N-dimethyl-aniline
- 122-52-1
triethyl phosphite
A
- 78-40-0
triethyl phosphate
B
- 93-61-8
N-methyl-N-phenylformamide
| Conditions | Yield |
|---|---|
| With tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; oxygen In 1,2-dichloro-ethane; acetonitrile at 25℃; for 24h; Schlenk technique; Irradiation; | A n/a B 95% |
| Conditions | Yield |
|---|---|
| With Cu/Al2O3; dihydrogen peroxide In water at 50℃; for 12h; Green chemistry; | 95% |
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Chemistry
n-Methylformanilide (93-61-8) is also named as Formamide,N-methyl-N-phenyl- ; Formanilide, N-methyl- ; Methylphenylformamide ; FORMIC ACID N-METHYLANILIDE ; METHYLFORMANILIDE and so on. n-Methylformanilide (93-61-8) is usually clear, colorless liquid. Its product categories are acids and esters.
CAS: 93-61-8
Molecular Formula: C8H9NO
Molecular Weight: 135.16
Molecular structure: 
EINECS: 202-262-3
Water Solubility: immiscible
Melting point: 8-13 °C(lit.)
Boiling Point: 243 °C at 760 mmHg
Index of Refraction: 1.567
Flash Point: 126.7 °C
BRN: 636496
Polarizability: 16.15 10-24cm3
Surface Tension: 42.3 dyne/cm
Enthalpy of Vaporization: 48 kJ/mol
Vapour Pressure: 0.0329 mmHg at 25 °C
Surface Tension: 42.3 dyne/cm
Density: 1.083 g/cm3
Uses
n-Methylformanilide (93-61-8) is commonly used as organic intermediates.
Toxicity Data With Reference
RTECS#: CAS# 93-61-8: None listed
LD50/LC50: RTECS: Not available.
Carcinogenicity: N-METHYLFORMANILIDE, 99% - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: The toxicological properties have not been fully investigated.
Safety Profile
Hazard Codes: 
Xn,
Xi
Risk Statements: 22-43-38
R22:Harmful if swallowed.
R43:May cause sensitization by skin contact.
R38:Irritating to skin.
Safety Statements: 36/37
S36/37:Wear suitable protective clothing and gloves.
WGK Germany: 2
HS Code: 29242995
Specification
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, strong oxidants.
Incompatibilities with Other Materials Strong oxidizing agents.
Hazardous Decomposition Products Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization Has not been reported.